The need for reducing fossil fuel consumption and greenhouse gas (GHG) emissions in internal combustion engines has raised the opportunity for the use of renewable energy sources. For the progressive replacement of fossil fuels like diesel, those derived from the sustainable management of forest resources may be a good option. In Portugal, pine trees (pinus pinaster) are among the most widely cultivated tree species. Turpentine can be extracted from their sap without harming the tree. Turpentine is known to be a good fuel with a lower viscosity than regular diesel but with a comparable caloric value, boiling point and ignition characteristics, although it is not widely used as a compression ignition fuel. Moreover, recent research has highlighted the possibility of substantially increasing the turpentine yield through biotechnology, bringing it closer to economic viability. The present study investigates the performance, pollutant emissions and fuel consumption of a 1.6 L four-cylinder direct-injection diesel engine operating with several blends of commercial diesel fuel and turpentine obtained from pine trees. The aim of this study was to assess whether it would be possible to maintain or even improve the performance, fuel consumption and GHG and pollutant emissions (HC, NO_x, CO and PM) of the engine with the partial incorporation of this biofuel. Turpentine blends of up to 30% in substitution of regular diesel fuel were tested. The main novelties of the present work are related to (i) the careful testing of a still-insufficiently studied fuel that could gain economical attractiveness with the recent developments in yield improvement through biotechnology and (ii) the tests conducted under fixed engine load positions typical of road and highway conditions. The addition of this biofuel only slightly impacted the engine performance parameters. However, a slightly positive effect was observed in terms of torque, with an increase of up to 7.9% at low load for the 15T85D mixture and 6.8% at high load being observed. Power registered an increase of 9% for the 15T85D mixture at low speed and an increase of 5% for the 30T70D mixture at high speed when compared to the reference fuel (commercial diesel fuel). While the efficiency and fossil GHG emissions were improved with the incorporation of turpentine, it had a mixed effect on polluting emissions such as unburned hydrocarbons (HC) and smoke (PM) and a negative effect on nitrogen oxides (NO_x). NO_x emissions increased by 30% for high loads and 20% for low loads, mainly as an indirect effect of the improvement in the engine performance and not so much as a consequence of the marginally higher oxygen content of turpentine relative to commercial diesel fuel.

Waste heat recovery from exhaust gas is one of the most convenient methods to save energy in internal combustion engine-driven vehicles. This paper aims to investigate a reduction in waste heat from the exhaust gas of an internal combustion engine of a serial Diesel–electric hybrid bus by recovering part of the heat and converting it into useful power with the help of a split-flow supercritical CO₂ (sCO₂) recompression Brayton cycle. It can recover 17.01 kW of the total 33.47 kW of waste heat contained in exhaust gas from a 151 kW internal combustion engine. The thermal efficiency of the cycle is 38.51%, and the net power of the cycle is 6.55 kW. The variation in the sCO₂ temperature at the shutdown of the internal combustion engine is analyzed, and a slow drop followed by a sudden and then a slow drop is observed. After 80 s from stopping the engine, the temperature drops by (23–33)% depending on the tube thickness of the recovery heat exchanger. The performances (net power, thermal efficiency, and waste heat recovery efficiency) of the split-flow sCO₂ recompression Brayton cycle are clearly superior to those of the steam Rankine cycle and the organic Rankine cycle (ORC) with cyclopentane as a working fluid.

This research evaluates the feasibility of using eucalyptus oil blended with conventional diesel fuel in diesel engines. Eucalyptus globulus is one of the main tree species cultivated for paper pulp in western European countries such as Portugal, and eucalyptus oil is one of the byproducts that so far has not been sufficiently evaluated as a biofuel. This study assesses the impact of using this additive on engine performance parameters and emissions as a means to contribute to reducing fossil fuel consumption and pollutant and greenhouse gas (GHG) emissions. The analysis revealed that the addition of eucalyptus oil had a positive effect on torque, a critical performance parameter, with biofuel blends showing consistent torque increases at lower engine speeds. However, torque tended to decrease towards the higher range of engine speed for eucalyptus oil–diesel blends. Several blends showed lower brake specific fuel consumption compared to regular diesel at high engine loads and low engine speeds. Brake thermal efficiency did not vary substantially at lower engine speeds and loads but decreased at higher speeds and loads. Pollutant emissions, particularly unburned hydrocarbons and nitrogen oxides, were influenced by fuel composition, with biofuel blends showing both increases and decreases compared to diesel. It is noteworthy that eucalyptus oil blends exhibited up to a 60% reduction in smoke opacity under specific operating conditions at low speed and high load for 10% incorporation (10EU90D), suggesting that in addition to the already positive effects of cutting down fossil CO₂ emissions in proportion to the substitution of fossil diesel with nearly carbon-neutral eucalyptus oil, more environmental benefits may be expected from the incorporation of this product. Although the present economic viability of using eucalyptus oil as a biofuel is still not guaranteed, the present study seems to reinforce its technical viability. Future prospects for the improvement of oil yield through biotechnology, the economic interest of this product for several countries, and the updating and upscaling industrial processes may allow the viability of this biofuel to remain a possibility in the future

