In this work, an evaluation of the air of two Italian industrial cities, Turin and Biella, has been performed to identify the main sources affecting its quality and to evaluate its evolution along 15 years. These two cities are placed at the border of the Po valley, one of the most polluted areas of Europe, and the automotive and textile industries have been their main economic sectors. The elemental analysis of the PM₁₀ collected there in 2007 has been performed by ICP-MS and ICP-AES. The results identify the urban activities and the soil/road dust resuspension as the main sources of metals. Biella was overall less polluted in PM₁₀ than Turin, probably because of its smaller size, its smaller traffic volume, and the lower number of industries. However, the limit value imposed by the European legislation for daily average PM₁₀ mass concentration (50 μg m⁻³) was frequently exceeded in the collected samples: 22% and 50%, respectively for Biella and Turin. The concentration of specific toxic metals regulated by Italian legislation was never higher than the limit value for Cd (4 ng m⁻³) and Pb (0.5 μg m⁻³), whereas it was exceeded for Ni (20 ng m⁻³) in 22% of the samples from Turin and only in the 5% of those from Biella. In the same way, the risk analysis, performed using the target hazard quotient (THQ), calculated for children and adult populations, did not reveal warning values. Only for Cd in children were concerning values found (median THQ = 4.9). Element concentrations showed a seasonal trend, with higher values in November and December due to a combination of stable atmospheric conditions and strengthening of anthropic sources (e.g., combustion for heat generation). Finally, data concerning the amount of Cd, Ni, and Pb in the atmosphere provided by the regional agency for environmental protection (ARPA Piedmont) have been used to follow the evolution of these elements from 2007 to 2021 in the two cities. The data reveal a significant reduction of the concentrations of all considered metals in all the sites (higher than 50%), however maintaining the seasonal variability observed in PM₁₀ samples of 2007, with higher concentrations during the cold months and lower concentrations during the summer.

The determination of the authenticity of extra virgin olive oils (EVOOs) has become more interesting in recent years. Italy is the first country in Europe in terms of number of Protected Designation of Origin (PDO) oils, which connects consumers to a feeling of tradition and thus to higher quality standards. This work focused on the consideration of the inorganic content as a possible marker of EVOOs. Ten vegetable oils (VOs), eight Italian EVOOs and seven not Italian EVOOs were analyzed. After pretreatment by acid mineralization, Al, Ba, Ca, Cu, Fe, K, Li, Mg, Mn, Na, P, Sb, Se and Zn were determined by ICP-OES. The electrochemical properties of a selected group of EVOOs and other vegetal oils of different botanical origin were investigated by voltammetry. Carbon paste electrodes (CPEs) were prepared. The features observed in the voltammograms reflect the reactions of electroactive compounds, which are present in the oils. A chemometric treatment of the results was performed to assess the possibility to distinguish (i) the region of provenience considering the inorganic profile; and (ii) the plant species from which each oil was obtained on the basis of the current profile registered during voltammetric analysis. Inorganic composition seems to be a useful marker for the assessment of the geographical origin of an EVOO. The EVOO-CPEs voltammetry seems to have a good ability to distinguish the plant species of origin. This method could be useful to monitor the conservation status of the oils, as the redox profile is linked to the oxidative degradation state.

Rice husk is a waste byproduct of rice production. This material has a moderate cost and is readily available, representing 20–22% of the biomass produced by rice cultivation. This study focused on the properties of rice husk in the remediation of soils contaminated by heavy metals. The effect of particle size, pH, and the presence of organic ligands on sorption efficiency was evaluated for Cd, Cu, and Mn. The continuous flow method was used to select suitable operative conditions and maximize the retention of heavy metals. Subsequently, pot experiments were carried out by growing two broadleaf plants, Lactuca sativa and Spinacia oleracea, in aliquots of soil collected in a Piedmont (Northwest Italy) site heavily contaminated by Cu, Cr, and Ni. Rice husk was added to the contaminated soil to evaluate its effectiveness in immobilizing heavy metals. The availability of Cr, Mn, Ni, Cu, Zn, Cd, and Pb in soil was studied using Tessier’s sequential extraction protocol. The content of the elements was also analyzed in plants and the uptake of heavy metals was evaluated in relation to the addition of rice husk. The growth of both plants was more efficient in the presence of rice husk due to its ability to reduce the mobility of heavy metals in the soil. The simplicity, cost-effectiveness, and scalability of its employment make the use of rice husk suitable for practical applications in soil remediation.

