In this work, a molecular dynamics simulation was conducted to study the microscopic mechanism of how nitrogen bubbles affect the formation of THF hydrates at the molecular level. The results obtained reveal that the nitrogen bubble can promote the formation of THF hydrates. In the system with a nitrogen bubble, more THF-filled cages were generated, and the crystal structure was more orderly. The promotion of nitrogen bubbles on hydrate crystallization comes from the dissolution of nitrogen molecules. Some of dissolved nitrogen molecules can be enclosed in small hydrate cages near the nitrogen bubble, which can serve as stable sites for hydrate crystal growth, resulting in the fact that THF-filled cages connected with N₂-filled cages are much more stable and have a long lifetime. The results in this work can help to understand the promotion effect of micro- and nano-air bubbles on the crystallization of THF hydrates.

This study simulated seabed high pressure and low temperature conditions to synthesize natural gas hydrates, multi-stage depressurization mode mining hydrates as the blank group, and then carried out experimental research on the decomposition and mining efficiency of hydrates by depressurization and injection of different alcohols, inorganic salts, and different chemical agent concentrations. According to the experimental results, the chemical agent with the best decomposition efficiency is preferred; the results show that: the depressurization and injection of a certain mass concentration of chemical agents to exploit natural gas hydrate is more effective than pure depressurization to increase the instantaneous gas production rate. This is because depressurization combined with chemical injection can destroy the hydrate phase balance while effectively reducing the energy required for hydrate decomposition, thereby greatly improving the hydrate decomposition efficiency. Among them, depressurization and injection of 30% ethylene glycol has the best performance in alcohols; the decomposition efficiency is increased by 52.0%, and the mining efficiency is increased by 68.2% within 2 h. Depressurization and injection of 15% calcium chloride has the best performance in inorganic salts; the decomposition efficiency is increased by 46.3%, and the mining efficiency is increased by 61.1% within 2 h. In the actual mining process, the appropriate concentration of chemical agents should be used to avoid polluting the environment.