Silicone rubber is widely used as an insulating material. In this article, silicone rubber samples were prepared by varying the content of crosslinker (2,5-bis(tert-butyl-peroxy)-2,5-dimethylhexane, DBPMH), and the free volume holes in the samples were investigated by means of positron annihilation lifetime spectroscopy (PALS) measurement. The surface chemical structure, surface micromorphology and water diffusion of the samples after corona discharge treatment were studied by FTIR, SEM and EIS measurements, respectively. As the crosslinker weight ratio increased from 0.2 wt.% to 1.5 wt.%, the mean free volume hole size first decreased and then remained unchanged. However, the concentration of free volume holes did not vary as the crosslinker weight ratio increased. SEM morphologies show that surface cracks were produced on samples having high crosslinking levels after corona treatment. The water diffusion coefficient of samples after corona treatment increased from 3.13 × 10⁻¹⁰ cm² s⁻¹ to 17.68 × 10⁻¹⁰ cm² s⁻¹ in the initial immersion period, as the crosslinker weight ratio increased from 0.2 wt.% to 3.0 wt.%. The results indicated that deterioration of samples with high crosslinking levels were more serious and water repellency more easily lost. The corona resistance ability of low crosslinking level silicone rubber stems from internal low molecular weight molecules.

In this study, silicone rubber (SiR) with 0, 90, and 180 parts of aluminum hydroxide (Al(OH)₃, ATH) contents prepared in the laboratory was treated in a certain concentration of NO₂ for 0, 12, 24, and 36 h. Fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and thermogravimetry (TG) were used to study the changes in the surface structure and thermal stability of SiR, as well as the influence of Al(OH)₃ on the properties of SiR. According to AFM, the root-mean-square roughness of ATH-90 SiR was 192 nm, which was 2.7 times of ATH-0 SiR. With the incorporation of ATH, the surface of SiR became more susceptible to corrosion by NO₂. According to FT-IR and XPS, with the increase in aging time, the side chain Si-CH₃ of polydimethylsiloxane (PDMS) was oxidized gradually and a few of nitroso -NO₂ groups were formed. According to TG, the incorporation of ATH caused the maximum decomposition rate temperature of PDMS to advance from 458.65 °C to 449.37 and 449.26 °C, which shows that the thermal stability of SiR degraded by adding ATH. After NO₂ aging, a new decomposition stage appeared between 75 and 220 °C (stage Ⅰ), and this decomposition trend was similar to aluminum nitrate, which was proven to reduce the thermal stability of PDMS. The effects of NO₂ on the surface structure and thermal stability of different ATH contents of silicone rubber were preliminarily clarified by a variety of characterization methods, which provided ideas for the development of silicone rubber resistant to NO₂ aging.

Enhancing the corona resistance of epoxy resin (EP) is crucial for ensuring the reliable operation of electrical equipment and power systems, and the incorporation of inorganic nanofillers into epoxy resin has shown significant potential in achieving this. In this study, functionalized graphene oxide (KHGO) was synthesized via a sol-gel method to enhance the corona resistance of EP with electrochemical impedance spectroscopy (EIS) used to assess the properties of KHGO/EP composites. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) verified the successful grafting of epoxy groups onto the GO surface. The thermal conductivity and stability of the KHGO/EP composite initially increased with KHGO content but declined when the content exceeded 1.2 wt.%. Positron annihilation lifetime spectroscopy (PALS) indicated that KHGO improved interfacial compatibility with EP compared to GO, with agglomeration occurring when KHGO content exceeded a threshold value (1.2 wt.%). EIS analysis revealed that the corona resistance of the KHGO/EP composite was optimal at a filler content of 0.9 wt.%. After corona treatment, the saturation water uptake of the 0.9 wt.% KHGO/EP composite decreased by 15% compared to pure EP with its porosity reduced to just 1/40th of that of pure EP. This study underscores that well-dispersed KHGO/EP composite exhibits excellent corona resistance property suggesting the potential for industrial applications in high-voltage equipment insulation.

