Flue gas condensation heat recovery technology has a good technical and economic performance in industrial exhaust gas waste heat recovery. Thermal efficiency analysis is the traditional analysis method for the flue gas condensation heat recovery system but it cannot reflect the recovered heat degree. Exergy analysis, which can reflect the recovered energy heat degree, was first applied to the evaluation of a flue gas condensation waste heat recovery system in this paper. The calculation method of wet flue gas exergy is more complex as both a heat and mass transfer is presented. Flue gas waste heat exergy efficiency (EE) and the flue gas waste heat exergy utilization rate (EUR) were proposed as the evaluation indexes for exergy analysis. The exergy analysis method was applied to the comparative evaluation of three recovery schemes in a practical project. The results show that when the water vapor content of wet flue gas is less than 10%, the condensed water exergy can be neglected when calculating EE. The EUR could be used as a comprehensive index for comparing different waste heat recovery schemes, and EE could be used to judge whether the energy grade of heat exchange equipment was seriously decreased. Exergy analysis could effectively make up for the deficiency of thermal efficiency analysis that could not reflect the waste heat grade utilization. Exergy analysis and thermal efficiency analysis are recommended to be used simultaneously to make a more comprehensive analysis and evaluation of the system.

The results of the second trial production of the gas hydrate reservoir in the Shenhu area of the South China Sea show that the production of a gas hydrate reservoir by horizontal wells can greatly increase the daily gas production, but the current trial production is still far below the minimum production required for commercial development. Compared with a single horizontal well, a fishbone well has a larger reservoir contact area and is expected to achieve higher productivity in the depressurization development of gas hydrate reservoirs. However, there is still a lack of systematic research on the application of fishbone wells in Class I gas hydrate reservoirs. In this paper, a grid system for gas hydrate reservoirs containing fishbone wells is first established using the PEBI unstructured grid, and fine-grained simulation of reservoirs near the bottom of the wells is achieved by adaptive grid encryption while ensuring computational efficiency. On this basis, Tough + Hydrate software is adopted to simulate the productivity and physical field change of a fishbone well with different branching numbers. The results show that: the higher the number of branches in a fishbone well, the faster the free water production rate, reservoir depressurization, and free gas production rate in the initial stage of depressurization development, and the faster depressurization can effectively promote hydrate dissociation. Compared with a single horizontal well, the cumulative gas production of a six branch fishbone well can increase by 59.3%. Therefore, using multi-branch fishbone depressurization to develop Class I gas hydrate reservoirs can effectively improve productivity and the depressurization effect, but the hydrate dissociation will absorb a lot of heat and lead to a rapid decrease in reservoir temperature and hydrate dissociation rate. At the end of the simulation, the hydrate dissociation rate of all schemes was lower than 50%. In the later stage of depressurization development, the combined development method of heat injection and depressurization is expected to further provide sufficient thermal energy for hydrate dissociation and promote the dissociation of the hydrate.

The Shunbei oil formation is a deep, high-temperature carbonate reservoir. Acid fracturing is an effective technology to stimulate this formation. For acid fracturing, the temperature field is fundamental information for the acid system selection, acid–rock reaction, live acid penetration distance prediction, acid fracturing design, etc. Therefore, in this paper, we conduct a numerical study on the temperature field in acid fracturing to account for the acid–rock reaction in the Shunbei formation. Firstly, a new mathematical model of the fracture temperature field during acid fracturing is established based on the laws of mass and energy conservation and acid–rock reaction kinetics. The fracture model is based on a PKN model, which accounts for a few factors, such as the acid–rock reaction heat, acid–rock reaction rate dependence on the temperature, and the fracture width change with acid erosion. Then, the numerical mode is developed. Next, an extensive numerical study and a parameter analysis are conducted based on the model with the field data from the Shunbei formation. The study shows that the acid–rock reaction in acid fracturing has obvious effects on the temperature field, resulting in a 10~20 °C increase in the Shunbei formation. The acid–rock reaction dependence on temperature is a factor to be accounted for. The rock dissolution increases first and then decreases from the inlet to the tip of the fracture, unlike the monotonous decrease without temperature dependence. The temperature gradient is high near the inlet and then decreases gradually. Beyond half of the fracture, the temperature is close to the formation temperature. The temperature drops fast in the initial injection stage and tends to stabilize at about 50 min.

