Broadband metamaterial absorbers (MAs) are critical for applications of photonic and optoelectronic devices. Despite long-standing efforts on broadband MAs, it has been challenging to achieve ultrabroadband absorption with high absorptivity and omnidirectional characteristics within a comparatively simple and low-cost architecture. Here we design, fabricate, and characterize a novel compact Cr-based MA to achieve ultrabroadband absorption in the visible to near-infrared wavelength region. The Cr-based MA consists of Cr nanorods and Cr substrate sandwiched by three pairs of SiO2/Cr stacks. Both simulated and experimental results show that an average absorption over 93.7% can be achieved in the range of 400–1000 nm. Specifically, the ultrabroadband features result from the co-excitations of localized surface plasmon (LSP) and propagating surface plasmon (PSP) and their synergistic absorption effects, where absorption in the shorter and longer wavelengths are mainly contributed bythe LSP and PSP modes, respectively. The Cr-based MA is very robust to variations of the geometrical parameters, and angle-and polarization-insensitive absorption can be operated well over a large range of anglesunder both transverse magnetic(TM)- and transverse electric (TE)-polarized light illumination.
This research delves into the corrosion resistance and wear behavior of Ni60-based composite coatings strengthened by TiC and NbC particles, which are produced by laser cladding. Three distinct coatings were prepared: S1 (Ni60 + 20%TiC), S2 (Ni60 + 10%TiC + 10%NbC), and S3 (Ni60 + 20%NbC). Microstructural characterization revealed that the addition of TiC and NbC altered phase composition, inducing lattice distortion and promoting the formation of carbides such as Cr7C3, Ni3C, and Nb2C. The S2 coating exhibited the highest average microhardness (1045 HV) due to synergistic grain refinement and homogeneous carbide dispersion. Wear resistance followed the order S2 > S3 > S1, attributed to the optimized balance of hard-phase distribution and reduced abrasive wear. Electrochemical tests in 3.5 wt% NaCl solution demonstrated superior corrosion resistance for S3, characterized by the lowest corrosion current density (1.732 × 10−6 A/cm2) and a stable passivation film, facilitated by NbC-induced oxide formation. While S2 achieved peak mechanical performance, S3 excelled in corrosion resistance, highlighting the trade-off between carbide reinforcement and electrochemical stability. This work underscores the potential of tailoring dual-carbide systems in Ni60 coatings to enhance durability in harsh environments.
The influence of nodule defects on the characteristics of femtosecond laser-induced damage has not been fully investigated. In this study, two types of 800 nm/1064 nm dual-band high-reflection films with different configurations were analyzed. Combined with finite-difference time-domain electric field simulation and focused ion beam analysis, the initial state and growth process of femtosecond laser damage of nodules were explored. In particular, the sequence of blister damage determined by the film design and the inner damage caused by nodules were clarified. The rule of the laser-induced damage threshold of different size nodules was obtained. The difference in the damage behavior of nodules in the two types of films was elucidated.
CoCrFeNiMn high-entropy alloy (HEA) composite coatings with 0, 10, and 20 wt% TiC are synthesized through laser cladding technology, and their corrosion and wear resistance are systematically investigated. The X-ray diffraction (XRD) results show that with the addition of TiC, the phases of TiC and M23C6 are introduced, and lattice distortion occurs simultaneously (accompanied by the broadening and leftward shift of the main Face-Centered Cubic (FCC) peak). Scanning electron microscopy (SEM) reveals that the incompletely melted TiC particles in the coating (S2) are uniformly distributed in the matrix with 20 wt% TiC, while in the coating (S1) with 10 wt% TiC, due to gravitational sedimentation and decomposition during laser processing, the distribution of the reinforcing phase is insufficient. When rubbed against Si3N4, with the addition of TiC, S2 exhibits the lowest friction coefficient of 0.699 and wear volume of 0.0398 mm3. The corrosion resistance of S2 is more prominent in the simulated seawater (3.5 wt% NaCl). S2 shows the best corrosion resistance: it has the largest self-corrosion voltage (−0.425 V vs. SCE), the lowest self-corrosion current density (1.119 × 10−7 A/cm2), and exhibits stable passivation behavior with a wide passivation region. Electrochemical impedance spectroscopy (EIS) confirms that its passivation film is denser. This study shows that the addition of 20 wt% TiC optimizes the microstructural homogeneity and synergistically enhances the mechanical strengthening and electrochemical stability of the coating, providing a new strategy for the making of HEA-based layers in harsh wear-corrosion coupling environments.
3 June 2024 in High Power Laser Science and Engineering
This paper systematically investigated the impact mechanisms of proton irradiation, atomic oxygen irradiation and space debris collision, both individually and in combination, on the laser damage threshold and damage evolution characteristics of HfO2/SiO2 triple-band high-reflection films and fused silica substrates using a simulated near-Earth space radiation experimental system. For the high-reflection film samples, the damage thresholds decreased by 15.38%, 13.12% and 46.80% after proton, atomic oxygen and simulated space debris (penetration) irradiation, respectively. The coupling irradiation of the first two factors resulted in a decrease of 26.93%, while the combined effect of all the three factors led to a reduction of 63.19%. Similarly, the fused silica substrates exhibited the same pattern of laser damage performance degradation. Notably, the study employed high-precision fixed-point in situ measurement techniques to track in detail the microstructural changes, surface roughness and optical-thermal absorption intensity before and after proton and atomic oxygen irradiation at the same location, thus providing a more accurate and comprehensive analysis of the damage mechanisms. In addition, simulations were conducted to quantitatively analyze the transmission trajectories and concentration distribution lines of protons and atomic oxygen incident at specific angles into the target material. The research findings contribute to elucidating the laser damage performance degradation mechanism of transmissive elements in near-Earth space environments and provide technical support for the development of high-damage-threshold optical components resistant to space radiation.
Hf1−xSixO2 nanocomposites with different SiO2 doping ratios were synthesized using an ion-assisted co-evaporation process to achieve dense amorphous Hf1−xSixO2 coatings with low loss and a high laser-induced damage threshold (LIDT). The results showed that the Hf1−xSixO2 nanocomposites (x ≥ 0.20) exhibited excellent comprehensive performance with a wide band gap and a dense amorphous microstructure. High-temperature annealing was carried out to ensure better stoichiometry and lower absorption. Precipitation and regrowth of HfO2 grains were observed from 400 °C to 600 °C during annealing of the Hf0.80Si0.20O2 nanocomposites, resulting in excessive surface roughness. A phenomenological model was proposed to explain the phenomenon. The Hf1−xSixO2 nanocomposites (x = 0.3 and 0.4) maintained a dense amorphous structure with low absorption after annealing. Finally, a 1064-nm Hf0.70Si0.30O2/SiO2 high-performance reflector was prepared and achieved low optical loss (15.1 ppm) and a high LIDT (67 J/cm2).