Alkali‐activated materials (AAMs) and “geopolymers” are inorganic polymeric materials obtained by mixing of solid aluminosilicate precursors with an alkaline solution (generally, KOH or NaOH and Na₂SiO₃ mixed in various ratios). This class of aluminosilicate materials has emerged as a greener alternative to traditional concrete, for large‐scale as well as for niche applications such as conservation and restoration of built heritage. In this work we apply Raman spectroscopy both to aluminosilicate precursors (metakaolin, pumice, volcanic ash, volcanic soils, clayey sediments, ceramic waste) and to the respective AAMs. In the field of vibrational spectroscopy, Raman is much less employed in the literature with respect to Fourier transform infrared (FTIR) to have insights into the alkali activation process from a molecular point of view. The aim of this paper is to investigate the potentiality of a Raman approach to the comparison of the employed raw materials with the respective AAMs. Raman analyses during the first hours of geopolymerization were also carried out on the clayey sediments and ceramic waste‐based products. The results, differentiated according to the employed precursors, exhibit spectra relative to crystalline and amorphous phases that can give an indication about the newly formed aluminosilicate gel.

This paper analyses the net social benefits deriving from the medium-scale production of geopolymers based on volcanic ash compared to traditional cementitious materials used in construction and restoration sectors. In contrast to the existing literature grounded on the physical and mechanical characterization of geopolymers, our analysis considers two aspects: public finance savings from avoiding the disposal of volcanic ash in landfills and environmental benefits deriving from reduction in CO₂ releases due to the production process at room temperature. Our case study focuses on the reuse of natural waste, namely the volcanic ash of the Mt. Etna volcano (Italy), whose disposal involves significant costs for society. Its use in the alkaline activation process avoids the exploitation of natural resources. Considering the huge amount of volcanic ash from Mt. Etna that falls on the urban areas of Eastern Sicily, the results show relevant economic benefits, in terms of both avoided costs and tax reductions for the citizens. Alongside these, significant environmental benefits are evidenced thanks to the release of up to 78% lower CO₂ emissions by synthesised materials with volcanic ash than by traditional cementitious ones. Overall, the social cost savings compared to traditional materials is 0.339 EUR/kg for geopolymer.