In this research, the curing degree of an acrylate-based monomer using direct UV-assisted writing technology was characterized by differential photo calorimetry (Photo-DSC) to investigate the curing behavior. Triggered by the UV light, the duo function group monomer 1,6-Hexamethylene diacrylate (HDDA), photoinitiator 1173 and photoinhibitor exhibit a fast curing process. The exothermal photopolymerization reaction was performed in the isothermal mode in order to evaluate the different thermal effects that occurred during the photopolymerization process. The influences of both UV light intensity and exposure time were studied with single-factor analysis. The results obtained by photo-DSC also allow us to perform the kinetic study of the polymerization process: The results show that, for the reaction, the higher the UV intensity, the higher the curing degree together with faster curing speed. At the same time, the effect of the heat released during the exothermic reaction is negligible for the polymerization process. When increasing the exposure time, limited improvement of curing degree was shown, and the distribution is between 65–75%. The reaction enthalpy and related curing degree work as a function of time. The Avrami theory of phase change was introduced to describe the experimental data. The functions of a curing degree with light intensity and exposure time were achieved, respectively.

For semicrystalline thermoplastics, aside from pressure and shear, the temperature-time behavior while cooling the melt significantly affects the geometry and degree of ordered structures (e.g., spherulite size, degree of crystallization, and crystal modification) and, as a consequence, the resulting global component properties. Previous research has shown that a higher isothermal holding temperature (e.g., mold temperature and chill-roll temperature) leads to the formation of more distinct ordered structures and, therefore, can lead to greater stiffness and strength. Nevertheless, isothermal holding time during manufacturing is typically not taken into account. In this paper, fast scanning calorimetry (FSC) measurements were taken using polypropylene to analyze the crystallization during idealized temperature-time profiles based on the dynamic temperature process and to investigate the crystallization behavior at different temperatures and isothermal holding times analytically. Furthermore, iPP foils were extruded and tested mechanically to investigate the knowledge gained experimentally. Analytical and mechanical results show that foils produced at the same isothermal holding temperature can obtain significantly different ordered structures and mechanical properties depending primarily on the isothermal holding time.

In this research, the effects of fumed silica (FS) on the Ultraviolet (UV)-ink rheological behavior and processing windows were discussed. Objects using different concentrations of FS inks were printed by the modified UV-Direct ink writing (DIW) printer. The function of fumed silica in the ink-based system has been verified, and the processing scope has been expended with a suitable amount of FS combined with the UV light. The results show that the combination of a suitable amount of FS with the UV-DIW system reaches fast and accurate printing with a larger processing window compared to the non-UV system. However, an excessively high concentration of FS will increase the yield stress of the ink, which also increases the requirement of extrusion unit and the die-swelling effects.

A new expandable graphite (EG) type was studied as a flame retardant additive in Polyamide 6 (PA6). The fire behavior was characterized by a cone calorimeter using external heat fluxes of 35, 50 and 65 kW/m², limiting the oxygen index (LOI) and UL-94 burning tests. Additionally, electric and thermal conductivity as well as rheological properties were characterized to provide a general property overview. Fire tests were conducted using dry and humid conditioned samples. Cone Calorimeter tests showed a minimum filling degree of 15 wt.% (8.6 vol.%) EG was required to achieve a significant fire inhibiting effect in PA6 independent of the sample condition. UL-94 fire tests show a V0 classification at filling degrees greater than 20 wt.% (humid) and 25 wt.% (dry), although the associated LOI values of 39% and 38% demonstrate good flammability inhibition. Correlation analyses were conducted to identify major influences given by the sample condition for most important key figures measured in cone calorimeter tests. Accordingly, humid-conditioned samples containing between 2.5 (PA6 + 25 wt.% EG) and 4.2 wt.% (PA6) water were found to reduce the total heat evolved (THE) on average by 16% and the total smoke production (TSP) on average by 22%.

Mechanical and geometrical properties of parts produced by selective beam melting of thermoplastic powders depend on a large extend on interactions between following process and material parameters: Powder coating, geometry exposure and material behavior in solid and molten state. Consequently for demands of series production critical process repeatability only can be improved by fundamental studies of mentioned interactions. The following article analyzes first part density distribution for varying exposure parameters. In a second step results are correlated with typical parameters of the powder coating process during additive part generation. Furthermore part volume as well as part weight are taken into account. Result is a basic understanding of interactions between considered parameters

Powder Bed Fusion of Polymers (PBF-LB/P) is a layer-wise additive manufacturing process that predominantly relies on the quasi-isothermal processing of semi-crystalline polymers, inherently limiting the spectrum of polymers suitable for quasi-isothermal PBF. Within the present paper, a novel approach for extending the isothermal processing window towards significantly lower temperatures by applying the quasi-simultaneous laser-based exposure of fractal scan paths is proposed. The proposed approach is based on the temporal and spatial discretization of the melting and subsequent crystallization of semi-crystalline thermoplastics, hence allowing for the mesoscale compensation of crystallization shrinkage of distinct segments. Using thermographic monitoring, a homogenous temperature increase of discrete exposed sub-segments, limited thermal interference of distinct segments, and the resulting avoidance of curling and warping can be observed. Manufactured parts exhibit a dense and lamellar part morphology with a nano-scale semi-crystalline structure. The presented approach represents a novel methodology that allows for significantly reducing energy consumption, process preparation times and temperature-induced material aging in PBF-LB/P while representing the foundation for the processing of novel, thermo-sensitive material systems in PBF-LB/P.