Polystyrene (PS) is widely used in the plastics industry, but the application range of PS is limited due to its inherently high flammability. A variety of two-dimensional (2D) nanomaterials have been reported to impart excellent flame retardancy to polymeric materials. In this study, a 2D nanomaterial MXene–organic hybrid (O-Ti₃C₂) was applied to PS as a nanofiller. Firstly, the MXene nanosheets were prepared by acid etching, intercalation, and delamination of bulk MAX (Ti₃AlC₂) material. These exfoliated MXene nanosheets were then functionalized using a cationic surfactant to improve the dispersibility in DMF. Even with a small loading of functionalized O-Ti₃C₂ (e.g., 2 wt%), the resulting PS nanocomposite (PS/O-Ti₃C₂) showed good thermal stability and lower flammability evidenced by thermogravimetric analysis (TGA) and pyrolysis-combustion flow calorimetry (PCFC). The peak heat release rate (pHRR) was significantly reduced by 32% compared to the neat PS sample. In addition, we observed that the temperature at pHRR (T_pHRR) shifted to a higher temperature by 22 °C. By comparing the TGA and PCFC results between the PS/MAX and different weight ratios of PS/O-Ti₃C₂ nanocomposites, the thermal stability and 2D thermal- and mass-transfer barrier effect of MXene–organic hybrid nanosheets were revealed to play essential roles in delaying the polymer degradation.

Metal–organic frameworks (MOFs) are emerging as novel flame retardants for polymers, which, typically, can improve their thermal stability and flame retardancy. However, there is a lack of specific studies on the thermal decomposition kinetics of MOF-based polymer composites, although it is known that they are important for the modeling of flaming ignition, burning, and flame spread over them. The thermal decomposition mechanisms of poly (methyl methacrylate) (PMMA) have been well investigated, which makes PMMA an ideal polymer to evaluate how fillers affect its decomposition process and kinetics. Thus, in this study, UiO-66, a common type of MOF, was embedded into PMMA to form a composite. Based on the results from the microscale combustion calorimeter, the values of the apparent activation energy of PMMA/UiO-66 composites were calculated and compared against those of neat PMMA. Furthermore, under cone calorimeter tests, UiO-66, at only 1.5 wt%, can reduce the maximum burning intensity and average mass loss rate of PMMA by 14.3% and 12.4%, respectively. By combining UiO-66 and SiO₂ to form a composite, it can contribute to forming a more compact protective layer, which shows a synergistic effect on reducing the maximum burning intensity and average mass loss rate of PMMA by 22.0% and 14.7%, respectively.

Carbon dots (CDs) have aroused colossal attention in the fabrication of nanocomposite membranes ascribed to their ultra-small size, good dispersibility, biocompatibility, excellent fluorescence, facile synthesis, and ease of functionalization. Their unique properties could significantly improve membrane performance, including permeance, selectivity, and antifouling ability. In this review, we summarized the recent development of CDs-based nanocomposite membranes in many application areas. Specifically, we paid attention to the structural regulation and functionalization of CDs-based nanocomposite membranes by CDs. Thus, a detailed discussion about the relationship between the CDs’ properties and microstructures and the separation performance of the prepared membranes was presented, highlighting the advantages of CDs in designing high-performance separation membranes. In addition, the excellent optical and electric properties of CDs enable the nanocomposite membranes with multiple functions, which was also presented in this review.

Structured biochar (SC) was prepared by biochar from cattail-sludge mixture (CS) and high-density polyethylene (HDPE) and treated as an adsorbent, and the KH2PO4 and NH4Cl solution were treated as adsorbates, to explore the adsorption capacity of phosphorus (P) and nitrogen (N) on SC in water. A single factor experimental method was employed to determine the optimal parameters for SC. The results showed that: 60% sizing amount, 5 N (cm2)−1 molding pressure, 160 °C molding temperature and 95 min molding time were optimal parameters for SC preparation. The adsorption of P and N on SC conforms to the Langmuir model, with the distribution of adsorption sites on the surface tending to be even. The adsorption of P and N on SC is favorable and spontaneous, and the adsorption tends to be monolayer adsorption with a major role for chemical adsorption. The higher the temperature, the higher the adsorption capacity of P and N on SC is, and the affinity of SC with P is higher than that with N. The pseudo-second-order kinetic model for the adsorption of N and P by SC has a high degree of fit. The pHpzc value of SC was 8.57. The hydrophobicity and stability of SC are rather high, with the surface particles closely bonded and increased roughness and pore diameter. The adsorption mechanism of P and N on SC can be attributed to pore filling, electrostatic attraction and hydrogen bonding. The results can provide a new technology for the resource utilization of cattails and sludge, a new idea for the recycling and reuse of biochar, and a basis for the selection of materials for the treatment of eutrophic water bodies.

With the development of the information society, display technologies are evolving toward greater flexibility and advanced performance. Dye-based polyvinyl alcohol (PVA) complex films have gained widespread attention for their excellent resistance to high temperature and humidity. This review systematically summarizes the research progress of dye-based polarizers using PVA as the substrate, focusing on their preparation principles, film properties, and impacts on optical performance. Strategies to enhance optical properties and durability are discussed, including dye molecular optimization, formulation design, control of the dyeing process, and PVA substrate film modification. Notably, improving interfacial interactions between dyes and PVA enhances molecular orientation and stability, while PVA modification improves mechanical properties, water resistance, thermal stability, and flame retardancy. By demonstrating these enhanced comprehensive properties, this review highlights the potential of PVA–based films to serve as high-performance platforms for the development of next-generation multifunctional optical and display materials. Finally, the challenges and development directions of dye-based PVA complex films for optical applications in harsh environments are prospected. This review provides a theoretical basis and technical pathway for the design and development of next-generation high-performance composite polarizers.

To develop a highly efficient and environmentally friendly flame-retardant system, ionic liquids (ILs) have recently emerged as promising candidates. However, the addition of ILs into emulsion paint disrupts emulsion stability, leading to rapid demulsification due to electrostatic effects. Herein, IL–silica capsules were developed using a soft-template method. These capsules can be directly added to an acrylic emulsion paint system as flame-retardant additives. Incorporating 5 wt% IL–silica capsules into the system and coating it on fabric reduced flammability by 53% compared to untreated fabric. This work provides a novel and practical approach to enhance flame retardancy in emulsion paint systems without compromising their stability.