The objective of this study was to utilize agro-lignocellulosic wastes for growing oyster mushroom which become problematic for disposal. Pleurotus ostreatus was cultivated on five agro-industrial wastes: rice straw (RS), wheat straw (WS), corncobs (CC), saw dust and rice husk @ 3:1 (SR) and sugarcane bagasse (SB). Approximately 500 g sized polypropylene bags (20.32 × 30.48 cm) were used for each substrate. The SR significantly improved the number of fruiting body (27.80), size of the fruiting body (5.39 g), yield (115.13 g/packet), ash and shortened the days for stimulation to primordial initiation and harvest (9.2 days). The maximum percentage of visual mycelium growth with the least time (15.0 days) to complete the mycelium running was found in SB, whereas the highest biological efficiency value (56.5) was calculated in SR. The topmost value of total sugar (33.20%) and ash (10.87 g/100 g) were recorded in WS, whereas the utmost amount of protein (6.87 mg/100 g) and total polyphenolics (196.88 mg GAE/100 g) were detected from SB and SR, respectively. Overall SR gave the highest amount of the fruiting body with the topmost polyphenols and ash, moderate protein and total sugar, and secured maximum biological efficiency too. The results demonstrate that saw dust with rice husk could be used as an easy alternative substrate for oyster mushroom cultivation.

Red Sea coastal development has rapidly accelerated in recent decades that has led to a rise in the anthropogenic heavy metal levels in sediments. A total of 80 surficial sediment samples were collected from the shallow waters along the eastern Red Sea coast near Jeddah, Saudi Arabia. These samples were collected from three locations, designated as North, Middle and South of Jeddah, to assess the concentrations of six heavy metals: chromium (Cr), manganese (Mn), nickel (Ni), copper (Cu), zinc (Zn), and lead (Pb). The results showed that the concentrations (mg/kg) of these metals in the studied sediments follow this order: Pb (77.34 ± 150.59) > Mn (36.52 ± 37.72) > Zn (18.02 ± 23.94) > Cr (9.56 ± 5.81) > Cu (9.18 ± 13.67) > Ni (3.68 ± 4.54). The majority of the polluted sediments were recorded in the Middle and South locations. Pollution and enrichment indices such as Geo-accumulation indices (Igeo), Enrichment Factors (E_f), Contamination Factors (C_f), Pollution Load Indices (PLI), Potential Ecological Risk Indices (PERI) and Potential Toxicity Response Indices (RI) were calculated from the measured metals to establish baselines for the region and assess specific metal enrichments by location along the Jeddah coastline. The Igeo values showed that 30% of the Southern location stations are considered moderately to highly polluted. The Ef for all the studied sediments followed this order: Pb (extremely severe enrichment) > Zn > Cu > Cd > Cr (severe enrichment) > Ni (moderate enrichment).

In this study, a novel technique is introduced that involves the combination of an ion-imprinted polymer and solid-phase extraction to selectively adsorb lithium ions from reverse osmosis brine. In the process of synthesizing ion-imprinted polymers, phthalocyanine acrylate acted as the functional monomer responsible for lithium chelation. The structural and morphological characteristics of the molecularly imprinted polymers and non-imprinted polymers were assessed using Fourier transform infrared spectroscopy and scanning electron microscopy. The adsorption data for Li on an ion-imprinted polymer showed an excellent fit to the Langmuir isotherm, with a maximum adsorption capacity (Qm) of 3.2 mg·g⁻¹. Comprehensive chemical analyses revealed a significant Li concentration with a higher value of 45.36 mg/L. Through the implementation of a central composite design approach, the adsorption and desorption procedures were systematically optimized by varying the pH, temperature, sorbent mass, and elution volume. This systematic approach allowed the identification of the most efficient operating conditions for extracting lithium from seawater reverse osmosis brine using ion-imprinted polymer–solid-phase extraction. The optimum operating conditions for the highest efficiency of adsorbing Li⁺ were determined to be a pH of 8.49 and a temperature of 45.5 °C. The efficiency of ion-imprinted polymer regeneration was evaluated through a cycle of the adsorption–desorption process, which resulted in Li recoveries of up to 80%. The recovery of Li from the spiked brine sample obtained from the desalination plant reverse osmosis waste through the ion-imprinted polymer ranged from 62.8% to 71.53%.

Mass and cost tradeoffs by deploying three optimized spars, made of all-glass, hybrid and all-carbon composites, applied to a publicly available large-scale composite blade of 100 m in length for a 13.2 MW wind turbine, are explored. The blade mass and cost minimizations are calculated for two design load cases, generating the worst aerodynamic loads for parked and rotating rotor blades, while meeting the stiffness, strength, stability and resonance design requirements, as recommended by the wind turbine standards. The optimization cases are formulated as a single-objective, multi-constraint optimization problem, while taking into account the manufacturability of hybrid spars in particular, and it is solved using a genetic algorithm method. The blade mass lowers in the range of 8.1–13.3%, 18.5–20.7% and 25.7–26.4% for the optimized all-glass, hybrid and all-carbon spars, respectively, while the cost decreases for the optimized all-glass spars only. The cost increases in a range of 1.2–13.6% and 24.5–31.5% when the optimized hybrid and all-carbon spars are used. Further, the hybrid spar optimization using the blade mass and cost objective functions, as well as the effects of spar optimization on the blade’s structural performance in terms of tip deflection, strength, buckling resistance and first natural frequency, are discussed.

Fouling and biofouling remain significant challenges in seawater desalination plants. One practical approach to address these issues is to develop anti-biofouling membranes. Therefore, novel hybrid zinc phthalocyanine/polyvinylidene fluoride-co-hexafluoropropylene (Zn(4-PPOx)₄Pc/PVDF-HFP) membranes were prepared by electrospinning to evaluate their properties against biofouling. The hybrid nanofiber membrane was characterized by atomic force microscopy (AFM), attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, and contact angle measurements. The theoretical calculations of PVDF-HFP, Zn(4-PPOx)₄Pc), and Zn(4-PPOx)₄Pc/PVDF-HFP nanofibers were performed using a hybrid functional RB3LYP and the 6-31 G (d,p) basis set, employing Gaussian 09. DFT calculations illustrated that the calculated physical and electronic parameters ensured the feasibility of the interaction of PVDF-HFP with Zn(4-PPOx)₄Pc via a halogen–hydrogen bond, resulting in a highly stable and remarkably reactive structure. Moreover, molecular electrostatic potential (MEP) maps were drawn to identify the reactive regions of the Zn(4-PPOx)4Pc and PVDF-HFP/Zn(4-PPOx)4Pc nanofibers. Molecular docking analysis revealed that Zn(4-PPOx)₄Pc has highest binding affinity (−8.56 kcal/mol) with protein from S. aureus (1N67) mainly with ten amino acids (ASP405, LYS374, GLU446, ASN406, ALA441, TYR372, LYS371, TYR448, LYS374, and ALA442). These findings highlight the promising potential of Zn(4-PPOx) ₄Pc/PVDF-HFP nanocomposite membranes in improving the efficiency of water desalination by reducing biofouling and providing antibacterial properties.