Currently there is a growing concern about the presence of emerging contaminants (EC) in water bodies and their potential ecotoxicological effects. Pharmaceuticals, a type of EC, are widely distributed in the environment and their main entry is through wastewater from treatment plants, since these systems are not designed to remove EC. In this sense, the photo-Fenton process, an advanced oxidation process, has proven to be highly efficient in degrading new potentially harmful contaminants. However, this process is affected by multiple factors, which makes it necessary to implement a methodological strategy to optimize the photo-Fenton process. Within these, the Taguchi method provides robust and low-cost solutions with the least number of experiments, providing knowledge of the contribution of each of the factors studied to the response variable. In addition to the above, the Taguchi method can be coupled to a Grey relational analysis (Grey–Taguchi method), which will allow the optimization of more than one response variable at the same time. This paper discusses the parameters that affect the photo-Fenton process and the application of designs of experiments to optimize the process.

Constructed wetland-microbial fuel cells (CW-MFCs) systems are a sustainable technology capable of producing bioelectricity and treating wastewater simultaneously. It is also possible to obtain bioelectricity from the photosynthetic substrates obtained by the rhizodeposition of macrophytes, where the electroactive microorganisms present in the rhizosphere use these compounds as biofuel. In the present study, the bioelectricity production capacity of Juncus effusus and Philodendron cordatum species was evaluated in a CW-MFC without an external carbon source. The Juncus effusus species showed a higher bioelectrochemical performance, as they recorded a maximum voltage of 399 mV, a power density of 63.7 mW/m², a volumetric power density of 15.9 W/m³, an internal resistance of 200 Ω, an anodic potential of - 368 mV, and a cathodic potential of 229 mV. In addition, different types of carbohydrates in the form of sugars (sucrose, fructose, galactose, and glucose) were quantified by liquid chromatography, with concentrations of 100-450 μg/L. Chromatographic analysis were performed from the root exudates released in the effluent of both species of macrophyte. Sucrose and glucose were the types of sugars that produced the largest amount with portions of up to 35% and 24%, respectively. Sugars are compounds that worked as electron donors for the production of bioelectricity by using endogenous substrates that fed the anodic biofilm. Consumption was 45-55% for sucrose and 40-65% for glucose. Of the different macrophytes evaluated in the CW-MFCs, it was observed that the production of bioelectricity differs mainly due to the quantity of the root exudates released in the rhizosphere. GRAPHICAL ABSTRACT

Erosion of the leading edge is one of the most severe forms of damage in wind turbine blades, particularly in offshore wind farms. This degradation, mainly caused by rain, sand, and airborne particles through droplet impingement wear, significantly decreases blade aerodynamic efficiency and power output. Since blades, typically made of fiber-reinforced polymer composites, are the most expensive components of a turbine, developing protective coatings is essential. In this study, polyurethane (PU) composite coatings reinforced with titanium dioxide (TiO₂) particles were added on glass fiber substrates by spray coating. The incorporation of TiO₂ improved the mechanical and electrochemical performance of the PU coatings. FTIR and XRD confirmed that low TiO₂ loadings (1 and 3 wt%) were well dispersed within the PU matrix due to hydrogen bonding between TiO₂ –OH groups and PU –NH groups. The PU/TiO₂ 3% coating exhibited ~61% lower corrosion current density (I_corr) compared to neat PU, indicating superior corrosion resistance. Furthermore, uniform TiO₂ dispersion resulted in statistically significant improvements (p < 0.05) in hardness, yield strength, elastic modulus, and adhesion strength. Overall, the PU/TiO₂ coatings, particularly at 3 wt% loading, show strong potential as protective materials for wind turbine blades, given their enhanced mechanical integrity and corrosion resistance.