Reservoir sediments act as important receivers and sources for nutrients in the overlaying water. To determine the sediments adsorption and release characteristics and their impacts on water quality, surface sediments samples collected from Biliuhe reservoir in August 2015 were studied through simulation experiments in a laboratory. The results demonstrated that the equilibrium concentrations (EC₀) of ammonia nitrogen (NH₄⁺–N) and total phosphorus (TP) were 8.29 mg/L and 0.025 mg/L, respectively, which were both higher than the average concentrations in the overlying water. Therefore, the sediments of Biliuhe reservoir mainly acted as the pollution sources for NH₄⁺–N and TP, and the release to water showed a seasonal variation. When potential release amounts were considered, the average concentrations of NH₄⁺–N and TP in the overlaying water could reach 6.4 mg/L and 0.21 mg/L, respectively, which significantly exceeded the current contents. Further, water quality exhibited a decreased tendency after taking the release potential of nutrients into account of water quality assessment. Among the samples, 42% and 33% of them in summer and autumn exceeded the third level of the National Surface Water Quality Standards of China (GB3838-2002). The results indicated that sediments release potential had an unignored influence on water quality during various seasons.

Artificial underground reservoirs have changed the hydrological cycle from its natural condition. This modification may trigger a series of negative environmental effects both at the local and regional levels. This study investigated the impact of the Wanghe artificial underground reservoir on groundwater flow and quality in the reservoir and its downstream area. Wanghe is a typical artificial underground reservoir scheme in China, which assumes the dual function of fresh-water preservation and control of seawater intrusion. The groundwater flow pattern has changed after the reservoir construction, and the water level in the reservoir rose rapidly. Evaluation of long-term groundwater level fluctuation suggested that the reservoir deprived the downstream aquifer of the runoff, which it received under the natural flow regime. A preliminary isotopic evaluation using ³H was developed to understand the groundwater flow and renewal rates in the study area. The uniform distribution of tritium levels in the reservoir indicated that the stored water was well-mixed in both horizontal and vertical directions. The intervention on groundwater circulation also made differences in groundwater renewal rates between stored and downstream water. Field investigations on groundwater nitrogen pollution showed that the construction of the artificial underground reservoir resulted in nitrate accumulation in the stored water. Agriculturally derived nitrate was the largest contributor, and ${\mathrm{NO}}_3^{-}$ concentration varied considerably over time due to fertilization and irrigation activities, rainfall, and denitrification. ${\mathrm{NO}}_3^{-}$ -N distributed homogeneously in the reservoir, which was attributed to the construction of the subsurface dam, land use pattern and artificial groundwater flow.

Continuous water-level decline makes the changes of water quality in reservoirs more complicated. This paper uses trend analyses, wavelet analysis and principal component analysis-multiple linear regression to explore the changes and pollution sources affecting water quality during a period of continuous reservoir water level decline (from 65.37 m to 54.15 m), taking the Biliuhe reservoir as an example. The results showed that the change of water level of Biliuhe reservoir has a significant 13-year periodicity. The unusual water quality changes during the low water level period were as follows: total nitrogen continued to decrease. And iron was lower than its historical level. pH, total phosphorus, and ammonia nitrogen were higher than historical levels and fluctuated seasonally. Permanganate index increased as water level decreased after initial fluctuations. Dissolved oxygen was characterized by high content in winter and relatively low content in summer. The pollutant sources of non-point source pollution (PC1), sediment and groundwater pollution (PC2), atmospheric and production & domestic sewage (PC3), other sources of pollution (PC4) were identified. The main source of DO, pH, TP, TN, NH₄-N, Fe and COD_Mn were respectively PC3 (42.13%), PC1 (47.67%), PC3 (47.62%), PC1 (29.75%), PC2 (47.01%), PC1 (56.97%) and PC2 (50%). It is concluded that the continuous decline of water level has a significant impact on the changes and pollution sources affecting water quality. Detailed experiments focusing on sediment pollution release flux, and biological action will be explored next.

