Energy conservation in buildings has been the focus of many studies since nearly one-third of global energy consumption is due to buildings. Phase change material (PCM) technology promises to be an attractive solution for energy saving in buildings since it is a passive and effective technology, as demonstrated in the literature. Therefore, this study focuses on the energy-saving performance of PCM-integrated buildings located in a Mediterranean climate to reveal their energy-saving potential. PCM is integrated both in external or internal south walls and roofs of buildings under four different climatic conditions. EnergyPlus, which is a well-known building simulation software, is adopted for building thermal analyses. The effects of melting temperature, location of PCM layer in the wall, thickness of PCM layer, type of envelope (wall or roof), and PCM double-layer system in the wall are investigated. The corresponding energy savings and CO₂ emission reductions are obtained for the considered cases. The results showed that up to 41.6% reduction in energy demand can be obtained depending on the PCM application. Besides, PCM with a low melting temperature (21 °C) favored heating energy savings, while PCM with a high melting temperature (29 °C) favored cooling energy savings. Moreover, the double-layer PCM system provided higher energy savings than the single-layer PCM system, especially in warm and arid regions (Sousse and Tozeur).

This paper presents a comprehensive investigation of the synthesis and characterization of Zn_1−xCo_xO (0 ≤ x ≤ 0.05) nanopowders using a chemical co-precipitation approach. The structural, morphological, and vibrational properties of the resulting ZnO nanostructures were assessed through X-ray diffraction, scanning electronic microscopy, and Raman spectroscopy to examine the influence of cobalt doping. Remarkably, a notable congruence between the experimental results and the density functional theory (DFT) calculations for the Co-doped ZnO system was achieved. Structural analysis revealed well-crystallized hexagonal wurtzite structures across all samples. The SEM images demonstrated the formation of spherical nanoparticles in all the samples. The vibrational properties confirmed the formation of a hexagonal wurtzite structure, with an additional Raman peak corresponding to the F_2g vibrational mode characteristic of the secondary phase of ZnCo₂O₄ observed at a 5% cobalt doping concentration. Furthermore, a theoretical examination of cobalt doping’s impact on the elastic properties of ZnO demonstrated enhanced mechanical behavior, which improves stability, recyclability, and photocatalytic activity. The photocatalytic study of the synthesized compositions for methylene blue (MB) dye degradation over 100 min of UV light irradiation demonstrated that Co doping significantly improves photocatalytic degradation. The material’s prolonged lifetime, reduced rate of photogenerated charge carrier recombination, and increased surface area were identified as pivotal factors accelerating the degradation process. Notably, the photocatalyst with a Zn_0.99Co_0.01O composition exhibited exceptional efficiency compared to that reported in the literature. It demonstrated high removal activity, achieving an efficiency of about 97% in a shorter degradation time. This study underscores the structural and photocatalytic advancements in the ZnO system, particularly at lower cobalt doping concentrations (1%). The developed photocatalyst exhibits promise for environmental applications owing to its superior photocatalytic performance.

Capacitance nonlinearities were studied in atomic layer deposited HfO₂ films using two types of signals: a pure ac voltage of large magnitude (ac nonlinearities) and a small ac voltage superimposed to a large dc voltage (dc nonlinearities). In theory, ac and dc nonlinearities should be of the same order of magnitude. However, in practice, ac nonlinearities are found to be an order of magnitude higher than dc nonlinearities. Besides capacitance nonlinearities, hopping conduction is studied using low-frequency impedance measurements and is discussed through the correlated barrier hopping model. The link between hopping and nonlinearity is established. The ac nonlinearities are ascribed to the polarization of isolated defect pairs, while dc nonlinearities are attributed to electrode polarization which originates from defect percolation paths. Both the ac and dc capacitance nonlinearities display an exponential variation with voltage, which results from field-induced lowering of the hopping barrier energy.