Plastics have become an essential part of our daily lives, and global plastic production has increased dramatically in the past 50 years. This has significantly increased the amount of plastic garbage produced. Researchers have recently been interested in using trash and recyclable plastics in concrete as an ecologically acceptable building material. A large number of publications have been published that describe the behavior of concrete, containing waste and recovered plastic com ponents. However, information is scattered, and no one knows how plastic trash behaves as concrete materials. This research examines the use of plastic waste (PW) as aggregate or fiber in cement mortar and concrete manufacturing. The article reviewed the three most significant features of concrete: fresh properties, mechanical strength, and durability. PW and cement connections were also studied using microstructure analysis (scan electronic microscopy). The results showed that PW, as a fiber, enhanced mechanical performance, but PW, as a coarse aggregate, impaired concrete performance owing to poor bonding. The assessment also identified research needs in order to enhance the performance of PW-based concrete in the future.

The efficiency of Azadirachta indica (neem leaves) on the removal of Pb(II) ions by adsorption from aqueous solution was investigated in this study. The efficiency of these leaves (without chemical or thermal treatment) for the adsorption of Pb(II) ions has not previously been reported. Batch experiments were performed to study the effect of the particle size, pH, adsorbent dose, contact time, initial Pb(II) ion concentration, and temperature. The maximum removal of 93.5% was achieved from an original Pb(II) ion solution concentration of 50 mg/L after 40 min, at pH 7, with 0.60 g of an adsorbent dose. The maximum adsorption capacity recorded was 39.7 mg/g. The adsorption process was also studied by examining Langmuir, Freundlich, Temkin isotherm, and Dubinin–Radushkevich (D-R) isotherm models. The results revealed that the adsorption system follows the pseudo-second-order model and fitted the Freundlich model. Several thermodynamic factors, namely, the standard free energy (∆G°), enthalpy (∆H°), and entropy (∆S°) changes, were also calculated. The results demonstrated that the adsorption is a spontaneous, physical, and exothermic process. The surface area, pore size, and volume of adsorbent particles were measured and presented using a surface area analyzer (BET); the morphology was scanned and presented with the scanning electron microscope technique (SEM); and the functional groups were investigated using μ-FTIR.

For the sustainability of the construction industry, geopolymers (GPMs) play an important role compared with Portland cement due to their improved mechanical properties, enhanced durability, and outstanding performance in alkali and acidic conditions. Most of the previous review investigations explored the general behavior of GPM developed with kaolin, silica fume (SF), rice husk ash, ground granulated blast furnace slag, fly ash,etc., but a comprehensive review study on the industrial by-products, including granite waste powder (GWP) and bauxite residue (BR), is required to investigate their suitability in the construction industry. The current investigation aims to present a detailed review of the fresh, mechanical, durability, and microstructural behavior of the GPM paste produced using BR and GWP from the literature. The effect of different ingredients and testing conditions are evaluated for the fresh, mechanical, durability, thermal, and microstructural performance of the GPM paste. The results indicate that the pure BR having a lower ratio of SiO₂/Al₂O₃reacts poorly; therefore, it should be blended with other aluminosilicates comprising a higher ratio of SiO₂/Al₂O₃for better geopolymerization. Pre-activation of BR including 3 h calcination at 800°C, 1 h thermal pretreatment of alkali with solid activators at 800°C, mechanical co-grinding, and pulverization presented improved strength and microstructural properties of GPM. When mixing GWP in large quantities, heat curing is preferred for 8 h at 60–80°C for better behavior of GPM. Incorporating the nanomaterials into GWP-based GPM showed a significant impact on initial compressive and tensile strengths. Further studies on the synergistic use of GWP with aluminosilicate products and BR with silica-rich pozzolanic ingredients for GPM are required. Improved physiochemical features of BR-GPM and GWP-GPM are the potential research areas that can be addressed by incorporating raw materials for enhancing the internal matrix, such as nanoparticles, bio-additives, micro-fibers,etc., that have been observed to be effective for the GPM pastes.

Adsorption investigations in batch approaches were performed to explore the biosorption of Ni(II) ions from aqueous solutions on date seeds powder. The effects of pH, particle size, initial concentration of Ni(II) ions, adsorbent mass, temperature, and contact on the adsorption efficacy were studied. The maximum removal obtained was 90% for an original Ni(II) ion solution concentration of 50 ppm was attained at pH 7 after 30 min and with 0.30 g of an added adsorbent. The four adsorption models, namely Freundlich, Langmuir, Dubinin–Radushkevich (D–R), and Temkin were examined to fit the experimental findings. The adsorption system obeys the Freundlich model. The system was found to follow the pseudo-second order kinetic model. Thermodynamic factors; entropy (ΔS°), enthalpy (ΔH°), and Gibbs free energy (ΔG°) changes were also assessed. Results proved that adsorption of Ni(II) ions is exothermic and spontaneous. Sticking probability value was found to be less than unity, concluding that the process is dominated by physical adsorption.

In this study, the effect of micro-carbon fiber on the properties of concrete incorporating recycled coarse aggregate at three different levels, i.e., 0%, 50%, and 100% by volume replacement of natural coarse aggregate, was studied. Carbon fiber was incorporated at a dosage of 0.5% by volume fraction. The effect of silica fume or micro-silica on the efficacy of fiber reinforcement was also investigated. Studied parameters include important mechanical properties, such as compressive strength, splitting tensile strength, and flexural strength, and physical/quality parameters such as water absorption capacity and ultrasonic pulse velocity. The results showed that the mechanical and durability performance deteriorates with the increasing percentage of recycled coarse aggregate. Carbon fiber can significantly improve the tensile properties of recycled aggregate concrete. The combination of carbon fiber and silica fume proved to be highly useful in addressing both mechanical and durability concerns simultaneously. Concrete made with 50% recycled coarse aggregate, 8% silica fume, and 0.5% carbon fiber yielded 20% greater tensile and flexural strength compared to the control mix. Likewise, concrete containing 100% recycled coarse aggregate with silica fume and carbon fiber yielded higher tensile strength compared to the control mix. Silica fume ameliorated the bonding between fibers and matrix and improved the overall efficacy of fiber reinforcement.