Agriculture may hold the key to a sustainable future. By efficiently capturing atmospheric CO₂, we can simultaneously produce food, feed, biomass, and biofuels. For more eco-friendly soil processing practices, biofuels can replace diesel in agricultural machinery, significantly reducing the carbon footprint of crop production. Thus, biofuel production can be a sustainable solution for a future with a decreasing carbon footprint. This paper examines the possibility of replacing petroleum-based fuels with 100% biofuels to continue powering heavy-duty vehicles, where the use of electric vehicles is not the optimal solution. This study particularly focused on the operating scenario of heavy-duty engines under medium to high loads, typical of transport or soil processing in agriculture. Diesel was used as a benchmark, and each alternative, such as vegetable oil, methyl ester (B100), and methyl ester–ethanol blends (90B10E, 80B20E, and 70B30E), was tested individually. To find a sustainable fuel substitute, the goal was to identify a biofuel with a kinematic viscosity similar to that of diesel for a comparable spray process. Experimental results showed that an 80% methyl ester and 20% ethanol blend had a kinematic viscosity close to that of diesel. In addition to diesel, this blend resulted in a 48.6% reduction in exhaust gas opacity and a 6.54% lower specific fuel consumption (BSEC). The main aim of the tests was to find a 100% biofuel substitute without modifying the fuel injection systems of existing engines.

The use of renewable energy sources instead of conventional ones, together with the development of efficient electricity storage solutions, represents a central objective of the transition to sustainable and resilient energy systems. In this context, two main development directions are the integration of hydrogen in the energy chain (Power-to-Gas) and the use of batteries, each with specific advantages and disadvantages, compared to internal combustion engines. The purpose of this work was to evaluate the dynamic response time of a hydrogen fuel cell model powered by green hydrogen, under conditions of sudden and instantaneous power demand, for its integration into wind-based renewable energy systems. Experimental research was carried out on an autonomous installation designed to operate continuously for an unlimited duration, simulating the integration of hydrogen produced from wind sources. The novelty consists of the application of an instrumental method for automatic measurement of the response time of a proton exchange membrane hydrogen fuel cell, based on the automatic acquisition and processing of measured electrical signals. The response time of the fuel cell was compared with that of an internal combustion engine based on the classic Carnot cycle, using a dedicated oscilloscope. The load connection time, the current and voltage variation as a function of time were recorded simultaneously. The results show that the response time of the fuel cell is relatively short (approximately 0.3 ms), much lower than that of the internal combustion engine (0.7 s), being of the order of about 2333 times smaller. In conclusion, the hydrogen fuel cell can be effectively integrated into renewable energy systems for the role of an uninterruptible power supply, with an exceptionally fast dynamic response, suitable for applications in regulating and supporting wind-powered networks.

Heat transfer simulation in textile materials has many practical applications, such as in the design of protective clothing for firefighters, the development of thermal insulation materials, and the optimization of temperature control in textiles for comfort and performance. This paper presents a study on heat transfer simulation in woven fabrics using the Comsol Multiphysics® application. The simulations were carried out for both microscopic (3D) and macroscopic (1D) scales and the heat flux variation was compared with experimental results. The steady-state average heat flow through the textile was determined, and this value was used to calculate the thermal resistance of the woven fabrics. The thermal resistance values obtained were within a deviation range of 4.2% to 6.3% from the values determined according to ISO 11092/1016, thus validating the proposed model. For the transient regime, the microscopic approach proved to be more accurate, the estimated time for the heat flow to reach a certain value depending essentially on the scale approached in the modeling. This finding has particular significance in the field of protective clothing, especially for firefighters exposed to radiant heat sources, where estimating the time for burns to occur is crucial.