Due to the rising worldwide demand for green chemicals, the bio-based polymer market is anticipated to expand substantially in the future. The synthesis of functional polymers has been a burgeoning area of research for decades. The primary driving force behind the development of bio-based polymers has been their compostability and biodegradability, which are critical given the public concern about waste. Significant advancements in the method for refining biomass raw materials towards the creation of bio-based construction materials and products are driving this rise. Bio-based polymers with this chemical structure are more flexible and adaptive, which allows them to attain their intended characteristics and functionalities. In commercial applications and healthcare and biotechnology, where completely manufactured, naturally occurring biomolecules are utilized and such polymers have the greatest impact. At the same time, limitations in polymer architectural control, biostability, and structural dynamics hinder the creation of biocompatible and functionally varied polymers. From this standpoint, the importance of functional biosynthetic polymers in the future years is highlighted, as well as new methods for addressing the aforementioned challenges. The article comprehensively highlighted the current strategies, market dynamics, and research trends of emerging Bio-Based Polymers. In addition, the most recent scientific breakthroughs in bio-based polymers are discussed.

Polyhedral oligomeric silsesquioxane (POSS) has been considered as one of the most promising nanofillers in academic and industrial research due to its unique multifunctional nanostructure, easy functionalization, hybrid nature, and high processability. The progress of POSS has been extensive, particularly applications based on single- or multiple-armed POSS. In polymer hybrids, in order to enhance the properties, bifunctional POSS has been incorporated into the backbone chain of the polymer. This review summarizes recent developments in the synthesis, modification, and application of bifunctional POSS-containing composite materials. This includes amino-POSS, hydroxyl-POSS, aromatic ring-POSS, ether-POSS, and vinyl groups-POSS and their applications, exemplified by polyurethanes (PUs) and polyimides (PIs). In addition, the review highlights the enhancement of thermal, mechanical, and optical properties of the composites.

Currently, from the sustainable development point of view, edible films are used as potential substitutes for plastics in food packaging, but their properties still have limitations and require further improvement. In this work, novel edible carrageenan films reinforced with starch granules and nanocellulose were developed and investigated for application as a bio-based food packaging system. The nanocellulose was used to improve film mechanical properties. Aloe vera gel was incorporated for antibacterial properties. Glycerol and sesame oil were added as plasticizers into the nanocomposite film to improve flexibility and moisture resistance. The interactions between charged polysaccharide functional groups were confirmed by FTIR spectroscopy. The migration of starch particles on the upper film surface resulting in increased surface roughness was demonstrated by scanning electron and atomic force microscopy methods. Thermogravimetric analysis showed that all films were stable up to 200 °C. The increase in nanocellulose content in films offered improved mechanical properties and surface hydrophilicity (confirmed by measurements of contact angle and mechanical properties). The film with a carrageenan/starch ratio of 1.5:1, 2.5 mL of nanocellulose and 0.5 mL of glycerol was chosen as the optimal. It demonstrated water vapor permeability of 6.4 × 10⁻¹⁰ g/(s m Pa), oil permeability of 2%, water solubility of 42%, and moisture absorption of 29%. This film is promising as a biodegradable edible food packaging material for fruits and vegetables to avoid plastic.

Understanding the mechanism of molecular self-assembly to form well-organized nanostructures is essential in the field of supramolecular chemistry. Particularly, amphiphilic copolymers incorporated with polyhedral oligomeric silsesquioxanes (POSSs) have been one of the most promising materials in material science, engineering, and biomedical fields. In this review, new ideas and research works which have been carried out over the last several years in this relatively new area with a main focus on their mechanism in self-assembly and applications are discussed. In addition, insights into the unique role of POSSs in synthesis, microphase separation, and confined size were encompassed. Finally, perspectives and challenges related to the further advancement of POSS-based amphiphilics are discussed, followed by the proposed design considerations to address the challenges that we may face in the future.

At present, when the whole world is intensively switching to organic farming, the refusal or minimization of the usage of chemical plant protection products and synthesized fertilizers is a very urgent issue for the agro-industrial complex (AIC). Accordingly, the solution to the problems of increasing yields and ensuring the fight against pathogenic components should be carried out in accordance with the principles of “green” chemistry. In this regard, the usage of heteroleptic complexes based on carboxylic and amino acids with biogenic metals is dictated not only by their availability, low cost, and ability to increase crop yields but also by fungicidal activity, lower toxicity, and easy biodegradability, which lists them among the “green” and cost-effective plant biostimulants. In the present work, for the first time, a heteroleptic complex based on succinic acid and glycine, with the formula [Cu(succ)(gly)], was developed for usage as a fungicidal biostimulant, which has the ability to significantly reduce the number of pathogens. We found that this compound has a layered structure and was able to increase soybean germination up to 100%.