A CoCrCuFeNiTi0.8 high-entropy alloy was prepared using directional solidification techniques at different withdrawal rates (50 μm/s, 100 μm/s, 500 μm/s). The results showed that the microstructure was dendritic at all withdrawal rates. As the withdrawal rate increased, the dendrite orientation become uniform. Additionally, the accumulation of Cr and Ti elements at the solid/liquid interface caused the formation of dendrites. Through the measurement of the primary dendrite spacing (λ1) and the secondary dendrite spacing (λ2), it was concluded that the dendrite structure was obviously refined with the increase in the withdrawal rate to 500 μm/s. The maximum compressive strength reached 1449.8 MPa, and the maximum hardness was 520 HV. Moreover, the plastic strain of the alloy without directional solidification was 2.11%, while the plastic strain of directional solidification was 12.57% at 500 μm/s. It has been proved that directional solidification technology can effectively improve the mechanical properties of the CoCrCuFeNiTi0.8 high-entropy alloy.
Diffusion reaction was a crucial route to enhance the wear resistance of Ti-6Al-4V alloys surface. In this work, the Ni/Cu/Ni composite layers were fabricated on the surface of Ti-6Al-4V alloy by electroplate craft, and then different annealing temperatures were applied to further optimize its tribological properties. The diffusion behaviors at various temperatures were systematically analyzed to reveal the physical mechanism of the enhanced tribological properties of the coatings. It was demonstrated that CuxTiy and NixTiy intermetallic compounds with high hardness and strength were produced in the Ni/Cu/Ni coating, which acted as the reinforcing phases and improved the microhardness, reduced the friction coefficient, and lessened the wear rate. Specially, this effect reached the maximum when the annealing temperature was 800 °C, showing excellent wear resistance. This work revealed the relationship between annealing temperatures and tribological properties of the Ni/Cu/Ni coating, and proposed wear mechanism, aiming to improve the surface performance of Ti-6Al-4V alloy by appropriate diffusion behavior.
The poor surface performance of titanium alloys substantially limits their application in many fields, such as the petrochemical industry. To overcome this weakness, the Cu and Ni double layers were deposited on the surface of TC4 alloy by the electroplating method, and the isothermal diffusion process was performed at 700 °C to enhance the binding ability between Cu and Ni layers. The isothermal diffusion behavior and microstructure of the coating were systematically analyzed, and tribological property and corrosion resistance of the coating were also evaluated to reveal the influence of isothermal diffusion on the surface performance. It was shown that multiple diffusion layers appeared on the Cu/Ni and Ni/Ti interface, and that NixTiy and CuxTiy phases were formed in the coating with the increase of diffusion time. More importantly, Kirkendall diffusion occurred when the diffusion time increased, which led to the formation of continuous microvoids and cracks in the diffusion layer, weakening the surface performance of the Cu/Ni coatings. This paper unveils the relationship between the microstructure of the Cu/Ni coatings and isothermal diffusion behavior, providing guidelines in preparing high performance surface coatings.
Girth welds are weak points in pipelines, and failures occur frequently. In a gas transmission pipeline, a girth weld experienced cracking, prompting a failure analysis using experimental methods and finite element analysis (FEA). Experimental results showed that X-ray non-destructive testing (NDT) revealed cracks, porosity, and lack of fusion in the girth weld. However, the hardness and microstructure of the material showed no abnormalities. During operation, the pipeline experienced an increase in soil cover and was subjected to ground subsidence and vehicle loads. Finite element analysis was conducted on the defective girth weld under different conditions, including varying soil cover depths, different levels of subsidence, and varying vehicle loads, to examine the pipeline’s stress response. The results indicated that the combination of soil cover, subsidence, and vehicle loads led to pipeline failure, whereas none of these factors alone was sufficient to cause girth weld failure. To prevent such failures from occurring again, the following measures are recommended: strengthen on-site welding quality control of girth welds, conduct inspections for defects in girth welds of in-service pipelines, and promptly address any defects that exceed acceptable limits.
The integrity of oil and gas pipelines is critical to energy transportation and has significant implications for national energy security. This study employs finite-element numerical simulation to investigate the impact of multiple repairs on the microstructure and mechanical integrity of X80 pipeline girth welds. The effects of varying repair iterations on the microstructure, toughness, and loading capacity of high-strength steel pipes were analyzed. The results revealed that the microstructure of the welded joint remained unchanged across different repair instances, but the toughness, optimized by welding heat input, diminished after three repairs due to grain growth from repeated thermal cycles. Specifically, the impact toughness of the welding line, fusion line, and adjacent areas decreased significantly after three repairs, with the toughness of the welding line dropping to 25 J and the fusion line dropping to 30 J. The hardness of the welded joint decreased with repairs, and the dispersion of hardness increased. The average hardness at the welding line decreased from 25 HV to 20 HV after three repairs. Residual stress in the repaired girth weld was highest in the filling welding layer, increasing with the number of repairs. The loading capacity of the girth weld significantly decreased after the first repair (by 12.1%) and continued to decrease with additional repairs (15.3% after the second repair and 16.7% after the third repair). It is concluded that X80 pipeline girth welds should be repaired no more than twice to maintain optimal structural integrity.
An unstable assembly gap is detrimental to the formation and performance of the pipeline butt girth weld joint. Therefore, a numerical model of an 18.4 mm-thick X80 pipeline girth weld by a homogeneous body heat source was established to investigate the effect of the butt gap on the joint temperature and stress field, and carrying capacity. The accuracy of the simulation results was verified by measuring the welding thermal cycle with a thermocouple. The investigation results showed that the weld pool, heat-affected zone (HAZ) width, and maximum circumferential stress of the joint rose with the increase in the butt gap. The tensile stress unfavorable to the joint quality was mainly distributed in the weld metal and partial HAZ, and the distribution areas gradually expanded as the gap increased. The Von Mises stress peak value of the joint appeared in the order of 3 mm > 2 mm > 1 mm > 0 mm gap, reaching the maximum of 467.3 MPa (3 mm gap). This variation trend is directly related to the improvement in welding heat input with increasing butt gaps. The maximum Von Mises stress of the joint was positively correlated with the carrying capacity of the pipeline, which diminished as the butt gap enlarged. The pipeline carrying capacity reached 17.8 MPa for the joint with no butt gap, and dropped to 13.1 MPa for the joint with a 3 mm gap. The relationship between the carrying capacity (P) and butt gap (C) was described by P = −0.125C2 − 1.135C + 17.715, through which the pipeline carrying capacity with other butt gaps can be predicted.
About Me
Zhu Lixia specializes in the field of dynamic and intelligent safety technologies for oil and gas pipelines.
Zhu Lixia specializes in the field of dynamic and intelligent safety technologies for oil and gas pipelines.