The effects of micro-shot peening on the rotating bending fatigue resistance of AISI 304 stainless steel (SS) were investigated in this study. The strain-hardening, surface roughness and induced residual stress were inspected and correlated with fatigue strength. Micro-shot peening caused intense strain-hardening, phase transformation and residual stress but was also accompanied by a minor increase in surface roughness. A nanograined structure, which was advantageous to fatigue resistance, was observed in the severe shot-peened layer. The absence of microcracks, minor increase in surface roughness, nanograined structure and induced high compressive residual stress in the shot-peened layer were responsible for the improved fatigue strength of AISI 304 SS.
In this study, Fe40Cr19Mo18C15B8 amorphous coatings were prepared using high velocity oxygen fuel (HVOF) technology. Different temperatures were used in the heat treatment (600 °C, 650 °C, and 700 °C) and the annealed coatings were analyzed by DSC, SEM, TEM, and XRD. XRD and DSC results showed that the coating started to form a crystalline structure after annealing at 650 °C. From the SEM observation, it can be found that when the annealing temperature of the Fe-based amorphous alloy coating reached 700 °C, the surface morphology of the coating became relatively flat. TEM observation showed that when the annealing temperature of the Fe-based amorphous alloy coating was 700 °C, crystal grains in the coating recrystallized with a grain size of 5–20 nm. SAED analysis showed that the precipitated carbide phase was M23C6 phase with different crystal orientations (M = Fe, Cr, Mo). Finally, the corrosion polarization curve showed that the corrosion current density of the coating after annealing only increased by 9.13 μA/cm2, which indicated that the coating after annealing treatment still had excellent corrosion resistance. It also proved that the Fe-based amorphous alloy coating can be used in high-temperature environments. XPS analysis showed that after annealing FeO and Fe2O3 oxide components increased, and the formation of a large number of crystals in the coating resulted in a decrease in corrosion resistance.
Previous studies identified that extracts of Talinum triangulare rich in flavonoids and phenolic acids showed antioxidative and immunomodulatory activities. In this study, the L9 orthogonal array was used to determine the optimal extraction conditions for water-extracted polysaccharides of T. triangulare (TTP) by hot reflux extraction and ultrasonic assisted extraction (UAE) methods. Results showed that while both extraction methods obtained a maximum polysaccharide yield of 3.1%, the optimal conditions for obtaining TTP was by UAE method. TTP was separated into large (LTTP) and small (STTP) molecular weights by dialysis. Since LTTP showed better effects than STTP in inducing macrophages to produce nitric oxide (NO) and indirectly inhibiting human cervical cancer HeLa cells, six different LTTP fractions were separated using anion-exchange chromatography. Contents of polysaccharides, triterpenoids, polyphenols, and proteins and molecular weights of major polysaccharide in each fraction were analyzed. The F1 fraction of LTTP, which showed the highest inducing ability of mouse RAW264.7 macrophages to secrete NO and tumor necrosis factor-α, showed the most significant indirect inhibitory effect of human colon cancer SW620 cells. These results suggest that LTTP, especially the F1 fraction, of T. triangulare may be used in health foods or Chinese medicine for its immunomodulatory potential.
1 December 2021 in International Journal of Electrochemical Science
This study aims to investigate the wear and corrosion–wear behavior of 17-4PH stainless steel specimens, both fabricated via Selective Laser Melting (SLM) and conventional bulk material, after undergoing Solution Treatment (S.T.) in a seawater medium. Microstructural observations indicated that solution treatment contributed to a more uniform distribution of martensitic structures on the sample surface. Moreover, the solution-treated specimens exhibited improved microstructural uniformity and structural stability. SLM specimens exhibit the elimination of fine particles and scanning track traces. Based on the results of dynamic polarization tests, SLM specimens demonstrate superior corrosion resistance. However, in corrosion–wear conditions, the bulk material outperforms the SLM specimens, primarily due to the presence of pores in the latter, which are detrimental under such environments. XPS analysis of the passive film structure indicates that the passive layer is mainly composed of FeO, Cr2O3, and NiO, with the inner layer predominantly consisting of chromium oxide. The Cr2O3 layer, formed by the reaction between chromium and oxygen, significantly enhances the corrosion resistance of the material due to its extremely low chemical reactivity and high stability.
Amorphous thin films can be applied to increase the anti-corrosion ability of critical components. Atomized FeCrNiMoCSiB powders were hot-pressed into a disc target for R. F. magnetron sputtering on a 316L substrate to upgrade its corrosion resistance. The XRD spectrum confirmed that the film deposited by R. F. magnetron sputtering was amorphous. The corrosion resistance of the amorphous film was evaluated in a 1 M HCl solution with potentiodynamic polarization tests, and the results were contrasted with those of a high-velocity oxy-fuel (HVOF) coating and 316L, IN 600, and C 276 alloys. The results indicated that the film hardness and elastic modulus, as measured using a nanoindenter, were 11.1 and 182 GPa, respectively. The principal stresses in two normal directions of the amorphous film were about 60 MPa and in tension. The corrosion resistance of the amorphous film was much greater than that of the other samples, which showed a broad passivation region, even in a 1 M HCl solution. Although the amorphous film showed high corrosion resistance, the original pinholes in the film were weak sites to initiate corrosion pits. After polarization tests, large, deep trenches were seen in the corroded 316L substrate; numerous fine patches in the IN 600 alloy and grain boundary corrosion in the C276 alloy were observed.