Due to finite size effects, such as the high surface-to-volume ratio and different crystal structures, magnetic nanoparticles are found to exhibit interesting and considerably different magnetic properties than those found in their corresponding bulk materials. These nanoparticles can be synthesized in several ways (e.g., chemical and physical) with controllable sizes enabling their comparison to biological organisms from cells (10–100 μm), viruses, genes, down to proteins (3–50 nm). The optimization of the nanoparticles’ size, size distribution, agglomeration, coating, and shapes along with their unique magnetic properties prompted the application of nanoparticles of this type in diverse fields. Biomedicine is one of these fields where intensive research is currently being conducted. In this review, we will discuss the magnetic properties of nanoparticles which are directly related to their applications in biomedicine. We will focus mainly on surface effects and ferrite nanoparticles, and on one diagnostic application of magnetic nanoparticles as magnetic resonance imaging contrast agents.
Localized magnetic hyperthermia using magnetic nanoparticles (MNPs) under the application of small magnetic fields is a promising tool for treating small or deep-seated tumors. For this method to be applicable, the amount of MNPs used should be minimized. Hence, it is essential to enhance the power dissipation or heating efficiency of MNPs. Several factors influence the heating efficiency of MNPs, such as the amplitude and frequency of the applied magnetic field and the structural and magnetic properties of MNPs. We discuss some of the physics principles for effective heating of MNPs focusing on the role of surface anisotropy, interface exchange anisotropy and dipolar interactions. Basic magnetic properties of MNPs such as their superparamagnetic behavior, are briefly reviewed. The influence of temperature on anisotropy and magnetization of MNPs is discussed. Recent development in self-regulated hyperthermia is briefly discussed. Some physical and practical limitations of using MNPs in magnetic hyperthermia are also briefly discussed.
In the context of constant growth in the utilization of the Li-ion batteries, there was a great surge in the quest for electrode materials and predominant usage that lead to the retiring of Li-ion batteries. This review focuses on the recent advances in the anode and cathode materials for the next-generation Li-ion batteries. To achieve higher power and energy demands of Li-ion batteries in future energy storage applications, the selection of the electrode materials plays a crucial role. The electrode materials, such as carbon-based, semiconductor/metal, metal oxides/nitrides/phosphides/sulfides, determine appreciable properties of Li-ion batteries such as greater specific surface area, a minimal distance of diffusion, and higher conductivity. Various classifications of the anode materials such as the intercalation/de- intercalation, alloy/de-alloy, and various conversion materials are illustrated lucidly. Further, the cathode materials, such as nickel-rich LiNixCoyMnzO2 (NCM), were discussed. NCM members such as NCM 333, NCM 523 that enabled to advance for NCM622 and NCM81are reported. The nanostructured materials bridged the gap in the realization of next-generation Li-ion batteries. Li-ion batteries’ electrode nanostructure synthesis, performance, and reaction mechanisms were considered with great concern. The serious effects of Li-ion batteries disposal need to be cut significantly to reduce the detrimental effect on the environment. Hence, the recycling of spent Li-ion batteries has gained much attention in recent years. Various recycling techniques and their effect on the electroactive materials are illustrated. The key areas covered in this review are anode and cathode materials and recent advances along with their recycling techniques. In light of crucial points covered in this review, it constitutes a suitable reference for engineers, researchers, and designers in energy storage applications.
Hyperthermia is a noninvasive method that uses heat for cancer therapy where high temperatures have a damaging effect on tumor cells. However, large amounts of heat need to be delivered, which could have negative effects on healthy tissues. Thus, to minimize the negative side effects on healthy cells, a large amount of heat must be delivered only to the tumor cells. Magnetic hyperthermia (MH) uses magnetic nanoparticles particles (MNPs) that are exposed to alternating magnetic field (AMF) to generate heat in local regions (tissues or cells). This cancer therapy method has several advantages, such as (a) it is noninvasive, thus requiring surgery, and (b) it is local, and thus does not damage health cells. However, there are several issues that need to achieved: (a) the MNPs should be biocompatible, biodegradable, with good colloidal stability (b) the MNPs should be successfully delivered to the tumor cells, (c) the MNPs should be used with small amounts and thus MNPs with large heat generation capabilities are required, (d) the AMF used to heat the MNPs should meet safety conditions with limited frequency and amplitude ranges, (e) the changes of temperature should be traced at the cellular level with accurate and noninvasive techniques, (f) factors affecting heat transport from the MNPs to the cells must be understood, and (g) the effect of temperature on the biological mechanisms of cells should be clearly understood. Thus, in this multidisciplinary field, research is needed to investigate these issues. In this report, we shed some light on the principles of heat generation by MNPs in AMF, the limitations and challenges of MH, and the applications of MH using multifunctional hybrid MNPs.
Supercapacitors have become a popular form of energy-storage device in the current energy and environmental landscape, and their performance is heavily reliant on the electrode materials used. Carbon-based electrodes are highly desirable due to their low cost and their abundance in various forms, as well as their ability to easily alter conductivity and surface area. Many studies have been conducted to enhance the performance of carbon-based supercapacitors by utilizing various carbon compounds, including pure carbon nanotubes and multistage carbon nanostructures as electrodes. These studies have examined the characteristics and potential applications of numerous pure carbon nanostructures and scrutinized the use of a wide variety of carbon nanomaterials, such as AC, CNTs, GR, CNCs, and others, to improve capacitance. Ultimately, this study provides a roadmap for producing high-quality supercapacitors using carbon-based electrodes.