Transparent conducting electrode film is highly desirable for application in touch screen panels (TSPs), flexible and wearable displays, sensors, and actuators. A sputtered film of indium tin oxide (ITO) shows high transmittance (90%) at low sheet resistance (50 Ω/cm2). However, ITO films lack mechanical flexibility, especially under bending stress, and have limitation in application to large-area TSPs (over 15 inches) due to the trade-off in high transmittance and low sheet resistance properties. One promising solution is to use metal mesh-type transparent conducting film, especially for touch panel application. In this work, we investigated such inter-related issues as UV imprinting process to make a trench layer pattern, the synthesis of core-shell-type Ag and Cu@Ag composite nanoparticles and their paste formulation, the filling of Ag and Cu@Ag mixture nanoparticle paste to the trench layer, and touch panel fabrication processes.
This study compares the characteristics and low-temperature curing properties of pastes prepared from silver (Ag) powders synthesized by either wet powder (WP) or dry powder (DP) processing. The WP synthesis of electrode particles has the advantage of controlling the average particle size and particle size distribution but the disadvantage of producing low-purity, crystalline particles because they are synthesized through chemical reduction at less than 100 °C. Conversely, the DP synthesis of electrode particles has the advantage of producing pure, highly crystalline particles (due to synthesis at high temperatures) but the disadvantage of a high processing cost. WP and DP were used to manufacture pastes for low-temperature curing, and the physical properties of the pastes and the electrode characteristics after low-temperature curing were compared between powder types. Shear stress as a function of the shear rate shows that the WP paste is a plastic fluid, whereas the DP paste is a pseudoplastic fluid, closer to a Newtonian fluid. Screen printing the Ag pastes and curing for 30 min at 130 °C produces a nonconductive WP paste, whereas it produces a DP paste with a conductivity of 61 mΩ/sq, indicating that the highly crystalline DP paste is advantageous for low-temperature curing.
In this study, we investigate the electrochemical properties of a nickel oxide-carbon (NiO/C) material, synthesized in the form of highly porous carbon nanofibers through the electrospinning of polymers such as polyacrylonitrile (PAN) and polystyrene (PS) followed by a carbonization process. The primary focus of this work is to determine the optimal mixing ratio for the hybrid material composed of NiO and carbon. While it is widely acknowledged that supercapacitor materials benefit from having a high specific surface area, our findings reveal that hybrid carbon nanofibers with a 45% specific carbon-to-nickel oxide ratio exhibit significantly enhanced capacitance (39.9 F g−1). This outcome suggests the promising potential of our materials as an energy storage material for hybrid supercapacitors, combining the advantages of electric double-layer capacitors (EDLC) and Pseudo capacitors (Pseudo).
25 March 2025 in International Journal of Precision Engineering and Manufacturing-Green Technology
Integrating electronics into three-dimensional devices represents a significant advancement. There are two primary methods for manufacturing 3D electronic products: creating the curved product first and then applying printed electrodes by the non-contact printing method, or printing conductive patterns first on a film, followed by thermoforming. In this study, the latter method was chosen for its ease of manufacturing, cost-effectiveness, scalability, and ability to produce detailed patterns. The previous methods of manufacturing In-mold Electronics (IME) via thermoforming often introduce defects (cracks) that affect circuit conductivity. To fabricate a 3D IME-LED array, screen printing and thermoforming on a Polyethylene Terephthalate Glycol (PETG) substrate was utilized. For the reduction of conduction issues, a silver paste with a polyester resin (thermoplastic) binder was employed. Results demonstrated that the 3D IME circuit demonstrated elongation in length ranging from 5.9 to 6.7% before and after thermoforming, confirming its stretchability. Under optimal temperature of 110 °C and a vacuum level of – 3 psi, resistance decreased by 18%. Additionally, printed lines with a minimal width of 100 μm became conductive following this technique. This was achieved by taking advantage of the paste’s sintering and viscoelastic characteristics during the thermoforming process. This experiment demonstrates a novel approach to integrating electronics into 3D structures, providing valuable insights into the field of IME.
Efficient, stretchable wiring electrodes are achieved when the resistance change during expansion and contraction is minimal. Herein, we prepared silver pastes specifically designed for screen printing on thermoplastic polyurethane films; they exhibit minimal resistance changes. The pastes were prepared using silver particles with sizes of 2 and 7 μm as well as a mixture of 2 and 7 μm silver particles (50:50 wt%). These pastes were analyzed using methods such as rheological measurements, thermogravimetric analysis, printability tests, tensile and torsion tests, and light-emitting diode (LED) tests. The most promising results were obtained when exclusively using 2 μm silver flake particles. The pastes demonstrated a viscosity of 24,880 cps, a thixotropic index value of 2.82, excellent printability, and consistent resistance measurements even after 100% stretch, thus indicating exceptional tensile properties. Moreover, the pastes exhibited substantial stability, with no change in brightness after the attachment of seven LEDs at 20% tension.
28 February 2018 in Journal of Power System Engineering