Cement-based materials are essential in modern construction, valued for their versatility and performance. Rheological properties, including yield stress, plastic viscosity, and thixotropy, play indispensable roles in optimizing the workability, stability, and overall performance of cement composites. This review explores the effects of supplementary cementitious materials (SCMs), chemical admixtures, nanomaterials, and internal curing agents on modulating rheological properties. Specifically, SCMs, including fly ash (FA), ground granulated blast furnace slag (GGBFS), and silica fume (SF), generally improve the rheology of concrete while reducing the cement content and CO₂ emissions. Regarding chemical admixtures, like superplasticizers (SPs), viscosity-modifying agents (VMAs), setting-time control agents, and superabsorbent polymers (SAPs), they further optimize flow and cohesion, addressing issues such as segregation and early-age shrinkage. Nanomaterials, including nano-silica (NS) and graphene oxide (GO), can enhance viscosity and mechanical properties at the microstructural level. By integrating these materials above, it can tailor concrete for specific applications, thereby improving both performance and sustainability. This review presents a comprehensive synthesis of recent literature, utilizing both qualitative and quantitative methods to assess the impacts of various additives on the rheological properties of cement-based materials. It underscores the pivotal roles of rheological properties in optimizing the workability, stability, and overall performance of cement composites. The review further explores the influences of SCMs, chemical admixtures, nanomaterials, and internal curing agents on rheological modulation. Through the strategic integration of these materials, it is possible to enhance both the performance and sustainability of cement composites, ultimately reducing carbon emissions and advancing the development of eco-friendly construction materials.

In this study, the effect of microbead dosages (0%, 5%, 10%, 15%, and 20%) on the carbonation resistance of expanded polystyrene (EPS) concrete was investigated. Five groups of EPS concrete specimens were produced and underwent rapid carbonation testing. The carbonation depth and strength after carbonation of the specimens were measured at different carbonation ages (7 days, 14 days, and 28 days) and analyzed to determine the effect of microbead dosages and compressive strength on carbonation resistance. Results indicated that the carbonation depth increased with the progression of carbonation time. The introduction of microbeads was found to significantly improve the carbonation resistance of EPS concrete, leading to a reduction in carbonation depth of over 50% after 28 days and an increase in strength after carbonation by 18–56%. A relative compressive strength model for EPS concrete after carbonation was developed, which could accurately characterize the growth of compressive strength. Based on the analysis of EPS concrete carbonation depth data, a prediction model for the carbonation depth of EPS concrete with microbead dosage was established through fitting, providing improved accuracy in predicting carbonation resistance. The microstructure of EPS concrete was also examined using scanning electron microscopy to uncover the underlying mechanisms of microbead enhancement on carbonation resistance. These findings have potential implications for future research and engineering applications in the carbonation resistance of EPS concrete.

This study investigated the influence of microbead dosages (0, 5, 10, 15, and 20%) on the frost resistance of expanded polystyrene (EPS) concrete. Five groups of EPS concrete specimens were prepared and subjected to rapid freeze–thaw tests. The freeze–thaw deterioration of EPS concrete was assessed using macroscopic indicators, including mass loss, strength loss, and dynamic elastic modulus loss. The underlying deterioration mechanism was revealed through the analysis of the EPS particle–matrix interface. A concrete damage plasticity model of EPS concrete based on damage mechanics theory was established. The results indicate that the addition of microbeads increased the strength of EPS concrete by 38–53%, reduced the strength attenuation after freeze–thaw damage by 8.1%, and improved the frost resistance level by 10–60 grades. The optimal dosage of microbeads is 15% of the cementitious material. The interfacial transition zone gaps in EPS concrete with added microbeads after freeze–thaw cycles are smaller, contributing to a more complete hydration reaction. The freeze–thaw damage model established in this study accurately reflects the freeze–thaw damage law of EPS concrete and provides a reference for studying the mechanical properties of EPS concrete under freeze–thaw cycles. The research findings of this study can enhance the strength and service life of EPS concrete, expanding its application scope as a structural material. The study provides valuable insights for future research and engineering applications related to the frost resistance of EPS concrete.

