Perovskite solar cells (PSCs) are promising photovoltaic (PV) technologies due to their high-power conversion efficiency (PCE) and low fabrication cost. This review article delves into the changing PSC landscape by analyzing the various dimensional diversity, which includes zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) structures, and exploring the potential of mixed-dimensional integrations to improve the stability and performance of these promising PV devices. To fine-tune the properties of perovskite materials, researchers have used cutting-edge methods like passivation strategies, interface engineering, and exact crystal growth control. As a result, significant improvements in open-circuit voltage (VOC), long-term stability, and PCE have been made. This thorough review also discusses the complex trade-offs involved in each dimensional integration, offering important insights into the complex interplay between material properties, device architecture, and fabrication techniques. Dimensional diversity in PSCs ultimately represents a dynamic path toward advancing the state-of-the-art in PV technology, providing invaluable direction to scientists and engineers attempting to realize the full potential of these next-generation solar cells. In conclusion, this review article offers a thorough analysis of the developments, difficulties, and potential of perovskite-based solar cells. It contributes to the knowledge and development of high-efficiency PSCs that hold great promise in the race for better photovoltaic performance by looking at printing techniques, stability issues, applications, and the special properties of perovskite materials.
Herein, we present an interfacial engineering strategy to construct an efficient hydrothermal approach by in situ growing cobalt-doped@MnO2 nanocomposite on highly conductive nickel foam (Ni foam) for supercapacitors (SCs). The remarkably high specific surface area of Co dopant provides a larger contacting area for MnO2. In the meantime, the excellent retentions of the hierarchical phase-based pore architecture of the cobalt-doped surface could beneficially condense the electron transportation pathways. In addition, the nickel foam (Ni foam) nanosheets provide charge-transport channels that lead to the outstanding improved electrochemical activities of cobalt-doped@MnO2. The unique cobalt-doped@MnO2 nanocomposite electrode facilitates stable electrochemical architecture, multi-active electrochemical sites, and rapid electro-transports channels; which act as a key factor in enhancing the specific capacitances, stability, and rate capacities. As a result, the cobalt-doped@MnO2 nanocomposite electrode delivered superior electrochemical activities with a specific capacitance of 337.8 F g–1 at 0.5 A g–1; this is greater than pristine MnO2 (277.9 F g–1). The results demonstrate a worthy approach for the designing of high-performance SCs by the grouping of the nanostructured dopant material and metal oxides.
1 March 2022 in Journal of Colloid and Interface Science
Herein, this report uses Co3O4 nanoneedles to decorate Mo-Co3O4 nanosheets over Ni foam, which were fabricated by the hydrothermal route, in order to create a supercapacitor material which is compared with its counterparts. The surface morphology of the developed material was investigated through scanning electron microscopy and the structural properties were evaluated using XRD. The charging storage activities of the electrode materials were evaluated mainly by cyclic voltammetry and galvanostatic charge-discharge investigations. In comparison to binary metal oxides, the specific capacities for the composite Co3O4@Mo-Co3O4 nanosheets and Co3O4 nano-needles were calculated to be 814, and 615 C g−1 at a current density of 1 A g−1, respectively. The electrode of the composite Co3O4@Mo-Co3O4 nanosheets displayed superior stability during 4000 cycles, with a capacity of around 90%. The asymmetric Co3O4@Mo-Co3O4//AC device achieved a maximum specific energy of 51.35 Wh Kg−1 and power density of 790 W kg−1. The Co3O4@Mo-Co3O4//AC device capacity decreased by only 12.1% after 4000 long GCD cycles, which is considerably higher than that of similar electrodes. All these results reveal that the Co3O4@Mo-Co3O4 nanocomposite is a very promising electrode material and a stabled supercapacitor.