Groundwater contamination by heavy metals (HMs) released by weathering and mineral dissolution of granite, gneisses, ultramafic, and basaltic rock composition causes human health concerns worldwide. This paper evaluated the heavy metals (HMs) concentrations and physicochemical variables of groundwater around enriched chromite mines of Malakand, Pakistan, with particular emphasis on water quality, hydro-geochemistry, spatial distribution, geochemical speciation, and human health impacts. To better understand the groundwater hydrogeochemical profile and HMs enrichment, groundwater samples were collected from the mining region (n = 35), non-mining region (n = 20), and chromite mines water (n = 5) and then analyzed using ICPMS (Agilent 7500 ICPMS). The ranges of concentrations in the mining, non-mining, and chromite mines water were 0.02–4.5, 0.02–2.3, and 5.8–6.0 mg/L for CR, 0.4–3.8, 0.05–3.6, and 3.2–5.8 mg/L for Ni, and 0.05–0.8, 0.05–0.8, and 0.6–1.2 mg/L for Mn. Geochemical speciation of groundwater variables such as OH⁻, H⁺, Cr⁺², Cr⁺³, Cr⁺⁶, Ni⁺², Mn⁺², and Mn⁺³ was assessed by atomic fluorescence spectrometry (AFS). Geochemical speciation determined the mobilization, reactivity, and toxicity of HMs in complex groundwater systems. Groundwater facies showed 45% CaHCO₃, 30% NaHCO₃, 23.4% NaCl, and 1.6% Ca-Mg-Cl water types. The noncarcinogenic and carcinogenic risk of HMs outlined via hazard quotient (HQ) and total hazard indices (THI) showed the following order: Ni > Cr > Mn. Thus, the HHRA model suggested that children are more vulnerable to HMs toxicity than adults. Hierarchical agglomerative cluster analysis (HACA) showed three distinct clusters, namely the least, moderately, and severely polluted clusters, which determined the severity of HMs contamination to be 66.67% overall. The PCAMLR and PMF receptor model suggested geogenic (minerals prospects), anthropogenic (industrial waste and chromite mining practices), and mixed (geogenic and anthropogenic) sources for groundwater contamination. The mineral phases of groundwater suggested saturation and undersaturation. Nemerow’s pollution index (NPI) values determined the unsuitability of groundwater for domestic purposes. The EC, turbidity, PO₄⁻³, Na⁺, Mg⁺², Ca⁺², Cr, Ni, and Mn exceeded the guidelines suggested by the World Health Organization (WHO). The HMs contamination and carcinogenic and non-carcinogenic health impacts of HMs showed that the groundwater is extremely unfit for drinking, agriculture, and domestic demands. Therefore, groundwater wells around the mining region need remedial measures. Thus, to overcome the enrichment of HMs in groundwater sources, sustainable management plans are needed to reduce health risks and ensure health safety.

Groundwater contamination by potentially harmful elements (PHEs) originating from the weathering of granitic and gneissic rock dissolution poses a public health concern worldwide. This study investigated physicochemical variables and PHEs in the groundwater system and mine water of the Adenzai flood plain region, in Pakistan, emphasizing the fate distribution, source provenance, chemical speciation, and health hazard using the human health risk assessment HHRA-model. The average concentrations of the PHEs, viz., Ni, Mn, Cr, Cu, Cd, Pb, Co, Fe, and Zn 0.23, were 0.27, 0.07, 0.30, 0.07, 0.06, 0.08, 0.68, and 0.23 mg/L, respectively. The average values of chemical species in the groundwater system, viz., H⁺, OH⁻, Ni²⁺, Mn²⁺, Mn³⁺, Cr³⁺, Cr⁶⁺, Cu⁺, Cu²⁺, Cd²⁺, Pb²⁺, Pb⁴⁺, Co²⁺, Co³⁺, Fe²⁺, Fe³⁺, and Zn²⁺, were 1.0 × 10⁻⁴ ± 1.0 × 10⁻⁶, 1.0 × 10⁻⁴ ± 9.0 × 10⁻⁷, 2.0 × 10⁻¹ ± 1.0 × 10⁻³, 3.0 × 10⁻¹ ± 1.0 × 10⁻³, 1.0 × 10⁻²² ± 1.0 × 10⁻²³, 4.0 × 10⁻⁶ ± 2.0 × 10⁻⁶, 4.0 × 10⁻¹¹ ± 2.0 × 10⁻¹¹, 9.0 × 10⁻³ ± 1.0 × 10⁻², 2.0 × 10⁻¹ ± 2.0 × 10⁻³, 7.0 × 10⁻² ± 6.0 × 10⁻², 5.0 × 10⁻² ± 5.0 × 10⁻², 2.0 × 10⁻² ± 1.5 × 10⁻², 6.0 × 10⁻² ± 4.0 × 10⁻², 8.0 × 10⁻³¹ ± 6.0 × 10⁻³¹, 3.0 × 10⁻¹ ± 2.0 × 10⁻⁴, 4.0 × 10⁻¹⁰ ± 3.0 × 10⁻¹⁰, and 2.0 × 10⁻¹ ± 1.0 × 10⁻¹. The mineral compositions of PHEs, viz. Ni, were bunsenite, Ni(OH)₂, and trevorite; Mn viz., birnessite, bixbyite, hausmannite, manganite, manganosite, pyrolusite, and todorokite; Cr viz., chromite and eskolaite; Cu viz., CuCr₂O₄, cuprite, delafossite, ferrite-Cu, and tenorite; Cd viz., monteponite; Pb viz, crocoite, litharge, massicot, minium, plattnerite, Co viz., spinel-Co; Fe viz., goethite, hematite, magnetite, wustite, and ferrite-Zn; and Zn viz., zincite, and ZnCr₂O₄ demarcated undersaturation and supersaturation. However, EC, Ca²⁺, K⁺, Na⁺, HCO₃⁻, Cr, Cd, Pb, Co, and Fe had exceeded the WHO guideline. The Nemerow’s pollution index (NPI) showed that EC, Ca²⁺, K⁺, Na⁺, HCO₃⁻, Mn, Cd, Pb, Co, and Fe had worse water quality. Principal component analysis multilinear regression (PCAMLR) and cluster analysis (CA) revealed that 75% of the groundwater contamination originated from geogenic inputs and 18% mixed geogenic-anthropogenic and 7% anthropogenic sources. The HHRA-model suggested potential non-carcinogenic risks, except for Fe, and substantial carcinogenic risks for evaluated PHEs. The women and infants are extremely exposed to PHEs hazards. The non-carcinogenic and carcinogenic risks in children, males, and females had exceeded their desired level. The HHRA values of PHEs exhibited the following increasing pattern: Co > Cu > Mn > Zn > Fe, and Cd > Pb > Ni > Cr. The higher THI values of PHEs in children and adults suggested that the groundwater consumption in the entire region is unfit for drinking, domestic, and agricultural purposes. Thus, all groundwater sources need immediate remedial measures to secure health safety and public health concerns.