There is a lack of research on the early plastic deformation and capillary pressure of high-volume fly ash concrete (HVFAC) under varying ambient temperatures. This study aims to investigate the effects of water–binder ratio, fly ash admixture, and ambient temperature on the air entry time T, capillary pressure, and plastic shrinkage of HVFAC. Nine different fly ash concrete materials were designed and analyzed to determine the early plastic deformation and capillary pressure of HVFAC under different ambient temperatures. The dosage of different superplasticizers was adjusted to ensure a slump of 180 mm for all the HVFAC mixtures. The results showed that at 20 °C, T increases with the increase in the water–binder ratio and fly ash admixture, while the effect of T is negligible at 35 °C. The plastic shrinkage of HVFAC increases significantly with the increase in curing temperature, and there is a linear correlation between the air entry time T and the plastic shrinkage value at this time. At low water–binder ratios, the capillary pressure threshold P_a increases with increasing curing temperature, while at high water–binder ratios, there is no significant trend observed for P_a. The findings of the study can provide a theoretical basis for preventing plastic cracking of concrete and optimizing early curing methods.

Municipal solid waste incineration bottom ash (IBA), a major by-product of waste-to-energy plants, is typically landfilled or utilized as low-grade aggregate due to its low intrinsic reactivity and complex composition. This study systematically investigates the efficacy of chemical pretreatment in enhancing the cementitious behavior of IBA, specifically examining the effects of alkali type (Ca(OH)₂, NaOH, and Na₂CO₃) and pretreatment duration on reactivity, microstructure, and mechanical performance. The results indicate that Ca(OH)₂ activation provides the most significant enhancement; a one-day treatment yielded a 28-day strength activity index (H₂₈) of 76% and facilitated the formation of a compact microstructure rich in ettringite (AFt) and C-S-H gels. Conversely, NaOH and Na₂CO₃ treatments were less effective, leading to increased porosity and reduced strength attributed to charge imbalance and excessive carbonation, respectively. Prolonged alkaline treatment yielded diminishing returns, causing premature gel densification or excessive silicate depolymerization. Life-cycle assessment (LCA) revealed that Na₂CO₃ pretreatment entails the highest carbon footprint due to its high molar mass and energy-intensive production, whereas NaOH offers the highest CO₂ efficiency per unit of reactivity. Overall, Ca(OH)₂ represents a balanced strategy, combining strong activation potential, chemical compatibility, and moderate carbon emissions, thereby supporting the sustainable valorization of IBA in low-carbon cementitious systems.

High strength and high ductility concrete (HSHDC) exhibit exceptional compressive strength (up to 90 MPa) and remarkable tensile ductility (ultimate tensile strain reaching 6%), making them highly resilient under impact loading. To elucidate the influence of strain rate and wet–dry cycling of salt spray on the dynamic compressive response of HSHDC, a series of tests was conducted using a 75 mm split Hopkinson pressure bar (SHPB) system on specimens exposed to cyclic corrosion for periods ranging from 0 to 180 days. The alternating seasonal corrosion environment was reproduced by using a programmable walk-in environmental chamber. Subsequently, both uniaxial compression and SHPB tests were employed to evaluate the post-corrosion dynamic compressive properties of HSHDC. Experimental findings reveal that corrosive exposure significantly alters both the static and dynamic compressive mechanical behavior and constitutive characteristics of HSHDC, warranting careful consideration in long-term structural integrity assessments. As corrosion duration increases, the quasi-static and dynamic compressive strengths of HSHDC exhibit an initial enhancement followed by a gradual decline, with stress reaching its peak at 120 days of corrosion under all strain rates. All specimens demonstrated pronounced strain-rate sensitivity, with the dynamic increase factor (DIF) being minimally influenced by the extent of corrosion under dynamic strain rates (112.6–272.0 s⁻¹). Furthermore, the peak energy-consumption capacity of HSHDC was modulated by both the duration of corrosion and the applied strain rate.