All-solid-state sensors with polyvinyl chloride (PVC)-based membranes using off-the-shelf N-hydroxysuccinimide (NHS) and succinimide (Succ) ionophores were prepared using DOP (dioctyl phthalate) and NPOE (ortho-nitrophenyloctyl ether) as plasticizers. Good responses were obtained when NHS was used. The potentiometric response of the proposed electrode is independent of pH over the range 2–6. The electrode shows a fast response time of 0.25 s. The electrode exhibits a Super-Nernstian response, with 37.5 mV/decade, with a potentiometric detection limit of 4.4 µM. The proposed sensor revealed good selectivity towards a group of transition metal ions.

In this work, new films containing composite materials based on blends of thermoplastic polymers of the polyurethane (TPU) and polyolefin (TPO) type, in the absence and presence of BaTiO₃ nanoparticles (NPs) with the size smaller 100 nm, were prepared. The vibrational properties of the free films depending on the weight ratio of the two thermoplastic polymers were studied. Our results demonstrate that these films are optically active, with strong, broad, and adjustable photoluminescence by varying the amount of TPU. The crystalline structure of BaTiO₃ and the influence of thermoplastic polymers on the crystallization process of these inorganic NPs were determined by X-ray diffraction (XRD) studies. The vibrational changes induced in the thermoplastic polymer’s matrix of the BaTiO₃ NPs were showcased by Raman scattering and FTIR spectroscopy. The incorporation of BaTiO₃ NPs in the matrix of thermoplastic elastomers revealed the shift dependence of the photoluminescence (PL) band depending on the BaTiO₃ NP concentration, which was capable of covering a wide visible spectral range. The dependencies of the dielectric relaxation phenomena with the weight of BaTiO₃ NPs in thermoplastic polymers blends were also demonstrated.

This paper describes the process used to produce thermoplastic building materials from non-recyclable mixed plastic–paper packaging waste. A first step was dedicated to an innovative and sustainable sterilization technology for non-recyclable waste, based on exposure to microwave radiation in closed air-circulation ovens. Further, composites with different cellulose contents and with two polymer matrices, respectively, were obtained using an injection process, and the samples were subjected to mechanical and physical tests. Due to their superior features, the products based on mixed polypropylene–paper packaging waste may successfully replace the classic polyvinylchloride-based wood–plastic composites. The environmental impact of mixed plastic–paper packaging waste was analyzed, and the sustainability of the thermoplastic technology was demonstrated from an economic and environmental point of view.

Composite materials are materials with anisotropic properties that are created by combining several different components in a way that allows the best qualities of each component to be used. In this paper, raw materials were used to obtain composite materials of the type TPU/PP/BaTiO₃ powder. The thermogravimetric analysis, dynamic differential calorimetry, and scanning electron microscopy were carried out. The preliminary tests for making specific filaments for 3D printing with a diameter of 1.75 mm were carried out on a laboratory extruder. The purpose of the experiment was to develop the optimal extrusion temperatures and the speed of drawing the filament to make filaments with rigorously constant dimensions, and the variation in diameter had a maximum of 10%.

New aspects concerning the photodegradation (PD) of ampicillin are reported by photoluminescence (PL), Raman scattering and FTIR spectroscopy. The exposure of ampicillin in the absence (AM) and in the presence of the excipient (AMP) to UV light leads to an intensity diminution of the photoluminescence excitation (PLE) and photoluminescence (PL) spectra and the emergence of a new IR band at 3450 cm⁻¹. The photoluminescence studies demonstrate that the AM PD is amplified in the presence of excipients and an alkaline medium. In this last case, the PD process of AM involves the emergence of new compounds, whose presence is highlighted by: (i) the emergence of the isosbestic point at 300 nm in the UV-VIS spectra; (ii) a change in the ratio between the absorbance of IR bands situated in the spectral ranges 1200–1660 and 3250–3450 cm⁻¹; and (iii) a change in the ratio between the intensities of the Raman lines localized in the spectral ranges 1050–1800 and 2750–3100 cm⁻¹. A chemical mechanism of the PD processes of AM in an alkaline medium is proposed.

Buildings are among the most significant sources of energy consumption worldwide. Unfortunately, many are inefficient in terms of energy use, leading to high operational expenses. With modern technologies such as IoT sensors, smart meters, secure real-time communication, and advanced mathematical algorithms for data processing integrated into an efficient energy management platform, traditional buildings can be transformed into smart structures. In this context, a platform called “Building Energy Efficiency in Totality” (BENEFIT), which incorporates the smart building energy management (SBEM) concept, has been designed, developed, integrated, and tested as an innovative tool for monitoring and optimally controlling energy consumption. The platform is based on open-source software, enabling rapid and straightforward development of comprehensive solutions that address all aspects of the SBEM concept. The BENEFIT architecture allows the management of a wide range of devices within the building, including energy generation units, heating, ventilation, and air conditioning systems, indoor lighting, environmental sensors, surveillance cameras, and others. BENEFIT has been implemented and tested in a building belonging to the Faculty of Electrical Engineering at the Technical University of Iasi, Romania. The analysis of the results after one year of integrating the BENEFIT platform has resulted in a plan focused on measures to reduce energy consumption and improve the building’s performance and efficiency. The implementation of two measures (upgrading window insulation and improving lighting) resulted in a 12.14% reduction in total energy consumption.