Lignocellulosic biomass (LCB)-based thermal insulation materials available in the market are more expensive than conventional ones and consist mainly of wood or agricultural bast fibers which are primarily used in construction and textile industries. Therefore, it is crucial to develop LCB-based thermal insulation materials from cheap and available raw materials. The study investigates new thermal insulation materials from locally available residues of annual plants like wheat straw, reeds and corn stalks. The treatment of raw materials was performed by mechanical crushing and defibration by steam explosion process. Optimization of thermal conductivity of the obtained loose-fill thermal insulation materials was investigated at different bulk density levels (30–45–60–75–90 kg m−3). The obtained thermal conductivity varies in range of 0.0401–0.0538 W m−1 K−1 depending on raw material, treatment mode and a target density. The changes of thermal conductivity depending on density were described by the second order polynomial models. In most cases, the optimal thermal conductivity was revealed for the materials with the density of 60 kg m−3. The obtained results suggest the adjustment of density to achieve an optimal thermal conductivity of LCB-based thermal insulation materials. The study also approves the suitability of used annual plants for further investigation towards sustainable LCB-based thermal insulation materials.
The present study evaluates the mold fungal resistance of newly developed loose-fill thermal insulation materials made of wheat straw, corn stalk and water reed. Three distinct techniques for the processing of raw materials were used: mechanical crushing (Raw, ≤20 mm), thermo-mechanical pulping (TMP) with 4% NaOH and steam explosion pulping (SEP). An admixture of boric acid (8%) and tetraborate (7%) was applied to all processed substrates due to their anti-fungal properties. The fourth sample group was prepared from SEP substrates without added fungicide (SEP*) as control. Samples from all treatments were separately inoculated by five different fungal species and incubated in darkness for 28 days at 28 °C and RH > 90%. The highest resistance to the colonization of mold fungi was achieved by TMP and SEP processing, coupled with the addition of boric acid and tetraborate, where molds infested only around 35% to 40% of the inoculated sample area. The lowest mold fungi resistance was detected for the Raw and SEP* samples, each ~75%; they were affected by rich amount of accessible nutrients, suggesting that boric acid and tetraborate additives alone did not prevent mold fungal growth as effectively as in combination with TMP and SEP treatments. Together, the achieved fungal colonization scores after combined fungicide and pulping treatments are very promising for the application of tested renewable materials in the future development of thermal insulation products.
This study investigates the fire resistance capabilities of newly developed loose-fill thermal insulation materials crafted from annual plants such as wheat straw, corn stalk, and water reed. Three processing methodologies were employed: mechanical crushing (raw, size ≤ 20 mm), chemi-mechanical pulping (CMP) using 4% sodium hydroxide, and steam explosion (SE). An admixture of boric acid (8%) and tetraborate (7%) was added to all treated materials to enhance fire retardancy. The fire reaction characteristics of the insulation materials were assessed using a cone calorimeter measuring the key parameters like time to ignition, total heat release, heat release rate, and total smoke production. The findings indicate that nearly all tested insulation samples, apart from the raw and SE water reed, demonstrated fire resistance comparable to commercial cellulose insulation, surpassing the fire performance of various synthetic foams and composite materials. Furthermore, the single-flame source fire tests indicated that the developed insulation materials achieved a fire classification E, except for the SE water reed sample. Thus, the fire performance results approve the suitability of developed plant-based insulation materials for competing materials in building constructions.
The present study evaluates mold fungal resistance of newly developed loose-fill thermal insulation materials from wheat straw, corn stalk and water reed. Three different processing methods of raw materials was performed by mechanical crushing (Raw, ≤ 20 mm), thermal-mechanical pulping (TMP) using 4% NaOH and steam explosion pulping (SEP). An admixture of boric acid (8%) and tetraborate (7%) was applied to all processed substrates due to their anti-fungal properties. Additionally, the fourth sample group was prepared from SEPs of all raw species without boric acid and tetraborate (SEP*) as control. Samples from all treatments were separately inoculated by 5 different fungal species and incubated in darkness for 28 days at 28 ℃ and RH >90%. The highest resistance to the colonization of mold fungi was achieved by TMP and SEP processing coupled with addition of boric acid and tetraborate, where molds infest only around 35% to 40% of the inoculated sample area. The lowest mold fungi resistance was detected for Raw and SEP* samples, each ~75% that was affected by rich amount of accessible nutrients, suggesting that boric acid and tetraborate additives alone did not prevent mold fungal growth as effective as in combination with TMP and SEP treatments. Together, the achieved fungal colonization scores after combined fungicide and pulping treatments are acceptable for the application of various renewable materials in future thermal insulation product development.
Human activities undoubtedly increase greenhouse gases (GHG), negatively influencing global climate change. The building and construction sector uses at least 40% of the total energy consumption and produces the same percentage of GHG emissions. Therefore, the development of sustainable building materials is a crucial key factor for environmental protection. The study contributes to the development of bio-based façade materials using available raw biomass like wheat straw, grey alder, and softwood (a mix of spruce and pine), to promote reduced emissions of CO2. Two technologies were used to produce high-density particleboards based on (1) steam explosion treatment and (2) the addition of bio-based suberinic acids as a binder. In addition to the biomass species and board type, the influence of conventional and mold hot-pressing was investigated on produced board properties: density, thickness swelling, modules of rupture and elasticity in bending, and internal bonding. The obtained particleboards demonstrate significant differences in terms of the tested properties depending on all variable factors. The best performance, in terms of physical–mechanical properties, was achieved by the conventionally hot-pressed board of steam-exploded grey alder particles, being influenced by the highest density (1380 kg/m3). Mold hot-pressing in most cases resulted in decreased performance of obtained boards.
This study focuses on the development of wood-based particleboard that address resource efficiency, environmental sustainability, and health-related concerns. The conventional particleboard industry relies on synthetic, predominantly formaldehyde-based adhesives, which pose environmental, health, and end-use risks. Rising raw material prices, regulatory restrictions, and increasing competition in the wood-processing sector have further highlighted the importance of alternative biomass resources for particleboard production. In response to these challenges, this study investigates the suitability of available sawdust resources derived from the production residues of cellular wood materials and recycled particleboards, combined with natural suberinic acids mixture obtained from birch outer bark as a binder. The effects of furnish structure, binder content (15–21%), pressing temperature (190–220 °C), pressing rate (0.9–1.7 min/mm), and board density (650–850 kg/m3) on the resulting particleboard properties were evaluated. The results demonstrate that it is possible to meet the requirement values for thickness swelling (≤17%) and internal bonding strength (≥0.40 N/mm2) specified for interior fitment boards, including furniture applications according to EN 312, Type P2. The bending properties of the best-performing particleboards are very close to the requirement values (MOE ≥ 1800 N/mm2, MOR ≥ 11 N/mm2), indicating the potential for further improvement at the target density range. Furnish structure, board thickness, density, and pressing temperature were identified as the most influential factors affecting the final board properties.