The adhesion enhancement of graphene oxide (GO) and reduced graphene oxide (rGO) layer in the underlying polyethersulfone (PES) microfiltration membrane is a crucial step towards developing a high-performance membrane for water purification applications. In the present study, we modified the surface of a PES microfiltration membrane with plasma treatment (PT) carried out at different times (2, 10, and 20 min). We studied the effect of PT on the adhesion, stability, and performance of the synthesized GO/rGO-PES membranes. The membranes’ surface morphology and chemistry were characterized using atomic force microscopy, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy. The membrane performance was evaluated by conducting a diffusion test for potassium chloride (KCl) ions through the synthesized membranes. The results revealed that the 2 min PT enhanced the adhesion and stability of the deposited GO/rGO layer when compared to the other plasma-treated membranes. This was associated with an increase in the KCl ion rejection from ~27% to 57%. Surface morphology analysis at a high magnification was performed for the synthesized membranes before and after the diffusion test. Although the membrane’s rejection was improved, the analysis revealed that the GO layers suffered from micro/nano cracks, which negatively affected the membrane’s overall performance. The use of the rGO layer, however, helped in minimizing the GO cracks and enhanced the KCl ion rejection to approximately 94%. Upon increasing the number of rGO deposition cycles from three to five, the performance of the developed rGO-PES membrane was further improved, as confirmed by the increase in its ion rejection to ~99%.

In this work, we report the transfer of graphene onto eight commercial microfiltration substrates having different pore sizes and surface characteristics. Monolayer graphene grown on copper by the chemical vapor deposition (CVD) process was transferred by the pressing method over the target substrates, followed by wet etching of copper to obtain monolayer graphene/polymer membranes. Scanning electron microscopy (SEM), atomic force microscopy (AFM), and contact angle (CA) measurements were carried out to explore the graphene layer transferability. Three factors, namely, the substrate roughness, its pore size, and its surface wetting (degree of hydrophobicity) are found to affect the conformality and coverage of the transferred graphene monolayer on the substrate surface. A good quality graphene transfer is achieved on the substrate with the following characteristics; being hydrophobic (CA > 90°), having small pore size, and low surface roughness, with a CA to RMS (root mean square) ratio higher than 2.7°/nm.

Burst tests have been performed on the glass fiber-reinforced (GFR) thermoset pipes before and after exposure to natural and accelerated environmental conditions. The main objective of this study was to explore the effects of long-term natural outdoor and artificial accelerated environmental conditions on the burst resistance of the vinyl-based and epoxy-based GFR filament wound thermoset pipes which are targeted for use in crude oil transportation. The pipes were exposed to natural outdoor and accelerated dry heat conditions. The results show that these environments did not produce any noticeable degradation in the hydrostatic burst resistance of the pipes up to 24 months of natural exposure and up to 10,000 h of dry heat exposure.

In the present work, we developed a novel method for transferring monolayer graphene onto four different commercial hydrophilic micro/ultra-filtration substrates. The developed method used electrostatic charging to maintain the contact between the graphene and the target substrate intact during the etching step through the wet transfer process. Several measurement/analysis techniques were used in order to evaluate the properties of the surfaces and to assess the quality of the transferred graphene. The techniques included water contact angle (CA), atomic force microscopy (AFM), and field emission scanning electron microscopy (FESEM). Potassium chloride (KCl) ions were used for the transport study through the developed graphene-based membranes. The results revealed that 70% rejection of KCI ions was recorded for the graphene/polyvinylidene difluoride (PVDF1) membrane, followed by 67% rejection for the graphene/polyethersulfone (PES) membrane, and 65% rejection for graphene/PVDF3 membrane. It was revealed that the smoothest substrate was the most effective in rejecting the ions. Although defects such as tears and cracks within the graphene layer were still evolving in this new transfer method, however, the use of Nylon 6,6 interfacial polymerization allowed sealing the tears and cracks within the graphene monolayer. This enhanced the KCl ions rejection of up to 85% through the defect-sealed graphene/polymer composite membranes.

Membrane surface modification with the aim of lowering foulant to surface affinity, has recently gained considerable attention. In this article, we report improved performance (permeate flux, salt rejection, and resistance to alginate fouling) of surface-modified reverse osmosis (RO) membranes, under cross-flow filtration conditions. The surface of RO membranes was modified by amphiphilic hydroxethyl methacrylate-co-perfluorodecyl acrylate (HEMA-co-PFDA) copolymer films. The amphiphilic coatings were deposited via an all-dry and solventless vapor deposition technique, termed as initiated chemical vapor deposition. Scanning electron microscopy revealed that a dense and continuous layer of alginate formed on the surface of the unmodified membranes, whereas foulant deposition on the surface-modified membranes was found to be more sporadic and discontinuous. The coatings were found stable even after 6 h of exposure to sodium alginate at higher pressure (800 psi), as evidenced by ATR-FTIR analysis of the post-fouled membranes.