Aluminium is the most common substrate in studies using impactors for the measurement of the number or the weight of size-segregated atmospheric particulate matter (PM), as its characteristics perfectly fit impactor requirements. However, its use is not recommended by manufacturers when one of the purposes of the study is the determination of the metal content in the sample. The aim of this work was to develop an efficient analytical procedure for the removal and acid digestion of PM samples collected on aluminium foils by a cascade impactor to perform the determination of metals. The possibility of performing the trace metal analysis of PM samples collected using aluminium foils is of great importance, as it allows the determination of an accurate size distribution and the elemental composition of the PM collected on each impactor stage. Two procedures were optimised by using different digestion and analysis techniques. Both procedures were then applied to the two halves of several Dekati low-pressure impactor (DLPI) samples, and the results were critically compared. The two procedures proved to be effective in the determination of extremely low concentrations of a large suite of analytes in different size fractions of PM emitted by a brake system.

Rice husk is a waste by-product of rice production. This material has a moderate cost and is readily available, representing 20-22% of the biomass produced by rice cultivation. This study focused on the properties of rice husk in remediation of soils contaminated by heavy metals. The effect of particle size, pH, and the presence of organic ligands on sorption efficiency was evaluated for cadmium (Cd), copper (Cu), and manganese (Mn). The continuous flow method was used to select suitable operative conditions and maximize the retention of heavy metals. Subsequently, pot experiments were carried out by growing two broadleaf plants, Lactuca sativa, and Spinacia oleracea, in aliquots of soil collected in a Piedmont (Northwest Italy) site heavily contaminated by Cu, chromium (Cr), and nickel (Ni). Rice husk was added to the contaminated soil to evaluate its effectiveness in immobilizing heavy metals. The availability of Cr, Mn, Ni, Cu, Zn, Cd, and Pb in soil was studied using Tessier's sequential extraction protocol. The content of the elements was also analyzed in plants and the uptake of heavy metals was evaluated in relation to the addition of rice husk. The growth of both plants resulted more efficient in the presence of rice husk due to its ability to reduce the mobility of heavy metals in the soil. The simplicity, cost-effectiveness, and scalability of its employment make the use of rice husk suitable for practical applications in soil remediation.

Accurate analysis of trace elements in particulate matter (PM) emitted by brake systems critically depends on the filter selection and handling processes, which can significantly impact analytical results due to contamination and elemental interference from filter elemental composition. This study systematically evaluated two widely used filter types, EMFAB (borosilicate glass microfiber reinforced with PTFE) and Teflon (PTFE), for their suitability in the trace element determination of brake-wear PM₁₀ collected using a tribometer set-up. A total of twenty-three PM₁₀ samples were analyzed, encompassing two different friction materials, to thoroughly assess the performance and analytical implications of each filter type. Filters were tested for their chemical background, handling practicality and potential contamination risk through extensive elemental analysis by inductively coupled plasma–optical emission spectrometry (ICP-OES) and inductively coupled plasma-mass spectrometry (ICP-MS). Additionally, morphological characterization of both filter types was conducted via scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDS) to elucidate structural features affecting particle capture and subsequent analytical performance. Significant differences emerged between the two filters regarding elemental interferences: EMFAB filters exhibited substantial background contribution, particularly for alkali and alkaline earth metals (Ca, Na, Mg and K), complicating accurate quantification at trace levels. Conversely, Teflon filters demonstrated considerably lower background but required careful manipulation due to their structural fragility and the necessity to remove supporting rings, potentially introducing analytical variability. Statistical analysis confirmed that the filter material significantly affects elemental quantification, particularly when the collected PM₁₀ mass is limited, highlighting the importance of careful filter selection and handling procedures. Recommendations for optimal analytical practices are provided to minimize contamination risks and enhance reliability in trace element analysis of PM₁₀ emissions. These findings contribute to refining analytical methodologies essential for accurate environmental monitoring and regulatory assessments of vehicular non-exhaust emissions.