In this work, a molecular dynamics simulation was conducted to study the microscopic mechanism of how nitrogen bubbles affect the formation of THF hydrates at the molecular level. The results obtained reveal that the nitrogen bubble can promote the formation of THF hydrates. In the system with a nitrogen bubble, more THF-filled cages were generated, and the crystal structure was more orderly. The promotion of nitrogen bubbles on hydrate crystallization comes from the dissolution of nitrogen molecules. Some of dissolved nitrogen molecules can be enclosed in small hydrate cages near the nitrogen bubble, which can serve as stable sites for hydrate crystal growth, resulting in the fact that THF-filled cages connected with N₂-filled cages are much more stable and have a long lifetime. The results in this work can help to understand the promotion effect of micro- and nano-air bubbles on the crystallization of THF hydrates.

Natural gas hydrate reservoirs, with shallow burial, poor cementation, and low strength, are prone to submarine landslides triggered by hydrate decomposition during extraction. Prior studies have inadequately considered factors such as the dynamic decomposition of hydrates during depressurization, and its impacts on the reservoir’s geomechanical properties. In this paper, a coupled thermal–hydraulic–mechanical–chemical mathematical model of hydrate decomposition is proposed, and the dynamic geomechanical response and the effect of hydrate decomposition on seafloor settlement and slope destabilization during the process of depressurization mining are analyzed by combining the strength discount method with the example of a hydrate-bearing seafloor slope in the Shenhu area. Furthermore, the study employs an orthogonal experimental design along with range and variance analysis to gauge the impact of critical factors (degree of hydrate decomposition, seawater depth, hydrate reservoir burial depth, hydrate reservoir thickness, and slope angle) on slope stability. The findings suggest that hydrate decomposition is non-uniform and is influenced by stratigraphic temperature gradients and gravity. In the region where hydrate decomposition occurs, the decrease of pore pressure leads to the increase of effective stress. Additionally, the decomposition of hydrates decreases the shear modulus of sediments, leading to deformation and reduced permeability in the affected area. Over a three-year period of depressurization mining, the significantly reduced safety factor increases the risk of landslides. Various factors play a role in the control of submarine slope stability, with slope inclination being the primary factor, followed by the degree of hydrate decomposition, reservoir thickness, burial depth, and seawater depth. Among these factors, hydrate burial depth and seawater depth have a positive correlation with submarine slope stability, while increases in other factors generally decrease stability. These research findings have important implications for the safe exploitation of slopes that contain hydrates.

The significant vertical heterogeneity, variations in ground stress directions, and irregular bedding interfaces make it extremely challenging to predict fracture propagation in continental shale reservoirs. In this article, we conducted a series of triaxial laboratory experiments on continental shale outcrop rocks to investigate the effects of formation dip angle and wellbore orientation on crack propagation under horizontal well conditions. Our study revealed that fracture propagation features can be categorized into four distinct types: (1) hydraulic fractures pass through the bedding interface without activating it; (2) fractures pass through and activate the bedding interface; (3) hydraulic fractures open and penetrate the bedding interface while also generating secondary fractures; and (4) hydraulic fractures open but do not penetrate the bedding interface. We found that as the dip angle decreases, the likelihood of fractures penetrating through the bedding interface increases. Conversely, as the dip angle increases, fractures are more likely to simply open the interface without penetrating it. Moreover, we observed that the well azimuth significantly affects the degree of fracture distortion. Specifically, higher azimuth angles corresponded to a higher degree of fracture distortion.