The decarburization behaviour during the sintering of metal-injection-moulded 420 stainless steel was investigated. Particular attention has been paid to the decarburization mechanisms and carbon distribution of parts sintered at different temperatures. The results indicate that the loss of carbon content occurs mainly through the reduction of surface oxides of powder particles or reaction with the atmosphere. Depending on the densification level, the sintering decarburization is separated into two stages. Below 1200 °C, decarburization occurs at the powder particle surface. The surface oxides react with the amorphous carbon or residual organics to pose the metal surface. At this time, the carbon content distribution of the sintered body is similar to that of the as-debound sample. The reduction of surface oxides promotes sintering. At 1200 °C, the densification speed is higher in the centre region of the sample, where the interconnected pores close and the second stage of decarburization takes place. At temperatures above 1200 °C, carbon atoms in the inner layers must migrate to the surface to react with the atmosphere. The decarburization speed is reduced and the carbon content distribution of the as-sintered part is similar to that of the dense decarburized part.
The metal injection molding (MIM) method was applied to manufacture a shaped charge liner (SCL) used for petroleum perforating bombs. Its application could overcome the drawback of heterogeneous density distribution prepared using the traditional powder metallurgy and spinning process. The sintering results showed that because of the limitation in the sintering temperature, the relative density of the W–Cu alloy shaped charge liners prepared by metal injection molding (MIM W–Cu SCLs) ranged from 48.05% at 1050 °C to 52.52% at 1100 °C, which was far below those prepared by spinning. Further increase to higher temperature led to the W–Cu separation, cracks, and distortion of the SCL. The explosive test proved that the shaped charge liners prepared by metal injection molding (MIM SCLs) could achieve comparable or even better penetration performance than those prepared by spinning. The particle size of tungsten played a significant role in the penetration performance in which the sample prepared from a −250-mesh tungsten powder showed the highest penetration depth, which was 18.44% deeper than that of the spinning process. From the observation of ballistic holes, the jet of the MIM SCL was composed of dispersed W–Cu particles without a slug. The diameters of the holes bored by the MIM SCLs were larger than those SCLs produced by spinning, which proved that the MIM SCL jet is noncoherent.