To improve the mechanical properties and frost resistance of concrete, silica fume, and polyvinyl alcohol fiber compounded in concrete. The mechanical and frost resistance of concrete were comprehensively analyzed and evaluated for strength change, mass loss, and relative dynamic elastic modulus change by compressive strength test, flexural strength test, and rapid freeze-thaw test. The results showed that with the incorporation of silica fume and polyvinyl alcohol fiber, the compressive and flexural strengths of concrete were improved, and the decrease in mass loss rate and relative dynamic elastic modulus of concrete after freeze-thaw cycles were significantly reduced, which indicated that the compounding of silica fume and polyvinyl alcohol fiber improved the frost resistance of concrete. When the content of silica fume was 10% and the volume content of polyvinyl alcohol fiber was 1%, the comprehensive mechanical performance and frost resistance of concrete is the best. The compressive strength increased by 26.6% and flexural strength increased by 29.17% compared to ordinary concrete. Based on the test data, to study the macroscopic damage evolution of concrete compound silica fume and polyvinyl alcohol fiber under repeated freeze-thaw conditions. The Weibull distribution probability model and GM (1, 1) model were established. The average relative errors between the predicted and actual data of the two models are small and very close. It is shown that both models can reflect well the development of concrete damage under a freeze-thaw environment. This provides an important reference value and theoretical basis for the durability evaluation and life prediction of compound silica fume and polyvinyl alcohol fiber concrete in cold regions.

Cement-matrix composite are typical multi-scale composite materials, the failure process has the characteristics of gradual, multi-scale and multi-stage damage. In order to delay the multi-stage damage process of cement-matrix composites, the defects of different scales are suppressed by using different scales of fibres and fly ash (FA), and the overall performance of cement-matrix composites is improved, a new multi-scale fibre-reinforced cement-based composite composed of millimetre-scale polyvinyl alcohol fibre (PVA), micron-scale calcium carbonate whisker (CW), and nano-scale carbon nanotubes (CNTs) was designed in this study. The compressive strength, flexural strength, splitting tensile strength, and chloride ion permeability coefficient were used as assessment indices by the orthogonal test design. The impacts of the three fibre scales and fly ash on each individual index were examined, and the overall performance of the multi-scale fibre-reinforced cementitious materials (MSFRCC) was then optimized using grey correlation analysis. The optimized mix ratio for overall performance was PVA: 1.5%, CW: 2%, CNTs: 0.1%, FA: 40%. Compared with the optimal results for each group, the compressive strength of the final optimized MSFRCC group decreased by 8.9%, the flexural strength increased by 28.4%, the splitting tensile strength increased by 10%, and the chloride ion permeability coefficient decreased by 5.7%. The results show that the compressive performance and resistance to chloride ion penetration of the optimized group are slightly worse than those of the optimal group in the orthogonal test, but its flexural performance and splitting tensile performance are significantly improved.

The purpose of this research is to investigate the durability damage law for ultrahigh toughness cementitious composites (UHTCCs) under freeze–thaw environments and impact resistance. In this study, UHTCCs with fiber length-to-diameter ratios of 5/30, 8/30, 12/20, 12/30 and 12/48 were tested for impact resistance and freeze–thaw cycles. The freeze–thaw cycle process and impact resistance process for UHTCC are comprehensively analyzed and evaluated in terms of mass loss, compressive strength loss, relative dynamic elastic modulus loss and impact resistance number. The freeze–thaw damage prediction model for the relative dynamic elastic modulus of the UHTCC is established based on the regularity of the measured data for the relative dynamic elastic modulus of UHTCC and also on the GM(1,1) power model. The accuracy and reliability of the GM(1,1) power model is analyzed using the relative error, absolute correlation degree, mean variance and probability of small errors. According to the evolution law of the impact resistance number of the UHTCC, the impact damage prediction model for UHTCC is established based on the Weibull distribution model, and the accuracy of the model is analyzed by using the decision coefficient R². The results show that UHTCC has high durability performance, and the durability performance of UHTCC at a length-diameter ratio of 12/48 is optimal. The freeze–thaw damage evolution model and impact damage evolution model established in this research are sufficiently realistic, the average relative error of the GM(1,1) power model is less than 5%, and the coefficient of determination R² of the Weibull distribution model is greater than 0.93, which effectively reflects the damage development process for concrete under freeze–thaw and impact environment with high fitting accuracy.