Soil pollution is a highlighted concern of modern society, particularly in developing countries. The Drosh-Shishi valley, which is a hilly region near Afghanistan with a land area of around 15,000 km², is situated in the south of Chitral District (Pakistan) and has a population of approximately 450,000. Nowadays, this region is being explored for soil pollution, specifically heavy metals which pose a potential risk to human health. Therefore, our main goal was to investigate possible sources of heavy metals’ spread and to assess the content levels in soil and the associated risks for human. We collected 34 representative samples from transported sediments and 31 from agricultural crops. We analyzed the soil samples for the contents of Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn using ICP-OES analyzers. These values were used to obtain the contamination factor (CF) and to estimate the potential health risk caused by heavy metals according to the USEPA dose–response model. Our results suggest that the heavy metal pollution has a geogenic source, but it is also aggregated by chemical fertilizers used in farming. Regarding levels, most of the metals except Pb showed contents above the permissible level, with CF values from moderate to high. Overall, Cu and Ni showed a significant total cancer risk (TCR > 1 × 10⁻⁴) in children. Therefore, we conclude that heavy metal pollution is causing a serious threat to humans in this area, and we recommend that authorities should make more efforts in monitoring the heavy metals content in soils to reduce potential health risks.

Arsenic (As) contaminated groundwater is a worldwide concern due to its chronic effects on human health. The objectives of the study were to evaluate natural inexpensive raw laterite (RL) and kaolinite (RK) for their potential use as As sorbents and to understand the As sorption on laterite and kaolinite by employing sorption and kinetic models. Raw laterite and RK were tested for EC, pH, XRF and CEC as basic parameters. Batch sorption and kinetic experiments data were fitted in the sorption (Langmuir and Freundlich) model and kinetic (pseudo-first and pseudo-second order) reaction equations, respectively. Morphological and structural changes were observed in RL and RK samples before and after As saturation by employing FTIR and SEM. The major constituent in RL was Fe and Al oxides while in RK major oxides were silica and Al. The Freundlich sorption model well explained the experimental data, indicating a greater sorption capacity of RL on a hetero-layered surface compared to RK. The kinetic reaction equations showed that equilibrium was achieved after a contact time of 240 min and the adsorption was chemisorption in nature. The RL and RK were found to be effective sorbents for As removal, however, RL showed maximum As adsorption and thus superior in comparison with RK. Structural and morphological characterization reveals the role of Fe and Al oxides in the case of RL, and Al oxides in the case of RK, in the adsorption of As. Hence this study concludes that these naturally occurring inexpensive resources can be used as sorbent agents for As-contaminated drinking water treatment.

Open and non-engineered dumping is a typical method for solid waste disposal in most cities of Pakistan. This practice of waste dumping poses a serious threat to the surrounding ecosystem and human population due to the release and transport of decomposed organic matter, i.e., leachate from dumpsite into the groundwater. The present study was conducted over a non-engineered and open dumpsite (Chowa Gujar), located in the outskirts of the highly populated city of Peshawar by using integrated geophysical techniques such as electrical resistivity tomography (ERT) and ground-penetrating radar (GPR) and geochemical techniques. The main goal was to delineate the characterization and depth of buried waste, to map the subsurface extension of contaminant plumes towards agricultural land and groundwater table and the concentration of heavy metals (HMs) in dump and agricultural soil. Geophysical results showed that the thickness of buried waste (predominantly composed of domestic waste) was around 4 m and the leachate plumes have percolated to the adjacent agricultural land. A range of heavy metals (mg/kg) such as Cr (20.5–26.6), Cd (2.6–5.7), Pb (0.35–21.25), Ni (2.5–53.05), Cu (29–68.3), Zn (45.7–77), and Co (18.9–23.2) have been found in the agricultural land adjacent to the dumpsite. The findings demonstrated that combined use of ERT and GPR successfully characterize the buried waste and spread of pollutant plumes spatially and vertically from Chowa Gujar dumpsite. The anomalous geophysical signatures were confirmed by geochemical characterization. The movement of leachate plumes towards agricultural land and groundwater table and the concentration of HMs in soil show that Chowa Gujar dumpsite is a potential source of contamination not only to the surrounding population but also to the agricultural land, surface (Bara River), and subsurface water bodies. In the study region, there is an urgency to take remediation and mitigation measures to reduce the level of pollution created by the dumpsite.