Poly(acrylamide co-acrylic acid) hydrogels were prepared by free-radical copolymerization of acrylamide and acrylic acid in aqueous solutions using electron beam irradiation in the dose range of 2.5 kGy to 6 kGy in atmospheric conditions and at room temperature. The influence of the absorbed dose, the amount of cross-linker (trimethylolpropane trimethacrylate) and initiator (potassium persulfate) on the swelling properties and the diffusion coefficient and network parameters of hydrogels were investigated. The structure and morphology of hydrogels were characterized by Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The use of the obtained hydrogels by the removal of Cu2+ and Cr6+ from aqueous solutions was investigated at room temperature. During the adsorption of metal ions on hydrogels, the residual metal ion concentration in the solution was measured by an atomic absorption spectrophotometer (AAS). It has been established that the use of a relatively small amount of trimethylolpropane trimethacrylate for hydrogel preparation has led to the increasing of swelling up to 8500%.
The practical implementation of the European Council Directive no. 2013/59/EURATOM in Romania requires reliable indoor measurements of the radon (222Rn) activity concentration in air. In Romania, several Testing Laboratories were designated for radon activity and/or radon activity concentration in air measurements by the Romanian National Commission for Nuclear Activities Control (CNCAN). The calibration of the instruments used for indoor radon activity concentration measurements is very important. IFIN-HH, through its Ionizing Radiation Metrology Laboratory (LMRI), performed advanced research in the field of radon metrology, using radon standard sources prepared by LMRI, its radon chamber facility and a new reference radon monitor. The most recent results are described in this article. The radon chamber facility from IFIN-HH was technically improved, and new equipment and methods were set up and tested in order to provide new calibration services for customers. Additionally, calibration of the radon monitors was performed, as well as of the systems with solid-state nuclear track detectors, used for radon in air activity concentration measurements. IFIN-HH/LMRI obtained the CNCAN designation as Calibration Laboratory for installations measuring the radon activity concentration in air.