The phase structure and electronic properties of c-ZrO₂, t-ZrO₂ and m-ZrO₂ are calculated and compared using density functional theory. By calculating the energies for different lattice constants, the crystal structures of the three zirconia polymorphs are optimised. The calculation results are in good agreement with related experimental data and the cohesive energies do reflect the relative phase stability of the three zirconia polymorphs. The valence electronic density of states and the charge distributions on some typical planes are presented and discussed to investigate the valence electronic structure, the special electronic properties, and the Zr–O bond strength. The calculation results in this paper would be helpful to further predict the zirconia phase transition and some basic physical properties.

The effect of projectile nose shape on the ballistic performance of the ultra-high molecular weight polyethylene (UHMWPE) composite was studied through experiments and simulations. Eight projectiles such as conical, flat, hemispherical, and ogival nose projectiles were used in this study. The deformation process, failure mechanisms, and the specific energy absorption (SEA) ability were systematically investigated for analyzing the ballistic responses on the projectile and the UHMWPE composite. The results showed that the projectile nose shape could invoke different penetration mechanisms on the composite. The sharper nose projectile tended to shear through the laminate, causing localized damage zone on the composite. For the blunt nose projectile penetration, the primary deformation features were the combination of shear plugging, tensile deformation, and large area delamination. The maximum value of specific energy absorption (SEA) was 290 J/(kg/m²) for the flat nose projectile penetration, about 3.8 times higher than that for the 30° conical nose projectile. Furthermore, a ballistic resistance analytical model was built based on the cavity expansion theory to predict the energy absorption ability of the UHMWPE composite. The model exhibited a good match between the ballistic resistance curves in simulations with the SEA ability of the UHMWPE composite in experiments.

The effect of the layer sequence on the ballistic performance of Ti6Al4V (35 mm)/CP-Ti (5 mm) laminated composite armor, against a 12.7 mm armor piercing projectile, was systematically investigated, both experimentally and computationally. By introducing the Johnson–Cook constitutive model and fracture criterion, the penetrating process of the composite plate was well-simulated. Furthermore, the influence of the layer sequence on the ballistic performance and failure mechanism of the composite plate was evaluated from the perspective of energy absorption and the stress distribution. Numerical simulation results of the macro morphology and penetration depth agreed well with the experimental results. The results showed that the energy absorption histories of each layer and stress distribution of the composite plate were found to be significantly affected by the arrangement sequence. The ballistic performance of Ti6Al4V/CP-Ti was far superior to that of CP-Ti/Ti6Al4V because more energy was absorbed in the early stage of the penetration process, thereby reducing the damage to the rear face. Further studies showed that the first principal stress in both structures was radially distributed in space, but was mainly concentrated at the rear face when the CP-Ti was placed at the front. Therefore, this stress induced cracking and failure in that region and, consequently, lowered the overall ballistic performance.

The penetration of a 30CrMnMo ultra-high molecular weight polyethylene armor by a high-speed fragment was investigated via experiments and simulations. Analysis of the projectile revealed that the nose (of the projectile) is in the non-equilibrium state at the initial stage of penetration, and the low-speed regions undergo plastic deformation. Subsequently, the nose-tail velocities of the projectile were virtually identical and fluctuated together. In addition, the effective combination of the steel plate and polyethylene (PE) laminate resulted in energy absorption by the PE just before the projectile nose impacts the laminate. This early absorption plays a positive role in the ballistic performance of the composite armor. Further analysis of the internal energy and mass loss revealed that the PE laminate absorbs energy via the continuous and stable failure of PE fibers during the initial stages of penetration, and absorbs energy via deformation until complete penetration occurs. The energy absorbed by the laminate accounts for 68% of the total energy absorption, indicating that the laminate plays a major role in energy absorption during the penetration process.