Comprehensive assessment of water quality is an important technological measure for water environmental management and protection. Previous assessment methods tend to ignore the influences of sediment pollutant release and dynamic change of the water boundary. In view of this, this paper explores a new method for comprehensive water quality assessment. Laboratory simulation experiments are conducted to analyze the influences of sediment pollutant release on water quality, and the results are taken as increments, coupled with original samples, to constitute a new set of evaluation samples. Dynamic and comprehensive water quality assessment methods are created based on a principal component analysis (PCA)/analytic hierarchy process (AHP)–variable fuzzy pattern recognition (VFPR) model and adopted to evaluate water quality. A geographic information system (GIS) is applied to visually display the results of water quality assessment and the change of the water boundary. This study takes Biliuhe Reservoir as an engineering example. The results show the change process of the water boundary, during which the water level is reduced from 63.10 m to 54.15 m. The reservoir water quality is fine, of which the water quality level (GB3838-2002) is between level 2 and level 3, and closer to level 2 taking no account of sediment pollutant release. The water quality of Biliuhe Reservoir, overall, is worse in summer and better in winter during the monitoring period. Meanwhile, the water quality shows the tendency of being better from upstream to downstream, and the water quality in the surface layer is better than that in the bottom layer. However, water quality is much closer, or even inferior, to level 3 when considering the release of nitrogen and phosphorus in sediments, and up to 42.7% of the original assessment results of the samples undergo changes. It is concluded that the proposed method is comparatively reasonable as it avoids neglecting sediment pollutant release in the water quality assessment, and the presentation of the evaluation results and change of the water boundary is intuitive with the application of GIS.

Sediment gradually accumulates at the bottom of reservoirs after decades of running. To explore the influences of sediments on the water quality of reservoirs, the spatial distribution, adsorption/release characteristics, and environment influence of sediment pollutants should be analyzed. In this paper, the spatial distributions of phosphorus (P) and P fractions in the Biliuhe reservoir (river valley reservoirs) sediments were investigated. The adsorption and release characteristics of sediments P were studied in the experiment, while its environmental influence was analyzed too. The results indicate that the concentration of P in sediments was higher at the dam and the Zhongling site, while lower at other entrances of the reservoir and the smallest in the water-level fluctuating zone. Total Phosphorus (TP) varied from 355.46 to 764.57 mg/kg. Inorganic Phosphorus (IP) was the main form of TP in sediments, making up a proportion of 56–75%, while the correlation coefficient of P bound to Al, Fe, and Mn oxides was 0.922. Hydroxide (Fe/Al-P) was the main form of IP, which accounted for 46–83% with a correlation coefficient of 0.888. The maximum adsorption capacity calculated by Langmuir model was between 714.29 and 3333.33 mg/kg. The adsorption efficiency obtained by the Freundlich model was within the range of 0.40–1.42, which indicated that P adsorption was more difficult in the water-level fluctuating zone. The critical adsorption and release concentration range was 0.1–0.2 mg/L for the majority of the sampling points. The amount of P released in 24 h (the initial concentration of TP in the overlying water was 0 mg/L) accounted for 1.15–4.16% of TP in sediments, which was higher than the average concentration in the reservoir. It is concluded that the sediment is the potential pollution source. The relationship between the change of environmental factors and the release of sediment contaminants should be considered in the future.

Human activities, especially dam construction, have changed the nutrient cycle process at the basin scale. Reservoirs often act as a sink in the basin and more nutrients are retained due to sedimentation, which induces the eutrophication of the surface water system. This paper proposes an integrated methodology to analyze the total nitrogen (TN) accumulation in a drinking water reservoir, based on the soil and water assessment tool (SWAT) model driven by the China Meteorological Assimilation Driving Datasets for the SWAT model (CMADS). The results show that the CMADS could be applied to drive the SWAT model in Northeast China. The dynamic process of TN accumulation indicates that the distribution of TN inputted into the reservoir fluctuated with the dry and wet seasons from 2009–2016, which was mainly governed by the amount of runoff. The annual average TN input and output fluxes of the Biliuhe reservoir were 274.41 × 10⁴ kg and 217.14 × 10⁴ kg, which meant that 19.76% of the TN input accumulated in the reservoir. Higher TN accumulation in the reservoir did not correspond to a higher TN load, due to the influence of flood discharge and the water supply. Interestingly, a higher TN accumulation efficiency was observed in normal hydrological years, because the water source reservoir always stores most of the water input for future multiple uses but rarely discharges surplus water. The non-point sources from fertilizer and atmospheric deposition and soils constituted the highest proportion of the TN input, accounting for 35.15%, 30.15%, and 27.72% of the average input. The DBWD (Dahuofang reservoir to Biliuhe reservoir water diversion) project diverted 32.03 × 10⁴ kg year⁻¹ TN to the Biliuhe reservoir in 2015–2016, accounting for 14.05% of the total annual input. The discharge output and the BDWD (Biliuhe reservoir to Dalian city water diversion) project output accounted for 48.75% and 47.74%, respectively. The effects of inter-basin water diversion projects should be of great concern in drinking water source water system management. There was a rising trend of TN level in the Biliuhe reservoir, which increases the eutrophication risk of the aquatic ecosystem. The TN accumulated in the sediment contributed to a large proportion of the TN accumulated in the reservoir. In addition to decreasing the non-point source nitrogen input from the upper basin, discharging anoxic waters and sediment with a high nitrogen concentration through the bottom hole of the dam could alleviate the nitrogen pollution in the Biliuhe reservoir.