Additive manufacturing technologies based on layer-by-layer deposition of material ejected from a nozzle provide unmatched versatility but are limited in terms of printing speed and resolution. Electrohydrodynamic jetting uniquely allows generating submicrometer jets that can reach speeds above 1 m s⁻¹, but such jets cannot be precisely collected by too slow mechanical stages. Here, we demonstrate that controlling the voltage applied to electrodes located around the jet, its trajectory can be continuously adjusted with lateral accelerations up to 10⁶ m s⁻². Through electrostatically deflecting the jet, 3D objects with submicrometer features can be printed by stacking nanofibers on top of each other at layer-by-layer frequencies as high as 2000 Hz. The fast jet speed and large layer-by-layer frequencies achieved translate into printing speeds up to 0.5 m s⁻¹ in-plane and 0.4 mm s⁻¹ in the vertical direction, three to four orders of magnitude faster than techniques providing equivalent feature sizes.

Melt electrowriting, a high‐resolution additive manufacturing technology, has so far been developed with vertical stacking of fiber layers, with a printing trajectory that is constant for each layer. In this work, microscale layer shifting is introduced through deliberately offsetting the printing trajectory for each printed layer. Inaccuracies during the printing of sinusoidal walls are corrected via layer shifting, resulting in accurate control of their geometry and mechanical properties. Furthermore, more substantial layer shifting allows stacking of fiber layers in a horizontal manner, overcoming the electrostatic autofocusing effect that favors vertical layer stacking. Novel nonlinear geometries, such as overhangs, wall texturing and branching, and smooth and abrupt changes in printing trajectory are presented, demonstrating the flexibility of the layer shifting approach beyond the state‐of‐the‐art. The practice of microscale layer shifting for melt electrowriting enables more complex geometries that promise to have a profound impact on the development of products in a broad range of applications.

Melt electrowriting (MEW), an electrohydrodynamic additive manufacturing technology, can produce polymer structures with micrometer resolution. Unlike conventional direct writing of fluids, the laydown pattern often deviates from the programmed one, due to a lag in the electrified jet. MEW of increasingly complex patterns currently entails a cumbersome trial‐and‐error procedure of adjusting printing parameters to ensure good accuracy. This issue is addressed with a geometrical model that predicts the expected printed fiber path, based on the coded trajectory, critical translation speed, and the collector speed. The influence of the process parameters on the jet lag is investigated and a general equation for the lag computation is implemented into the model. The presented model can evaluate the printing result up to ten times more accurate than the designed collector movement path and thus assist in identifying printing defects and adjustment of the printing G‐code in advance.

Electrohydrodynamic (EHD) jet printing of solvent-based inks or melts allows for the producing of polymeric fiber-based two- and three-dimensional structures with sub-micrometer features, with or without conductive nanoparticles or functional materials. While solvent-based inks possess great material versatility, the stability of the EHD jetting process using such inks remains a major challenge that must be overcome before this technology can be deployed beyond research laboratories. Herein, we study the parameters that affect the stability of the EHD jet printing of polyethylene oxide (PEO) patterns using solvent-based inks. To gain insights into the evolution of the printing process, we simultaneously monitor the drop size, the jet ejection point, and the jet speed, determined by superimposing a periodic electrostatic deflection. We observe printing instabilities to be associated with changes in drop size and composition and in the jet’s ejection point and speed, which are related to the evaporation of the solvent and the resulting drying of the drop surface. Thus, stabilizing the printing process and, particularly, the drop size and its surface composition require minimizing or controlling the solvent evaporation rate from the drop surface by using appropriate solvents and by controlling the printing ambient. For stable printing and improved jet stability, it is essential to use polymers with a high molecular weight and select solvents that slow down the surface drying of the droplets. Additionally, adjusting the needle voltages is crucial to prevent instabilities in the jet ejection mode. Although this study primarily utilized PEO, the general trends observed are applicable to other polymers that exhibit similar interactions between solvent and polymer.