Electrothermal processes were studied in pyroresistive composites based on high-density polyethylene (HDPE) containing 8 vol.% carbon black (CB), 8 vol.% carbon fibers (CF), and their mixture 4 vol.% CB + 4 vol.% CF. It is shown that the kinetic heating curves of composites are well described by an exponential dependence with a certain heating rate constant k for each type of composite. After a short heating time, the equilibrium temperature T_e is reached in the sample. When the applied voltage exceeds a certain value, the T_e value decreases due to the presence of the positive temperature coefficient of resistance (PTC) effect. Due to the PTC effect, the composites exhibit a self-regulating effect relative to the T_e. Relations between the applied voltage, electric power, and equilibrium temperature are found, the T_e value depends on the applied voltage according to the quadratic law whereas there is a linear relationship between the T_e and electric power. A possible application of such pyroresistive composites is resistance welding of plastics using a heating element (HE) made of a pyroresistive material. The use of HDPE-CB composite to create HE for resistance welding is demonstrated and the welded joint of HDPE parts obtained using HE is shown.

The development of easy and direct real-time monitoring of welded joint quality instead of surface damage analysis is crucial to improve the quality of industrial products. This work presents the results of high-density polyethylene (HDPE)-based composites with various carbon black (CB) content (from 20 to 30 vol.%) for use as a heating element and strain sensor in electrofusion-welded polymer joints. The pyroresistive heating process was used to determine the effect of generated Joule heat during welding on the structure and sensor properties of polymer–carbon composites. It is shown that the generation of Joule heat depends on the nanocarbon content and affects the crystallinity of the polymer matrix. The partial disruption of the conductive path of carbon black particles was observed and, as a result, a decrease in electrical conductivity for composites with lower CB content after welding was found. For the highest CB amount, conductivity increased, which is caused by smaller particle-to-particle distance for filler paths. Therefore, the best balance between pyroresistive and sensor properties was found.

The purpose of the work was to develop a new method of processing samples with a piezoresistive effect that will be sensitive to cyclic mechanical loads. The sensor material was based on ground vulcanizate, which was coated with a solution of an adhesive thermoplastic carrier-polymer containing different types of carbon filler. The samples were formed by hot compaction method. As a setup for the experiment, an adapted apparatus for TMA analysis (by TA instruments) was used. It was found that the proposed composites have a linear electrical response on mechanical load, operate at different frequencies in a wide temperature range. The effect of filler hybridization on response was also investigated.