Natural fiber (NF) is one of the many resources that nature has provided. NFs decompose quickly and are biodegradable, renewable, and cost-effective. It may be scavenged from a variety of plant and animal sources. They are employed as reinforcing materials in polymers for NF composite development. Because of its environmental friendliness and long-term survivability, NF is growing in appeal among academics and researchers for usage in polymer composites. This study aims to offer a thorough evaluation of the most suitable and widely utilized natural fiber-reinforced polymer composites (NFPCs), along with their manufacture, processing, and applications. It also defines several external treatments of NF and their influence on the characteristics of NFPCs. The characteristics of NFPCs are affected by fiber supply, fiber type, and fiber structure. Numerous physical and chemical treatments were tested to see how they affected the thermal and strength properties of natural fiber-reinforced thermoplastic and thermosetting composites. Several polymer composite fabrication techniques were also studied. NFPCs have several disadvantages, notably low fire protection, poor strength properties, and greater moisture absorption, which have prevented their application. It is shown how NFPCs are employed in a variety of industries, particularly automotive and research industries. The review discovered that intentionally changing the regular fiber enhanced the thermochemical and physico-mechanical properties of the NFPCs by means of improving the grip between the fiber surface and the polymer framework. This study aims to provide important and fundamental facts on NF and their composites, which will aid in new investigations, the creation of a creative framework for polymer composite types, and the achievement of Sustainable Development Goals.
Silica fume (SF) is a frequently used mineral admixture in producing sustainable concrete in the construction sector. Incorporating SF as a partial substitution of cement in concrete has obvious advantages, including reduced CO2 emission, cost-effective concrete, enhanced durability, and mechanical properties. Due to ever-increasing environmental concerns, the development of predictive machine learning (ML) models requires time. Therefore, the present study focuses on developing modeling techniques in predicting the compressive strength of silica fume concrete. The employed techniques include decision tree (DT) and support vector machine (SVM). An extensive and reliable database of 283 compressive strengths was established from the available literature information. The six most influential factors, i.e., cement, fine aggregate, coarse aggregate, water, superplasticizer, and silica fume, were considered as significant input parameters. The evaluation of models was performed by different statistical parameters, such as mean absolute error (MAE), root mean squared error (RMSE), root mean squared log error (RMSLE), and coefficient of determination (R2). Individual and ensemble models of DT and SVM showed satisfactory results with high prediction accuracy. Statistical analyses indicated that DT models bested SVM for predicting compressive strength. Ensemble modeling showed an enhancement of 11 percent and 1.5 percent for DT and SVM compressive strength models, respectively, as depicted by statistical parameters. Moreover, sensitivity analyses showed that cement and water are the governing parameters in developing compressive strength. A cross-validation technique was used to avoid overfitting issues and confirm the generalized modeling output. ML algorithms are used to predict SFC compressive strength to promote the use of green concrete.
Prediction of work Travel mode choice is one of the most important parts of travel demand forecasting. Planners can achieve sustainability goals by accurately forecasting how people will get to and from work. In the prediction of travel mode selection, machine learning methods are commonly employed. To fit a machine-learning model to various challenges, the hyperparameters must be tweaked. Choosing the optimal hyperparameter configuration for machine learning models has an immediate effect on the performance of the model. In this paper, optimizing the hyperparameters of common machine learning models, including support vector machines, k-nearest neighbor, single decision trees, ensemble decision trees, and Naive Bayes, is studied using the Bayesian Optimization algorithm. These models were developed and optimized using two datasets from the 2017 National Household Travel Survey. Using several criteria, including average accuracy (%), average area under the receiver operating characteristics, and a simple ranking system, the performance of the optimized models was investigated. The findings of this study show that the BO is an effective model for improving the performance of the k-nearest neighbor model more than other models. This research lays the groundwork for using optimized machine learning methods to mitigate the negative consequences of automobile use.
27 March 2023 in Construction and Building Materials
Ceramic-based wastes generated from different industrial activities have increasingly been reused as construction material incorporated into concrete. In general, these wastes just replace common concrete aggregates such as sand and gravel. In the present work, waste from clay brick industries composted of kaolinite minerals were for the first time evaluated for their potential to be reused as the pozzolan constituent of a cement for structural concrete. Initial standard testes revealed that the clay ceramic waste (CCW) displays high pozzolanicity. Concrete was then produced with 10 and 20 wt.% of CCW mixed with ordinary Portland cement (OPC) as its pozzolan constituent. Compression strength of these concretes and of pure OPC as a control sample were determined in standard tests after 14 and 28 days of curing. In addition, the corresponding density, water absorption, capillarity and percentage of voids were measured together with the evaluation of microstructural indices by scanning electron microscopy. The initial tests confirmed that the CCW is indeed an effective pozzolanic potential due to a chemical effect by reacting with CH to generate C–S–H. Moreover, the technological results proved that CCW might effectively replace the pozzolan cement constituent for structural concrete.
Given the increasing risks that antibiotic abuse poses to microecology and human health, it is imperative to develop incredibly powerful adsorbents. This study investigated the use of environmentally sustainable polymeric nanocomposite based on gum arabic (GA) and magnetic nanoparticles (MNPs) synthesized via co-precipitation method to form gum arabic magnetitic nanoparticles (GA-MNPs) as an efficient adsorbent for ciprofloxacin (CIP) removal from aqueous solution. The physicochemical properties and morphology of the synthesized GA-MNPs were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and Energy Dispersive X-Ray Analysis (EDX). The experiment was designed by response surface methodology (RSM) and the Central Composite Design (CCD) was utilized to optimize the operating variables: contact time (0–120 min), pH (3–10), adsorbent dosage (0.10–0.40 g/L), and concentration of adsorbate (5–100 mg/L). Results showed that 96.30% was the maximum percentage of CIP removed. The adsorption effect of the CIP molecule on the surface of the GA-MNPs was investigated using regression analysis and analysis of variance. Furthermore, Freundlich Isotherm and Pseudo Second order kinetic equations have the highest consistency with experimental investigations suggesting double-layer adsorption. This implies that chemisorption was the mechanism involved. In addition, the calculated thermodynamic parameters were postulating an exothermic and spontaneous method in nature. Owing to its adsorption selectivity and recyclability, GA-MNPs could be classified as an environmentally friendly, less expensive, and highly efficient promising adsorbent for remediation of CIP from aqueous solution.