High-performance electromagnetic interference (EMI) shielding materials with ultralow density and environment-friendly properties are greatly demanded to address electromagnetic radiation pollution. Herein, carbon nanotube/polylactic acid (CNT/PLA) materials with different CNT contents, which exhibit characteristics of light weight, environmental protection and good chemical stability, are fabricated using 3D printing technology, where CNTs are evenly distributed and bind well with PLA. The performances of 3D-printed CNT/PLA composites are improved compared to pure 3D-printed PLA composites, which include mechanical properties, conductive behaviors and electromagnetic interference (EMI) shielding. The EMI shielding effectiveness (SE) of CNT/PLA composites could be improved when the content of CNTs increase. When it reaches 15 wt%, the EMI SE of 3D-printed CNT/PLA composites could get up to 47.1 dB, which shields 99.998% of electromagnetic energy. Meanwhile, the EMI shielding mechanism of 3D-printed CNT/PLA composites is mainly of absorption loss, and it generally accounts for more than 80% of the total shielding loss. These excellent comprehensive performances endow a 3D-printed CNT/PLA composite with great potential for use in industrial and aerospace areas.
Composites with excellent thermomechanical and thermochemical properties are urgently needed in the aerospace field, especially for structural applications under high-temperature conditions. Carbon fiber-reinforced Si-based composites are considered the most promising potential high-temperature materials due to their excellent oxidation resistance and ablative behaviors, good structural designability, and excellent mechanical properties. The reinforcement of the relevant composites mainly involves carbon fiber, which possesses good mechanical and temperature resistance abilities. In this paper, the ablation behaviors and mechanisms of related composites are reviewed. For carbon fiber-reinforced pure Si-based composites (C/SiM composites), the anti-ablation mechanism is mainly attributed to the continuous glassy SiO2, which inhibits the damage of the substrate. For C/SiM composite doping with refractory metal compounds, the oxides of Si and refractory metal together protect the main substrate from ablation and oxidation. Moreover, in addition to thermochemical damage, thermophysical and thermomechanical behavior severely destroy the surface coating of the substrate.
This paper provides a comprehensive understanding of the amplitude- and frequency-dependent characteristics of rubber springs. The dynamic nonlinear inelasticity of rubber is a key academic problem for continuum mechanics and a bottleneck problem for the practical use of rubber structures. Despite intensive efforts witnessed in industrial applications, it still demands an unambiguous constitutive model for dynamic nonlinear inelasticity, which is known as the Payne effect. To this end, three types of rubber springs (shear-type (ST), compression-type (CT) and shear-compression-combination-type (SCCT)) were tested with amplitude and frequency sweeps in different conditions. We investigated and present changes in dynamic stiffness and loss factor with amplitude, frequency and the hysteresis loops of different rubber springs. We also propose a hypothesis and research strategy to study a constitutive model involving multiple factors of hyperelasticity, the Mullins effect, viscoelasticity and the Payne effect, which we hope will provide new ideas for the establishment of a constitutive equation.