We evaluated the distribution of 15 metal ions, namely Al, Cd, Cu, Cr, Fe, La, Mn, Ni, Pb, Sc, Ti, V, Y, Zn and Zr, in the soil of a contaminated site in Piedmont (Italy). This area was found to be heavily contaminated with Cu, Cr and Ni. The availability of these metal ions was studied using Tessier's sequential extraction procedure: the fraction of mobile species, which potentially is the most harmful for the environment, was much higher than that normally present in unpolluted soils. This soil was hence used to evaluate the effectiveness of treatment with vermiculite to reduce the availability of the pollutants to two plants, Lactuca sativa and Spinacia oleracea, by pot experiments. The results indicated that the addition of vermiculite significantly reduces the uptake of metal pollutants by plants, confirming the possibility of using this clay in amendment treatments of metal-contaminated soils. The effect of plant growth on metal fractionation in soils was investigated. Finally, the sum of the metal percentages extracted into the first two fractions of Tessier's protocol was found to be suitable in predicting the phytoavailability of most of the pollutants present in the investigated soil.

Soil is a non-renewable natural resource. However, the current rates of soil usage and degradation have led to a loss of soil for agriculture, habitats, biodiversity, and to ecosystems problems. Urban and former industrial areas suffer particularly of these problems, and compensation measures to restore environmental quality include the renaturation of dismissed areas, de-sealing of surfaces, or the building of green infrastructures. In this framework, the development of methodologies for the creation of soils designed to mimic natural soil and suitable for vegetation growth, known as constructed soils or technosols, are here reviewed. The possible design choices and the starting materials have been described, using a circular economy approach, i.e., preferring non-contaminated wastes to non-renewable resources. Technosols appear to be a good solution to the problems of land degradation and urban green if using recycled wastes or by-products, as they can be an alternative to the remediation of contaminated sites and to importing fertile agricultural soil. Nevertheless, waste use requires analysis to ensure the salubrity of the starting materials. Moreover, materials produced on site or nearby minimize the cost and the environmental impact of transport, thus the involvement of local stakeholders in the urban land management must be encouraged.

Currently, the pollution of soils by heavy metals is a problem of paramount relevance and requires the development of proper remediation techniques. In particular, lead is a frequently detected soil contaminant that poses adverse effects to the environment and human health. In this review, we provide an overview of the bioremediation treatments promoted by plants (phytoremediation), fungi, or bacteria that could be applied to areas polluted by lead. These restoration processes have the advantage of being environmentally friendly and cost-effective solutions that exploit plants to immobilize and extract contaminants from soil and water, and fungi and bacteria to degrade them. Phytoremediation is an extensively studied and mature practice, with many in-the-field applications where numerous plant species have been employed. In contrast, bioremediation processes promoted by fungi and bacteria are very promising but, up to now, studies have been mostly performed at a laboratory scale with only a few implementations in real-world situations; therefore, further research is needed.