In SF₆ gas-insulated equipment, solid dielectrics critically degrade insulation performance by reducing the electric field’s ability to withstand gas gaps. To investigate the critical role played by solid dielectric surfaces during the initial phase of gas–solid interface discharge phenomena, this paper experimentally measures the AC breakdown voltage (U_bd) of both dielectric surface-initiated breakdown (DIBD) and electrode surface-initiated breakdown (EIBD) across eight types of post insulator samples. Tests are conducted in 36 mm SF₆ gas gaps under pressures ranging from 0.1 to 0.4 MPa. Combined with electrostatic field simulations, the results reveal that DIBD requires substantially lower U_bd than EIBD under comparable maximum electric field (E_max) conditions. As gas pressure increases, this difference becomes more pronounced. This phenomenon can be explained by three key mechanisms: First, due to the regulatory effect of dielectric materials and shielding electrodes on the electric field distribution, the high-electric-field zone along the gas–solid interface exhibits a longer effective discharge path compared to that in a pure gas gap. This configuration creates more favorable conditions for discharge initiation and subsequent propagation toward the opposite electrode. Second, microscopic irregularities on the dielectric surface induce stronger local electric field enhancement than comparable features on metallic electrodes. Third, in high-electric-field regions adjacent to the dielectric surface, desorption processes significantly enhance electron multiplication during gas discharge, and this enhancement effect becomes more pronounced as gas pressure increases, further lowering the discharge inception threshold. As a result, discharge initiation at dielectric interfaces requires less stringent electric field conditions compared to breakdown in a gas gap, especially at high gas pressure. This conclusion not only accounts for the saturation behavior in the U_bd-p characteristic of SF₆ gas–solid interface discharges but also explains why surface contaminants/defects disproportionately degrade interfacial insulation performance relative to their impact on gas gaps.

Cross-linked polyethylene (XLPE) has been widely used in high-voltage cables due to its superior properties, but its thermoset cross-linked structure makes it difficult to recycle. Catalytic pyrolysis offers a feasible pathway for converting XLPE into high-value chemicals. In this study, a systematic study on the catalytic cracking of XLPE using metal ion-loaded ZSM-5 nanosheets was conducted, and ZSM-5 nanosheets loaded with Ag, Mo, Ni, and Ce were prepared via ion exchange. After metal loading, ZSM-5 retained the MFI framework structure, but the specific surface area and mesopore volume varied depending on the type of metal. Temperature-Programmed Desorption of Ammonia results indicated that metal–support interactions enhanced the acidity of ZSM-5. Among the catalysts, Ag-loaded ZSM-5 exhibited the highest efficiency: with 10 wt% Ag, at 380 °C, the conversion reached 94.1%, with 52.5% light olefins in the gas phase and 59.4% benzene, toluene, and xylene (BTX) in the liquid products. Further studies on different Ag loadings revealed that moderate Ag loading (5 wt%) provided the best overall balance, maintaining 92.3% conversion, 56.1% selectivity to light olefins, and 58.2% BTX in the liquid fraction. These findings demonstrate that tuning the metal loading effectively optimizes the acidity and pore structure of ZSM-5, thereby enabling controlled regulation of XLPE pyrolysis product distribution.

In this study, functional graphene oxide (f-GO) nanosheets were prepared to enhance the NO₂ resistibility of room-temperature-vulcanized (RTV) silicone rubber. A nitrogen dioxide (NO₂) accelerated aging experiment was designed to simulate the aging process of nitrogen oxide produced by corona discharge on a silicone rubber composite coating, and then electrochemical impedance spectroscopy (EIS) was used to test the process of conductive medium penetration into silicone rubber. After exposure to the same concentration (115 mg·L⁻¹) of NO₂ for 24 h, at an optimal filler content of 0.3 wt.%, the impedance modulus of the composite silicone rubber sample was 1.8 × 10⁷ Ω·cm², which is an order of magnitude higher than that of pure RTV. In addition, with an increase in filler content, the porosity of the coating decreases. When the content of the nanosheet increases to 0.3 wt.%; the porosity reaches a minimum value 0.97 × 10⁻⁴%, which is 1/4 of the porosity of the pure RTV coating, indicating that this composite silicone rubber sample has the best resistance to NO₂ aging.