Engineered cementitious composites (ECCs) are cement-based composite materials with strain-hardening and multiple-cracking characteristics. ECCs have multiscale defects, including nanoscale hydrated silicate gels, micron-scale capillary pores, and millimetre-scale cracks. By using millimetre-scale polyethylene (PE) fibres, microscale calcium carbonate whiskers (CWs), and nanoscale carbon nanotubes (CNTs) as exo-doped fibres, a multiscale enhancement system was formed, and the effects of multiscale fibres on the mechanical properties of ECCs were tested. The Box-Behnken experimental design method, which is a response surface methodology, was used to construct a quadratic polynomial regression equation to optimise ECC design and provide an optimisation of ECC mix proportions. The results of this study showed that a multiscale reinforcement system consisting of PE fibres, CWs, and CNTs enhanced the mechanical properties of ECCs. CWs had the greatest effect on the compressive strengths of highly ductile-fibre-reinforced cementitious composites, followed by CNTs and PE fibres. PE fibres had the greatest effect on the flexural and tensile strengths of high-ductility fibre-reinforced cementitious composites, followed by CWs and CNTs. The final optimisation results showed that when the ECC matrix was doped with 1.55% PE fibres, 2.17% CWs, and 0.154% CNTs, the compressive strength, flexural strength, and tensile strength of the matrix were optimal.

Silica-fume–polyvinyl-alcohol-fiber-reinforced concrete (SPRC) is a green and environmentally friendly composite material incorporating silica fume and polyvinyl alcohol fiber into concrete. To study the impact resistance of SPRC, compressive-strength and drop hammer impact tests were conducted on SPRC with different silica-fume and polyvinyl-alcohol-fiber contents. The mechanical and impact resistance properties of the SPRC were comprehensively analyzed in terms of the compressive strength, ductility ratio and impact-energy-dissipation variation. Based on the impact resistance of the SPRC, the impact life of SPRC with different failure probabilities was predicted by incorporating the Weibull distribution model, and an impact damage evolution equation for SPRC was established. The impact life of SPRC under the action of silica-fume content, polyvinyl-alcohol-fiber content and failure probability was analyzed in depth by the response surface method (RSM). The research results show that, when the content of silica fume is 10% and the content of polyvinyl alcohol fiber is 1%, the compressive strength and impact resistance of SPRC are the best. The RSM response model can effectively predict and describe the impact life of SPRC specimens under the action of three factors.

Engineered cementitious composites (ECCs) are a type of high-performance composite material, but in practical applications, ECCs that combine high strength with high toughness have greater development potential. Moreover, there is currently no unified standard or method for assessing the bending toughness of ECCs. This study is based on the Modified Andreasen and Andersen model (MAA) design ratio of the closest packing theory to investigate the effect of changes in the water–binder ratio and fiber content, where the water–binder ratio is taken as 0.19, 0.22, and 0.25, and the fiber content is taken as 1.0%, 1.5%, and 2.0%, respectively, to improve the comprehensive performance of ECCs. Information about tensile strength, bending strength, tensile toughness, and bending toughness is examined. Three different ways to measure bending toughness are compared and improved; the energy factor E_ms is used to measure bending toughness, and a response surface methodology is used to design and test the best mix ratio. The results indicate that when the water–binder ratio is 0.22 and the fiber content is 1.9%, the performance is optimal. Compared with the prediction group, the measured group presented an increase in tensile strength of 2.64%, a decrease in bending strength of 3.39%, an increase in tensile toughness of 3.22%, and an increase in the energy factor E_ms of 1.21%. This finding indicates that the response surface optimization improved the performance of the ECCs in various aspects.