This paper focuses on the characterization approach to evaluate the decay state of Pietra Serena of historic buildings in Florence (Italy). Pietra Serena is a Florentine sandstone largely used in the city especially during the Renaissance; it is a symbol of cultural heritage of Florence and constitutes a large part of the city center, which was named a World Heritage Site by UNESCO in 1982. Unfortunately, many environmental factors negatively affect the stone, increasing damage and the danger of falling material. Any detachment of stone fragments, in addition to constitute a loss in cultural heritage, can be dangerous for citizens and the many tourists that visit the city. The use of non-destructive techniques (NDTs) as ultrasonic and Schmidt hammer tests can quantitatively define some mechanical properties and help to monitor the decay degree of building stone. In this study, the NDTs were combined with mineralogical, petrographical, chemical and physical analyses to investigate the stone materials, in order to correlate their features with the characteristics of the different artefacts in Pietra Serena. Correlations between the NDTs results and the compositional characteristics of the on-site stone were carried out; such discussion allows to identify zones of weakness and dangerous unstable elements.

This article investigates the influence of natural organic materials on the properties of traditional mortars. Mortar specimens produced with two binders (natural hydraulic lime and aged lime putty) with the same sand and three different organic additives (linseed oil, brown sugar, and cow’s milk, with different percentages) were created. The color variations (colorimetry), waterproofing behavior (water capillarity test), permeability (water vapor permeability test), mechanical properties (maximum resistance to compression test), mineralogical composition (X-ray diffraction), and optical properties of mortars (transmitted light microscopy, UV fluorescence microscopy), and carbonation using a phenolphthalein indicator, were evaluated after 28 days, 3, 6, and 12 months. In this article, we highlighted a series of transformations induced by the additives: a strong modification of colorimetric parameters, a general hydrophobic effect of milk and oil not linked to a total occlusion of porosity, a decrease of mechanical parameters in the specimens prepared with hydraulic lime with respect to the specimen without additives, a different distribution and shape of macropores, a different level of carbonation. This article also describes the role of the preparation methods in the influence of natural organic materials on the properties of traditional mortars.

Today, the need to dispose of a huge amount of ceramic industrial waste represents an important problem for production plants. Contextually, it is increasingly difficult to retrieve new mineral resources for the realization of building materials. Reusing ceramic industrial waste as precursors for building blocks/binders, exploiting their aluminosilicate composition for an alkaline activation process, could solve the problem. This chemical process facilitates the consolidation of new binders/blocks without thermal treatments and with less CO₂ emissions if compared with traditional cements/ceramics. The alkali-activated materials (AAMs) are today thought as the materials of the future, eco-sustainable and technically advanced. In this study, six different kind of industrial ceramic waste are compared in their chemical and mineralogical composition, together with their thermal behaviour, reactivity in an alkaline environment and surface area characteristics, with the aim of converting them from waste into new resources. Preliminary tests of AAM synthesis by using 80%–100% of ceramic waste as a precursor show promising results. Workability, porosity and mechanical strengths in particular are measured, showing as, notwithstanding the presence of carbonate components, consolidated materials are obtained, with similar results. The main factors which affect the characteristics of the synthetized AAMs are the precursors’ granulometry, curing temperature and the proportions of the activating solutions.

The Historic Center of Florence, a UNESCO World Heritage Site, includes many examples of architecture characterized by rough-hewn rusticated block facades—a very common masonry technique in the Florentine Renaissance—made in Pietraforte sandstone. The latter features numerous criticalities related to its intrinsic characteristics and to decay phenomena that are due to weathering and pollution. A multidisciplinary methodology has been developed starting from historic analysis and architectural survey to a complete optometric, mechanical, physical, mineralogical, and petrographic characterization of rough-hewn rusticated blocks, applied to the case study of the Palazzo Medici Riccardi facades. The studies performed in this work cover several research fields, from architecture to geology, going through material diagnostics, and aim at improving knowledge and designing new restoration solutions for Pietraforte building-material criticalities. The research proposes an operative protocol aimed at supporting restoration projects and monitoring plans, with the aim to protect historical, architectural, and artistic cultural heritage and to safeguard the people who visit the city of Florence every year.

Here, we demonstrate, for the first time, the possibility of distinguishing between geogenic and anthropogenic calcite in a non-destructive and effective way, using high-resolution micro-Raman spectroscopy combined with machine learning workflow.

Prior to restoration work, the frescoes created at the end of the XV century by the painter Saturnino Gatti (1463–1518) in the apse of the Church of St. Panfilo in Villagrande di Tornimparte (L’Aquila) were the subject of a thorough diagnostic study involving several tests, from in situ non-destructive analysis to laboratory micro-destructive analysis on the collected samples. In this paper, we report the application of the sonic pulse velocity test, hygrometric tests, and infrared thermography to assess the state of conservation of the frescoes, i.e., the combined system of plaster and wall support. The complete analysis of the frescoes’ state of conservation revealed significant insights. The integrity of the plaster was evaluated through sonic pulse velocity tests, which highlighted several areas of detachment or degradation phenomena. Hygrometric analysis described humidity variations, particularly near the boundary between the conch area and the church naves. Passive infrared thermography detected temperature inhomogeneities, emphasizing differences in the wall texture and the masonry structure. Moreover, by comparing sonic pulse velocity and passive thermography images, a certain degree of correlation between hot areas and slow areas in the presence of possible detachments was noticed. In addition, pulse-compression active thermography was applied in a few spots, and for the first time, to the best of our knowledge, the virtual wave concept was applied to the cultural heritage field. This strategy helps in better associating anomalies with depth. The measurement campaign was part of a research project conducted by members of the Italian Association of Archaeometry (AIAr), and the results were compared and integrated with those of other non-destructive and analytical methods.