The presence of heavy metals in waste water brings serious environmental pollution that threatens human health and the ecosystem. Bioremediation of heavy metals has received considerable and growing interest over the years. Thus, this paper presents the use of the Spent Mushroom Substrate (SMS) of Agaricus bisporus cultivation as a bioremediating agent to remove heavy metals that are present in industrial waters. These metals include chromium, lead, iron, cobalt, nickel, manganese, zinc, copper and aluminium. In particular, this study analyses the performance of SMS bioreactors with different groups of heavy metals at various concentrations. Between 80% and 98% of all contaminants that were analysed can be removed with 5 kg of SMS at hydraulic retention times of 10 and 100 days. The best removal efficiencies and longevities were achieved when removing iron (III), nickel and cobalt from contaminated water at a pH of 2.5. These results suggest that SMS can successfully treat waste water that has been contaminated with heavy metals.
The exhaustion of natural resources has increased petroleum prices and the environmental impact of oil has stimulated the search for an alternative source of energy such as biodiesel. Waste cooking oil is a potential replacement for vegetable oils in the production of biodiesel. Biodiesel is synthesized by direct transesterification of vegetable oils, which is controlled by several inputs or process variables, including the dosage of catalyst, process temperature, mixing speed, mixing time, humidity and impurities of waste cooking oil that was studied in this case. Yield, turbidity, density, viscosity and higher heating value are considered as outputs. This paper used multi-response surface methodology (MRS) with desirability functions to find the best combination of input variables used in the transesterification reactions to improve the production of biodiesel. In this case, several biodiesel optimization scenarios have been proposed. They are based on a desire to improve the biodiesel yield and the higher heating value, while decreasing the viscosity, density and turbidity. The results demonstrated that, although waste cooking oil was collected from various sources, the dosage of catalyst is one of the most important variables in the yield of biodiesel production, whereas the viscosity obtained was similar in all samples of the biodiesel that was studied.
Knowledge of the free draft of ports is essential for the adequate management of ports. To maintain these drafts, it is necessary to carry out dredging periodically, and to conduct bathymetries using traditional techniques, such as echo sounding. However, an echo sounder is very expensive and its accuracy is subject to weather conditions. Thus, the use of recent advancements in remote sensing techniques provide a better solution for mapping and estimating the evolution of the seabed in these areas. This paper presents a cost-effective and practical method for estimating satellite-derived bathymetry for highly polluted and turbid waters at two different ports in the cities of Luarca and Candás in the Principality of Asturias (Spain). The method involves the use of the support vector machine (SVM) technique and open Sentinel-2 satellite imagery, which the European Space Agency has supplied. Models were compared to the bathymetries that were obtained from the in situ data collected by a single beam echo sounder that the Port Service of the Principality of Asturias provided. The most accurate values of the training and testing dataset in Candás, were R2 = 0.911 and RMSE = 0.3694 m, and R2 = 0.8553 and RMSE = 0.4370 m, respectively. The accuracies of the training and testing dataset values in Luarca were R2 = 0.976 and RMSE = 0.4409 m, and R2 = 0.9731 and RMSE = 0.4640 m, respectively. The regression analysis results of the training and testing dataset were consistent. The approaches that have been developed in this work may be included in the monitoring of future dredging activities in ports, especially where the water is polluted, muddy and highly turbid.
The kinematic behavior of models that are based on the finite element method (FEM) for modeling the human body depends greatly on an accurate estimate of the parameters that define such models. This task is complex, and any small difference between the actual biomaterial model and the simulation model based on FEM can be amplified enormously in the presence of nonlinearities. The current paper attempts to demonstrate how a combination of the FEM and the MRS methods with desirability functions can be used to obtain the material parameters that are most appropriate for use in defining the behavior of Finite Element (FE) models of the healthy human lumbar intervertebral disc (IVD). The FE model parameters were adjusted on the basis of experimental data from selected standard tests (compression, flexion, extension, shear, lateral bending, and torsion) and were developed as follows: First, three-dimensional parameterized FE models were generated on the basis of the mentioned standard tests. Then, 11 parameters were selected to define the proposed parameterized FE models. For each of the standard tests, regression models were generated using MRS to model the six stiffness and nine bulges of the healthy IVD models that were created by changing the parameters of the FE models. The optimal combination of the 11 parameters was based on three different adjustment criteria. The latter, in turn, were based on the combination of stiffness and bulges that were obtained from the standard test FE simulations. The first adjustment criteria considered stiffness and bulges to be equally important in the adjustment of FE model parameters. The second adjustment criteria considered stiffness as most important, whereas the third considered the bulges to be most important. The proposed adjustment methods were applied to a medium-sized human IVD that corresponded to the L3–L4 lumbar level with standard dimensions of width = 50 mm, depth = 35 mm, and height = 10 mm. Agreement between the kinematic behavior that was obtained with the optimized parameters and that obtained from the literature demonstrated that the proposed method is a powerful tool with which to adjust healthy IVD FE models when there are many parameters, stiffnesses, and bulges to which the models must adjust.