Electric vehicles (EVs) are becoming more attractive for a variety of reasons. One of the major advantages of EVs is that they emit fewer polluted gases. Other factors that must be addressed include an increase in fuel prices and a decline in energy resources such as fossil fuels. These characteristics have a greater impact on Pakistan’s clean and green image. Electric vehicles are becoming an attractive option for reducing global fossil fuel usage, as well as CO₂ emissions, from road transportation. The electricity required to charge an EV’s battery is commonly sourced from the power grid. When EVs are charged by the electrical grid, there are significant power constraints in the system. To promote renewable energy consumption and reduce CO₂ emissions, specific solar system-based charging stations should be designed. Other benefits of renewable energy generation include increased grid flexibility and reduced grid congestion. Moreover, the State of Azad Jammu and Kashmir, Pakistan, has a huge potential for solar energy. This article investigates the possibility of designing a solar photovoltaic-based EV charging station for security bikes located in the State of Azad Jammu and Kashmir, Pakistan. Before installing a PV charging station, the charging station’s feasibility must be studied. The proposed study also analyzes the power reliability, energy cost, and CO₂ emissions of a PV-powered charging station. The proposed system’s outcomes are compared to grid-based charging stations. In comparison to other existing approaches, there is a significant reduction in greenhouse gas (GHG) emissions, including CO₂, CO, SO₂, and NOX. The proposed study anticipates the economic and environmental benefits of EV charging stations powered by renewable energy resources.