Lithium niobate (LN) has been the material of choice for electro-optic modulators owing to its excellent physical properties. While conventional LN electro-optic modulators continue to be the workhorse of the modern optoelectronics, they are becoming progressively too bulky, expensive, and power-hungry to fully serve the needs of this industry. Here, we demonstrate plasmonic electro-optic directional coupler switches consisting of two closely spaced nm-thin gold nanostripes on LN substrates that guide both coupled electromagnetic modes and electrical signals that control their coupling, thereby enabling ultra-compact switching and modulation functionalities. Extreme confinement and good spatial overlap of both slow-plasmon modes and electrostatic fields created by the nanostripes allow us to achieve a 90% modulation depth with 20-μm-long switches characterized by a broadband electro-optic modulation efficiency of 0.3 V cm. Our monolithic LN plasmonic platform enables a wide range of cost-effective optical communication applications that demand μm-scale footprints, ultrafast operation and high environmental stability.

Historically, the field of plasmonics has been relying on the framework of classical electrodynamics, with the local-response approximation of material response being applied even when dealing with nanoscale metallic structures. However, when the confinement of electromagnetic radiation approaches atomic scales, mesoscopic effects are anticipated to become observable, e.g., those associated with the nonlocal electrodynamic surface response of the electron gas. Here, we investigate nonlocal effects in propagating gap surface plasmon modes in ultrathin metal–dielectric–metal planar waveguides, exploiting monocrystalline gold flakes separated by atomic-layer-deposited aluminum oxide. We use scanning near-field optical microscopy to directly access the near-field of such confined gap plasmon modes and measure their dispersion relation via their complex-valued propagation constants. We compare our experimental findings with the predictions of the generalized nonlocal optical response theory to unveil signatures of nonlocal damping, which becomes appreciable for few-nanometer-sized dielectric gaps.