Historically, the field of plasmonics has been relying on the framework of classical electrodynamics, with the local-response approximation of material response being applied even when dealing with nanoscale metallic structures. However, when the confinement of electromagnetic radiation approaches atomic scales, mesoscopic effects are anticipated to become observable, e.g., those associated with the nonlocal electrodynamic surface response of the electron gas. Here, we investigate nonlocal effects in propagating gap surface plasmon modes in ultrathin metal–dielectric–metal planar waveguides, exploiting monocrystalline gold flakes separated by atomic-layer-deposited aluminum oxide. We use scanning near-field optical microscopy to directly access the near-field of such confined gap plasmon modes and measure their dispersion relation via their complex-valued propagation constants. We compare our experimental findings with the predictions of the generalized nonlocal optical response theory to unveil signatures of nonlocal damping, which becomes appreciable for few-nanometer-sized dielectric gaps.

Here, we show that the optical properties of direct-laser-written on-chip hollow-core waveguides—so-called light cages—can be controlled to a very high degree by dielectric nanofilms. Using low-temperature atomic layer deposition (ALD), alumina nanofilms are concentrically deposited on the high-aspect strands that surround the central air core and confine the light via the anti-resonant effect. In accordance with modal cutoff simulations without any free parameters, a linear spectral shift of the resonances with increasing film thickness is experimentally observed. The phenomenon is explained by a shift in the dispersions of cladding supermodes. As neither cage geometry nor polymer is affected by the film deposition, our results suggest ALD to be an essential tool for fine-tuning the properties of hollow-core light cages and to protect them from aggressive substances, being relevant for, e.g., bioanalytics or quantum technology.