In this paper, Li_xCa_(1−x)Cu₃Ti₄O₁₂ (LCCTO) solid solutions were successfully synthesized. XRD diagrams showed that dopant acceptor Li⁺ cations, in a concentration range of x = 0.01–0.10, were successfully merged into CCTO structure. It was found that doping with low concentrations of lithium (x < 0.05) inhibited grain growth during annealing; however, for x > 0.05, the grain growth process resumed. Permittivity and dielectric losses of obtained LCCTO ceramics were analyzed by the means of impedance spectroscopy in a frequency range from 10⁻¹ to 10⁶ Hz. It was revealed that acceptor doping with lithium at an appropriate concentration of x = 0.05 allowed to obtain ceramics with a permittivity level of ε′ = 3 × 10⁴ and low dielectric losses tanδ < 0.1 at 1 kHz. Further addition of lithium in a concentration range of x = 0.075–0.10 led to a sharp decline in permittivity and an increase in dielectric losses. It was discovered that lithium addition to CCTO ceramics drastically decreased grain boundary resistivity from 115 MΩ·cm to 5–40 MΩ·cm at x = 0.01–0.10. Using Havriliak–Negami equation, the relaxation times for grain dipoles and grain boundary dipoles were found to be ranging from 0.8 × 10⁻⁶ to 1.7 × 10⁻⁶ s and from 0.4 × 10⁻⁴ to 7.1 × 10⁻⁴ s, respectively. The developed materials can be used in the manufacture of Multilayer Ceramic Capacitors (MLCC) as a dielectric.

Some solid solutions with the chemical composition K_xFe_yTi_8-yO₁₆ (KFTO) and a hollandite-like structure were successfully synthesized by modified sol–gel method. The obtained powders were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The ceramic pellets based on KFTO powders were obtained by compressing and sintering at 1080 °C for 4 h. The sinters were characterized by X-ray and impedance spectroscopy. XRD results show that KFTO powders have a mono-phase tetragonal structure at x = 1.4–1.8 and y = 1.4–1.6. However, it was recognized that the hollandite-like phase could be broken during sintering to form TiO₂ and Fe₂TiO₅ crystals distributed throughout the volume of the ceramics. A frequency dependency of dielectric properties for the sinters was studied by impedance spectroscopy. It was found that an increase in the TiO₂ (rutile) phase during the sintering contributes to a decrease in dielectric losses. At the same time, the KFTO ceramics with reduced content of potassium had increased permittivity. The contribution of electron-pinned defect dipoles (EPDD) and internal barrier layer capacitance (IBLC) in the permittivity of the obtained ceramics was estimated using the Havriliak–Negami equation. It is shown that the KFTO ceramics have the polydisperse characteristic of dielectric relaxation. The observed grain and grain boundary dipole relaxation times were 1.03 × 10⁻⁶ to 5.51 × 10⁻⁶ s and 0.197 to 0.687 s, respectively.

It is shown that the potassium polytitanate powder (PPT) synthesized at 500 °C via the treatment of powdered TiO₂ (rutile) in molten mixtures of KOH and KNO₃ is a cheap and effective catalyst of H₂O₂ chemical decomposition in aqueous solutions. At the same time, the PPT catalytic activity strongly depends on the [TiO₂]:[KOH]:[KNO₃] weight ratio in the mixture used for the synthesis, increasing with [KNO₃] in the order of PPT (30:30:40) < PPT (30:50:20) < PPT (30:70:0). The obtained results are explained by increased [Ti³⁺] in the PPT structure (XPS data), which is grown in this order from 0 to 4.0 and 21.9 at.%, respectively, due to the reduced oxidation activity of the melt used for PPT synthesis. The mechanism of the autocatalytic process taking place in the PPT-H₂O₂-H₂O system is analyzed. Taking into account the data of FT-IR spectroscopy, it is assumed that the increased catalytic activity of the investigated materials is related to the increased surface concentration of the Ti⁴⁺-O(H)-Ti⁴⁺ groups, formed from the Ti³⁺-O(H₃O⁺)-Ti⁴⁺ clusters and further transformed into Ti-O-O-H catalytic centers. Some possible applications of the PPT-H₂O₂-H₂O catalytic system, including the oxidation processes of green chemistry and photo-catalysis, are discussed.

It was shown that quasi-amorphous potassium polytitanate polyphosphate particles with a layered structure and high antifriction properties can be synthesized by treatment of a titanium dioxide powder in melts in the KOH–KH₂PO₄ system. At a certain ratio between the components in the reaction mixture, one can obtain the product with a minimum content of crystalline phases. The particles of the obtained X-ray amorphous product have a layered structure similar to that of potassium polytitanate synthesized in melts in the system TiO₂–KOH–KNO₃ but are characterized by a high content of phosphorus, which improves the tribological characteristics of the material. It was detected that, at [KH₂PO₄] > [TiO₂], in the reaction mixture, a secondary crystalline phase K₂Ti₂(PO₄)₃ forms, which enhances the antiscuff properties of lubricants produced based on the obtained products, but reduces their antifriction properties.

The electrochemical and electrophysical properties of basic and protonated potassium titanates in contact with the graphite electrodes were studied using the method of impedance spectroscopy. The characteristics of potassium titanates are given depending on the methods of modification and on the methods of their processing. The activation energies for some compositions were determined.

The paper studies the influence of the ratio of components in the TiO2-KOH-KNO3 reaction mixture on the structural properties of the quasi-amorphous particles of the product obtained (potassium polytitanate, PPT) which has the chemical composition of K2O·(4.18 ± 0.16)TiO2·(2.2 ± 0.1)H2O. It is shown that by decreasing the KOH content in the melt used during heat treatment of TiO2 powders (500 °C, 2 h), a degree of crystallinity of the PPT particles increases, while the proportion of the titanium in the valence state Ti3+ and the amount of chemically adsorbed water decrease. The mechanism of the processes occurring during the synthesis of potassium polytitanate in nitrate- hydroxide melts is analyzed and an explanation for the patterns of change in the structure of the PPT particles observed with a change in the oxidizing properties of the meltis given. On the basis of the data obtained, some recommendations are given in order to use different variants of nitrate- hydroxide melts for the synthesis of PPT powders, depending on their further application.