The type IV hydrogen storage tank with a polymer liner is a promising storage solution for fuel cell electric vehicles (FCEVs). The polymer liner reduces the weight and improves the storage density of tanks. However, hydrogen commonly permeates through the liner, especially at high pressure. If there is rapid decompression, damage may occur due to the internal hydrogen concentration, as the concentration inside creates the pressure difference. Thus, a comprehensive understanding of the decompression damage is significant for the development of a suitable liner material and the commercialization of the type IV hydrogen storage tank. This study discusses the decompression damage mechanism of the polymer liner, which includes damage characterizations and evaluations, influential factors, and damage prediction. Finally, some future research directions are proposed to further investigate and optimize tanks.

The Mg-6%Al-3%Zn and Mg-6%Al-3%Zn-(1%, 1.5%, 2%)In alloys were prepared by melting and casting. Their microstructures were investigated via metallographic and energy-dispersive X-ray spectroscopy (EDS) analysis. Moreover, hydrogen evolution and electrochemical tests were carried out in 3.5 wt% NaCl solution aiming at identifying their corrosion mechanisms and discharge behaviors. The results suggested that indium exerts an improvement on both the corrosion rate and the discharge activity of Mg-Al-Zn alloy via the effects of grain refining, β-Mg₁₇Al₁₂ precipitation, dissolving-reprecipitation, and self-peeling. The Mg-6%Al-3%Zn-1.5%In alloy with the highest corrosion rate at free corrosion potential did not perform desirable discharge activity indicating that the barrier effect caused by the β-Mg₁₇Al₁₂ phase would have been enhanced under the conditions of anodic polarization. The Mg-6%Al-3%Zn-1.0%In alloy with a relative low corrosion rate and a high discharge activity is a promising anode material for both cathodic protection and chemical power source applications.

This paper presents a comprehensive study on the dynamic simulation modeling of alkaline water electrolyzers. Detailed experimental testing and characteristic analysis reveal that alkaline water electrolyzers have long startup times, rapid dynamic responses, and poor dynamic stability. These characteristics are critical for the development of accurate models and effective strategies. A dynamic simulation model was established in MATLAB R2022b and Simulink, enabling standalone simulation operation and module encapsulation. This model facilitates the construction of hydrogen production clusters and serves as a foundational tool for system strategy research. Simulations of rated current loading and unloading for four electrolyzers over 6 h showed significant differences in startup and operation. Key parameters such as cell voltage, maximum loadable power, hydrogen production efficiency, and energy consumption were analyzed. Temperature simulations indicated significant differences in thermal equilibrium points and cooling modes among the electrolyzers, as determined by structural design and cooling system efficiency. These findings highlight the need for efficiency improvements in high-current density electrolyzers. Overall, the model effectively represents commercial electrolyzer characteristics and offers a reliable tool for future research on control strategies for adapting hydrogen production systems to renewable energy power fluctuations, laying a solid foundation for the optimization of electrolyzer design and operation strategies.

Due to its high maturity and low cost, alkaline water electrolysis (AWE) technology has been widely integrated with large-scale renewable energy systems (RESs) for green hydrogen (H₂) production. Here, to evaluate the operational performance of a 50 kW AWE electrolyzer under different operation conditions, we developed an empirical modeling and experimental validation approach. The model particularly focuses on the polarization curve and the hydrogen to oxygen ratio (HTO). The relevant parameters of the empirical model were obtained by fitting the experimental data with MATLAB. The validity and accuracy of the established model and parameters were verified by comparing the fitted values with experimental values, and a good correlation was found. Since the experiments were performed in the sub-cell of 5 MW scale AWE electrolyzers, this model can also predict the performance of industrial MW-scale AWE electrolyzers and serve as a tool for the optimal design and control of industrial AWE electrolyzers. The results demonstrated that the models can achieve an accuracy with an R² value exceeding 0.95 across a range of operational conditions.

With the development of hydrogen energy, containerized hydrogen fuel cell systems are being used in distributed energy-supply systems. Hydrogen pipelines and electronic equipment of fuel cell containers can trigger hydrogen-explosion accidents. In the present study, Computational Fluid Dynamics (CFD) software was used to calculate the affected areas of hydrogen fuel cell container-explosion accidents with and without protective walls. The protective effects were studied for protective walls at various distances and heights. The results show that strategically placing protective walls can effectively block the propagation of shock waves and flames. However, the protective wall has a limited effect on the reduction of overpressure and temperature behind the wall when the protective wall is insufficiently high. Reflected explosion shock waves and flames will cause damage to the area inside the wall when the protective wall is too close to the container. In this study, a protective wall that is 5 m away from the container and 3 m high can effectively protect the area behind the wall and prevent damage to the container due to the reflection of shock waves and flame. This paper presents a suitable protective wall setting scheme for hydrogen fuel cell containers.

Hydrogen refueling stations are one of the key infrastructure components for the hydrogen-fueled economy. Skid-mounted hydrogen refueling stations (SHRSs) can be more easily commercialized due to their smaller footprints and lower costs compared to stationary hydrogen refueling stations. The present work modeled hydrogen explosions in a skid-mounted hydrogen refueling station to predict the overpressures for hydrogen-air mixtures and investigate the protective effects for different explosion vent layouts and protective wall distances. The results show that the explosive vents with the same vent area have similar overpressure reduction effects. The layout of the explosion vent affects the flame shape. Explosion venting can effectively reduce the inside maximum overpressure by 61.8%. The protective walls can reduce the overpressures, but the protective walls should not be too close to the SHRS because high overpressures are generated inside the walls due to the confined shock waves. The protective wall with a distance of 6 m can effectively protect the surrounding people and avoid the secondary overpressure damage to the container.