Auxetic structures (AXSs) are a novel class of materials with unique mechanical deformation behavior associated with negative Poisson ratio. The combination of AXS configurations with various types of materials has unveiled a wide field of applications, including military high-velocity protection against explosions and ballistic projectiles. However, the characteristic geometric re-entrant model of AXSs imposes limitations and difficulties when using conventional manufacturing methods to assemble the structure lattice. Additive manufacturing (AM) has recently been explored as a more efficient and cost-effective method to fabricate AXSs, regardless of the type of material. This review paper focuses on the development and applications of AM processed AXSs. The review highlights the significance and great potential for this class of materials that can be produced relatively fast and at a low cost. The advantages of AXS/AM are expected to extend to important industrial sectors, particularly for military ballistic armor, where the feasibility for products with improved properties is critical. The use of AM offers a viable solution to overcome the difficulties associated with the conventional manufacturing methods, and thus offers greater design flexibility, cost efficiency, and reduced material waste. This review paper aims to contribute to the understanding of the current state-of-the-art and future research prospects for the production and applications of AXS/AM.

The growing concern about the limitation of non-renewable resources has brought a focus on the development of environmentally sustainable and biodegradable composite materials. In this context, a trend in the development of natural fibers used as a reinforcement in composites is ever-increasing. In this work, for the first-time, fibers extracted from the seven-islands-sedge plant (Cyperus malaccensis) have been characterized by X-ray diffraction (XRD) to calculate the crystallinity index and the microfibrillar angle (MFA). Also, an evaluation of the ultimate tensile strength by diameter intervals has been investigated and statistically analyzed by both the Weibull method and the analysis of variance (ANOVA). Moreover, the maximum deformation and tensile modulus have been found from the data acquired. Pullout tests have been conducted to investigate the critical length and interfacial strength when sedge fibers, are incorporated into epoxy resin matrix. Microstructure analysis by scanning electron microscopy (SEM) was performed to observe the mechanism responsible for causing rupture of the fiber as well as the effective fiber interfacial adhesion to the epoxy matrix.

Basic properties of sedge fibers from the seven-islands-sedge plant (Cyperus malaccensis) were investigated with possible application in reinforcing composite materials. A dimensional distribution and the effect of fiber diameter on density were investigated using gas pycnometry. The Weibull method, used to statistically analyze the acquired data from the diameter intervals, indicated an inverse dependence, where the thinnest fibers had the highest density values. The morphology of the fibers was obtained through scanning electron microscopy (SEM), in which a lower presence of defects was revealed in the thinner fibers, corroborating the inverse density dependence. In addition, the sedge fiber was characterized by differential scanning calorimetry and thermogravimetric analysis, which indicate an initial thermal degradation at around 241 °C. These results revealed for the first time that thinner sedge fibers might be promising reinforcement for polymer composites with a limit in temperature application.

This article discusses research on utilizing natural fibers and red mud waste as eco-friendly alternatives in the production of polymer matrix composites. In this study, composites of isophthalic unsaturated polyester matrix were produced by combining bamboo fibers (Bambusa vulgaris) and red mud waste. The red mud waste utilized had a particle size of 50–100 mesh, and the fibers measured 15 mm and 30 mm in length, distributed randomly throughout the matrix. Bamboo fibers were utilized in their raw form and underwent treatment with NaOH (5% for 2 h). The composites underwent mechanical assessment via flexural and tensile testing. The mechanical properties measured were analyzed using analysis of variance (ANOVA) and Tukey’s test. The fracture surfaces of the composites were examined using Scanning Electron Microscopy (SEM). Composites featuring 30 mm long treated fibers and 30% red mud exhibited improved flexural strength (124.71 MPa), along with a deformation of 2.16 mm and a flexural modulus of 15.79 GPa. Tensile tests revealed that incorporating red mud waste significantly enhanced the tensile strength by 68% (15BTRMW10) compared to neat polyester. ANOVA confirmed the dependability of the findings, emphasizing the viability of producing hybrid composites from red mud waste and bamboo fiber.

Reliable ballistic armor systems are crucial to ensure the safety of humans and vehicles. Typically, these systems are constructed from various materials like fiber-reinforced polymer composites, which are utilized for a favorable weight to ballistic protection ratio. In particular, there has been a quest for eco-friendly materials that offer both strong mechanical properties and sustainable advantages. The present work conducted a ballistic analysis of epoxy matrix composites using raffia (Raphia vinifera) fibers from the Amazon region as reinforcement. The experiments investigated the limit and residual velocities of composites with 10, 20, and 30 vol% of raffia. The experimental density of the composites was lower than that of the epoxy. Fractured surfaces were examined by scanning electron microscopy (SEM) to reveal the failure mechanism. The results showed that composites with 10 vol% raffia fiber fabric had the highest ballistic energy absorption (168.91 J) and limit velocity (201.43 m/s). The ones with 30 vol% displayed a higher level of physical integrity. The SEM micrographs demonstrated the failure mechanisms were associated with delamination and fiber breakage. There was a small variation in residual velocity between the composites reinforced with 10, 20, and 30 vol% of raffia, with 826.66, 829.75, and 820.44 m/s, respectively.