Nitrogen is used as an alloying element, substituting the expensive and allergenic element nickel, in austenitic stainless steels to improve their mechanical properties and corrosion resistance. The development of austenitic stainless steel powders with increased nitrogen content for laser additive manufacturing has recently received great interest. To increase nitrogen content in the austenitic steel powders (for example AISI 316L), two measures are taken in this study: (1) melting the steel under a nitrogen atmosphere, and (2) adding manganese to increase the solubility of nitrogen in the steel. The steel melt is then atomized by means of gas atomization (with either nitrogen or argon). The resulting powders are examined and characterized with regard to nitrogen content, particle size distribution, particle shape, microstructure, and flowability. It shows that about 0.2–0.3 mass % nitrogen can be added to the austenitic stainless steel 316L by adding manganese and melting the steel under nitrogen atmosphere. The particles are spherical in shape and very few satellite particles are observed. The steel powders show good flowability and packing density, therefore they can be successfully processed by means of laser powder bed fusion (L-PBF).

Duplex stainless steel powders for laser additive manufacturing have not been developed extensively. In this study, the melts of a super duplex stainless steel X2CrNiMoCuWN25-7-4 (AISI F55, 1.4501) were atomized with different process gases (Ar or N₂) at different atomization gas temperatures. The process gas N₂ in the melting chamber leads to a higher nitrogen dissolution in the steel and a higher nitrogen content of the atomized powders. The argon-atomized powders have more gas porosity inside the particles than the nitrogen-atomized powders. In addition, the higher the atomization gas temperature, the finer the powder particles. The duplex stainless steel powders showed good processability during PBF-LB/M (Laser powder bed fusion). The gas entrapment in the powder particles, regardless of the gas chemistry and the gas content, appears to have a negligible effect on the porosity of the as-built parts.