Wood decay fungi (WDF) seem to be particularly suitable for developing myco-materials due to their mycelial texture, ease of cultivation, and lack of sporification. This study focused on a collection of WDF strains that were later used to develop mycelium mats of leather-like materials. Twenty-one WDF strains were chosen based on the color, homogeneity, and consistency of the mycelia. The growth rate of each strain was measured. To improve the consistency and thickness of the mats, an exclusive method (newly patented) was developed. The obtained materials and the corresponding pure mycelia grown in liquid culture were analyzed by both thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) to evaluate the principal components and texture. TGA provided a semi-quantitative indication on the mycelia and mat composition, but it was hardly able to discriminate differences in the production process (liquid culture versus patented method). SEM provided keen insight on the mycelial microstructure as well as that of the mat without considering the composition; however, it was able to determine the hyphae and porosity dimensions. Although not exhaustive, TGA and SEM are complementary methods that can be used to characterize fungal strains based on their desirable features for various applications in bio-based materials. Taking all of the results into account, the Fomitopsis iberica strain seems to be the most suitable for the development of leather-like materials.

This work evaluates the efficiency of three biochar samples toward the adsorption of manganese, iron, and selenium present in a sample of urban wastewater. The biochar was produced from the pyrolysis of rice husks at 350 °C for 6 h (RHB) and subsequently modified using HCl (RHB_HCl) or NaOH (RHB_NaOH) to increase its surface area. The RHB_NaOH sample exhibited the highest removal efficiency for the three metals. The metals’ adsorption removal efficiency for RHB_NaOH was in the order Mn (76%), Se (66%), and Fe (66%), while for RHB_HCl, it was Fe (59%), Mn (30%), and Se (26%). The results show that the as-prepared RHB can remove the metals, even if in low amounts (Fe (48%), Mn (3%), and Se (39%)). The adsorption removal for the three types of adsorbents follows the Langmuir isotherm model. Pseudo-first-order and pseudo-second-order models were used to determine the adsorption mechanism for each of the three adsorbents. Both models showed a good fit with R² (>0.9) for the RHB_NaOH and RHB sorption of Fe, Mn, and Se. Overall, this work demonstrates the potential of biochar for the removal of metals from real wastewater.

To improve the pharmaceutical behavior of the oral antidiabetic agent gliclazide through the synthesis of multicomponent crystals with tromethamine. Multicomponent crystals were prepared by solvent evaporation method, kneading, and combining mechanical and thermal activation. DSC, FT-IR spectroscopy, X-ray diffraction, SEM-EDS, and SSNMR were used to investigate their formation. Measurements of solubility and dissolution rate were carried out for the pharmaceutical characterization. The formation of multicomponent crystals of gliclazide and tromethamine was confirmed by all the techniques. In particular, FT-IR and NMR measurements revealed that the interaction between drug and coformer leads to significant changes of the hydrogen bond scheme, and that almost all the functional groups of the two molecules are involved. The dissolution profile of the new phase is significantly better than that of both pure gliclazide and of the reference commercial product Diabrezide®. The new system shows an improved pharmaceutical behavior and could be formulated in a dosage form to obtain a rapid and complete release of the drug available for absorption.

There are several techniques providing quantitative elemental analysis, but very few capable of identifying both the concentration and chemical state of elements. This study presents a systematic investigation of the properties of the X-rays emitted after the atomic capture of negatively charged muons. The probability rates of the muonic transitions possess sensitivity to the electronic structure of materials, thus making the muonic X-ray Emission Spectroscopy complementary to the X-ray Absorption and Emission techniques for the study of the chemistry of elements, and able of unparalleled analysis in case of elements bearing low atomic numbers. This qualitative method is applied to the characterization of light elements-based, energy-relevant materials involved in the reaction of hydrogen desorption from the reactive hydride composite Ca(BH₄)₂-Mg₂NiH₄. The origin of the influence of the band-structure on the muonic atom is discussed and the observed effects are attributed to the contribution of the electronic structure to the screening and to the momentum distribution in the muon cascade.

Worldwide energy costs have grown in recent years due to the dwindling global fossil fuel resources and the increased reliance on them for global energy production. This is a common scenario in many nations, including Sri Lanka. As a developing country, Sri Lanka should encourage the diversification of its renewable energy supplies using locally available resources. In this regard, Sri Lanka can promote the use of agricultural residues for energy generation. The present work explores the energy potential of the solid waste generated by the rice industry: rice straw (RS) and rice husk (RH). A new approach was developed using statistical data on rice production and paddy cultivation in each district of the island. The obtained data were integrated into a geographic information system (GIS) to provide geo-referenced results. A physico-chemical characterization of the RS and RH was conducted to correlate the properties of raw materials to their potential energy generation. As an energy generation technology, the grate-fired combustion boiler accompanied by steam turbine cycle (GFC/ST) was selected. Our findings show that the total energy capacity using by-products of the rice industry is estimated to be 2129.24 ktoe/year of primary energy, with a capacity of 977 Mwe, producing 5.65 TWh of electricity annually. An economic analysis shows ten districts have a high profit index (PI > 1). The districts with the highest PI values are Anuradhapura, Ampara, Polonnaruwa, and Kurunegala, with annual energy potentials of 286 ktoe, 279 ktoe, 231 ktoe, and 160 ktoe, respectively. This work aims to aid future policy decisions by identifying potential districts in which to develop infrastructure for energy generation using agricultural waste, thus reducing net greenhouse gas emissions (GHG) of Sri Lanka.

Cleaning is one of the most important, essential, and delicate operation which has to be handled by conservators before applying new materials to any substrates. In past decades, nanotechnology introduced new concepts and materials in the conservation field, which have been providing many advantageous performances, especially higher than older materials. As a result, the conservators have already started to use nanomaterials in the cleaning processes of artifacts. Taking into consideration this new approach, our study has focused on using nano-structured emulsions (NSE) as smart cleaning materials for removing polymer coatings (e.g., acrylic polymers). For this purpose, Paraloid B-72 was applied on three different substrates (glass, Lecce stone, and Arenaria stone) and cleaning was performed by a specific nano-structured emulsion (NSE) based on an eco-friendly surfactant (EcoSurf) and two organic solvents in different proportions. In order to better understand the interaction of surfactant and organic solvents with polymer coating, plain EcoSurf in water was also used for comparison. In this study, the decay process of the considered polymer was also deeply studied, because it directly affects the cleaning effectiveness. Coated specimens of the different substrates were artificially aged and examined by different techniques: chromatic variations and contact angle measurements, optical microscopy, FTIR, and SEM-EDS. This material characterization process is important to understand the colour, morphology, and micro-structural difference, and the changes of hydrophobic behaviour as well as chemical composition of Paraloid B-72 polymer due to different ageing processes. After that, substrates coated with both unaged and aged polymer were cleaned by NSE according to the direct-contact procedure and cellulose pulp method. Preliminary analyses suggested that the direct-contact cleaning performed by nano-emulsion (i.e., NSE) induced a complete removal of the acrylic polymer, despite that this method is not recommended for the artifacts and can be hardly applicable in real cases. On the other hand, experimental results showed that satisfactory cleaning of stone substrates can be obtained by using NSE/the cellulose pulp system.