Herein, we present an interfacial engineering strategy to construct an efficient hydrothermal approach by in situ growing cobalt-doped@MnO₂ nanocomposite on highly conductive nickel foam (Ni foam) for supercapacitors (SCs). The remarkably high specific surface area of Co dopant provides a larger contacting area for MnO₂. In the meantime, the excellent retentions of the hierarchical phase-based pore architecture of the cobalt-doped surface could beneficially condense the electron transportation pathways. In addition, the nickel foam (Ni foam) nanosheets provide charge-transport channels that lead to the outstanding improved electrochemical activities of cobalt-doped@MnO₂. The unique cobalt-doped@MnO₂ nanocomposite electrode facilitates stable electrochemical architecture, multi-active electrochemical sites, and rapid electro-transports channels; which act as a key factor in enhancing the specific capacitances, stability, and rate capacities. As a result, the cobalt-doped@MnO₂ nanocomposite electrode delivered superior electrochemical activities with a specific capacitance of 337.8 F g^–1 at 0.5 A g^–1; this is greater than pristine MnO₂ (277.9 F g^–1). The results demonstrate a worthy approach for the designing of high-performance SCs by the grouping of the nanostructured dopant material and metal oxides.

Battery-type electrode materials have attracted much attention as efficient and unique types of materials for hybrid battery supercapacitors due to their multiple redox states and excellent electrical conductivity. Designing composites with high chemical and electrochemical stabilities is beneficial for improving the energy storage capability of battery-type electrode materials. We report on an interfacial engineering strategy to improve the energy storage performance of a Co(OH)₂-based battery-type material by constructing polypyrrole-assisted and Ag-doped (Ag-doped@Co(OH)₂@polypyrrole) nanosheets (NSs) on a Ni foam using a hydrothermal process that provides richer electroactive sites, efficient charge transportation, and an excellent mechanical stability. Physical characterization results revealed that the subsequent decoration of Ag nanoparticles on Co(OH)₂ nanoparticles offered an efficient electrical conductivity as well as a reduced interface adsorption energy of OH^- in Co(OH)₂ nanoparticles as compared to Co(OH)₂@polypyrrole-assisted nanoparticles without Ag particles. The heterogeneous interface of the Ag-doped@Co(OH)₂@polypyrrole composite exhibited a high specific capacity of 291.2 mAh g⁻¹ at a current density of 2 A g⁻¹, and showed a good cycling stability after 5000 cycles at 5 A g⁻¹. The specific capacity of the doped electrode was enhanced approximately two-fold compared to that of the pure electrode. Thus, the fabricated Ag-doped@Co(OH)₂@polypyrrole nanostructured electrodes can be a potential candidate for fabricating low-cost and high-performance energy storage supercapacitor devices.

MgCo₂O₄ nanomaterial is thought to be a promising candidate for renewable energy storage and conversions. Nevertheless, the poor stability performances and small specific areas of transition-metal oxides remain a challenge for supercapacitor (SC) device applications. In this study, sheet-like Ni(OH)₂@MgCo₂O₄ composites were hierarchically developed on nickel foam (NF) using the facile hydrothermal process with calcination technology, under carbonization reactions. The combination of the carbon–amorphous layer and porous Ni(OH)₂ nanoparticles was anticipated to enhance the stability performances and energy kinetics. The Ni(OH)₂@MgCo₂O₄ nanosheet composite achieved a superior specific capacitance of 1287 F g⁻¹ at a current value of 1 A g⁻¹, which is higher than that of pure Ni(OH)₂ nanoparticles and MgCo₂O₄ nanoflake samples. At a current density of 5 A g⁻¹, the Ni(OH)₂@MgCo₂O₄ nanosheet composite delivered an outstanding cycling stability of 85.6%, which it retained over 3500 long cycles with an excellent rate of capacity of 74.5% at 20 A g⁻¹. These outcomes indicate that such a Ni(OH)₂@MgCo₂O₄ nanosheet composite is a good contender as a novel battery-type electrode material for high-performance SCs.

The composites of NiCo₂O₄ with unique structures were substantially investigated as promising electrodes. In this study, the unique structured nanosheets anchored on nickel foam (Ni foam) were prepared under the hydrothermal technique of NiCo₂O₄ and subsequent preparation of Co(OH)₂. The Co(OH)₂@NiCo₂O₄ nanosheet composite has demonstrated higher specific capacitances owing to its excellent specific surface region, enhanced rate properties, and outstanding electrical conductivities. Moreover, the electrochemical properties were analyzed in a three-electrode configuration to study the sample material. The as-designed Co(OH)₂@NiCo₂O₄ nanosheet achieves higher specific capacitances of 1308 F·g⁻¹ at 0.5 A·g⁻¹ and notable long cycles with 92.83% capacity retention over 6000 cycles. The Co(OH)₂@NiCo₂O₄ nanosheet electrode exhibits a long life span and high capacitances compared with the NiCo₂O₄ and Co(OH)₂ electrodes, respectively. These outstanding electrochemical properties are mainly because of their porous construction and the synergistic effects between NiCo₂O₄ and Co(OH)₂. Such unique Co(OH)₂@NiCo₂O₄ nanosheets not only display promising applications in renewable storage but also reiterate to scientists of the unlimited potential of high-performance materials.