We review epitaxial formation, basic properties, and device applications of a novel type of nanostructures of mixed (0D/2D) dimensionality that we refer to as quantum well-dots (QWDs). QWDs are formed by metalorganic vapor phase epitaxial deposition of 4–16 monolayers of In_xGa_1−xAs of moderate indium composition (0.3 < x < 0.5) on GaAs substrates and represent dense arrays of carrier localizing indium-rich regions inside In-depleted residual quantum wells. QWDs are intermediate in properties between 2D quantum wells and 0D quantum dots and show some advantages of both of those. In particular, they offer high optical gain/absorption coefficients as well as reduced carrier diffusion in the plane of the active region. Edge-emitting QWD lasers demonstrate low internal loss of 0.7 cm⁻¹ and high internal quantum efficiency of 87%. as well as a reasonably high level of continuous wave (CW) power at room temperature. Due to the high optical gain and suppressed non-radiative recombination at processed sidewalls, QWDs are especially advantageous for microlasers. Thirty-one μm in diameter microdisk lasers show a high record for this type of devices output power of 18 mW. The CW lasing is observed up to 110 °C. A maximum 3-dB modulation bandwidth of 6.7 GHz is measured in the 23 μm in diameter microdisks operating uncooled without a heatsink. The open eye diagram is observed up to 12.5 Gbit/s, and error-free 10 Gbit/s data transmission at 30 °C without using an external optical amplifier, and temperature stabilization is demonstrated.

In this study, exfoliated g-C₃N₄/NiO nanocomposites were synthesized by the heat treatment of urea and subsequent ultrasonic exfoliation of the colloidal solution with the introduction of nickel acetate.

Nanocrystals of gadolinium orthoferrite (GdFeO₃) with morphology close to isometric and superparamagnetic behavior were successfully synthesized using direct, reverse and microreactor co-precipitation of gadolinium and iron(III) hydroxides with their subsequent heat treatment in the air. The obtained samples were investigated by PXRD, FTIR, low-temperature nitrogen adsorption-desorption measurements, HRTEM, SAED, DRS and vibration magnetometry. According to the X-ray diffraction patterns, the GdFeO₃ nanocrystals obtained using direct co-precipitation have the smallest average size, while the GdFeO₃ nanocrystals obtained using reverse and microreactor co-precipitation have approximately the same average size. It was shown that the characteristic particle size values are much larger than the corresponding values of the average crystallite size, which indicates the aggregation of the obtained GdFeO₃ nanocrystals. The GdFeO₃ nanocrystals obtained using direct co-precipitation aggregate more than the GdFeO₃ nanocrystals obtained using reverse co-precipitation, which, in turn, tend to aggregate more strongly than the GdFeO₃ nanocrystals obtained using microreactor co-precipitation. The bandgap of the obtained GdFeO₃ nanocrystals decreases with decreasing crystallite size, which is apparently due to their aggregation. The colloidal solutions of the obtained GdFeO₃ nanocrystals with different concentrations were investigated by ¹H NMR to measure the T₁ and T₂ relaxation times. Based on the obtained r₂/r₁ ratios, the GdFeO₃ nanocrystals obtained using microreactor, direct and reverse co-precipitation may be classified as T₁, T₂ and T₁–T₂ dual-modal MRI contrast agents, respectively.

A novel ultra-high-entropy rare earth orthoferrite (UHE REO) of Sc_1/16Y_1/16La_1/16Ce_1/16Pr_1/16Nd_1/16Sm_1/16Eu_1/16Gd_1/16Tb_1/16Dy_1/16Ho_1/16Er_1/16Tm_1/16Yb_1/16Lu_1/16FeO₃ nominal composition was successfully synthesized for the first time through a simple and efficient solution combustion approach. PXRD, Raman, and ⁵⁷Fe Mössbauer spectroscopy confirmed the high chemical and phase purity of the synthesized UHE REO (hereafter denoted as ΣREFeO₃), which belonged to the Pnma space group, typical of the perovskite-like rare earth orthoferrites. Despite the fact that the main X-ray reflections, vibration modes, and spectral Mössbauer components unambiguously indicate the single-phase nature of the sample, the results of SEM and TEM make it possible to establish the presence of a main (about 50 nm) and a minor ultrafine (about 10 nm) fraction of ΣREFeO₃ nanoparticles. The bimodal size distribution of nanoparticles was also reflected in the magnetic behavior of this substance: the presence of several sextet components in the Mössbauer spectra, the hard single-domain magnetic nature of the main fraction of 50 nm UHE REO nanoparticles, and the superparamagnetic state of the minor fraction of 10 nm UHE REO nanoparticles. Thus, the unusual features of nanostructured ΣREFeO₃ can potentially be used for the creation of new generations of transformers, magnetic memory systems, magnetic screens, radio devices, etc.

Nanostructured hexagonal rare-earth orthoferrites (h-RfeO₃, R = Sc, Y, Tb-Lu) are well known as a highly effective base for visible-light-driven heterojunction photocatalysts. However, their application is limited by metastability, leading to difficulties in synthesis due to the irreversible transformation to a stable orthorhombic structure. In this work, we report on a simple route to the stabilization of h-YbFeO₃ nanocrystals by the synthesis of multiphase nanocomposites with titania additives. The new I-type heterojunction nanocomposites of o-YbFeO₃/h-YbFeO₃/r-TiO₂ were obtained by the glycine–nitrate solution combustion method with subsequent heat treatment of the products. An increase in the mole fraction of the h-YbFeO₃ phase in nanocomposites was found with the titanium addition, indicating its stabilizing effect via limiting mass transfer over heat treatment. The complex physicochemical analysis shows multiple contacts of individual nanocrystals of o-YbFeO₃ (44.4–50.6 nm), h-YbFeO₃ (7.5–17.6 nm), and rutile r-TiO₂ (~5 nm), confirming the presence of the heterojunction structure in the obtained nanocomposite. The photocatalytic activity of h-YbFeO₃/o-YbFeO₃/r-TiO₂ nanocomposites was evaluated by the photo-Fenton degradation of the methyl violet under visible light (λ ≥ 400 nm). It was demonstrated that the addition of 5 mol.% of TiO₂ stabilizes h-YbFeO₃, which allowed us to achieve a 41.5 mol% fraction, followed by a three-time increase in the photodecomposition rate constant up to 0.0160 min⁻¹.

A detailed experimental analysis of the impact of device topology on the performance of 1550 nm VCSELs with an active region based on thin InGaAs/InAlGaAs quantum wells and a composite InAlGaAs buried tunnel junction is presented. The high-speed performance of the lasers with L-type device topology (with the largest double-mesa sizes) is mainly limited by electrical parasitics showing noticeable damping of the relaxation oscillations. For the S-type device topology (with the smallest double-mesa sizes), the decrease in the parasitic capacitance of the reverse-biased p⁺n-junction region outside the buried tunnel junction region allowed to raise the parasitic cutoff frequency up to 13–14 GHz. The key mechanism limiting the high-speed performance of such devices is thus the damping of the relaxation oscillations. VCSELs with S-type device topology demonstrate more than 13 GHz modulation bandwidth and up to 37 Gbps nonreturn-to-zero data transmission under back-to-back conditions at 20 °C.