This study presents a novel approach to enhance photoelectrochemical (PEC) water oxidation by integrating cobalt phthalocyanine (CoPc) with bismuth vanadate (BVO) via a direct solvothermal method. The as-prepared BVO@CoPc photoanode demonstrated a photocurrent density of 4.0 mA cm⁻² at 1.23 V vs. RHE, which is approximately 3.1 times greater than that of the unmodified BVO, and has superior stability. The incident photon-to-current conversion efficiency (IPCE) of the BVO@CoPc photoanode reaches an impressive value of 81%, accompanied by significant enhancements in charge injection efficiency. This excellent performance can be ascribed to the enhanced hydrophilicity with the BVO/CoPc interface engineering, which facilitates interfacial interaction between the electrode and electrolyte, accelerates photogenerated charge carrier transfer and separation. Furthermore, compared to the immersion and drop-casting methods, the BVO@CoPc-S composite photoanode prepared via the solvothermal method exhibits a significant improvement in interfacial contact and surface hydrophilicity. These findings highlight the potential of the strategy based on interfacial hydrophilicity modification to overcome key limitations in PEC water splitting, providing a pathway to more efficient and durable photoanode design.

The optical properties of PET have always been a problem that related research has been trying to break through. In the previous work, we modified PET by adding PSLDH (phosphate antioxidant) to obtain a PET film with excellent optical properties. Through non-isothermal crystallization kinetic analysis of modified PET, we hope to verify the conclusion of optical properties by the effect of PSLDH addition on the crystallization properties of PET. PET and PSLDH modified PET were tested by DSC at different cooling rates. The non-isothermal crystallization kinetic process was calculated and analyzed by Jeziorny and Mo methods and the non-isothermal crystallization activation energy was analyzed by Kissinger and Friedman methods by analyzing the DSC curves. The results show that the addition of PSLDH at 0.05 wt% can make the crystallization of PET smaller and slower, which is the same as the case required for excellent optical properties. At the same time, the results can also guide the processing of the optical PET film.

The oxygen evolution reaction (OER), which involves a four-electron transfer and slow kinetics, requires an efficient catalyst to overcome the high energy barrier for high-performance water electrolysis. In this paper, a novel Ni₃S₂@V-NiFe(III) LDH/NF catalyst was prepared via a facile two-step hydrothermal method. The constructed heterostructure of Ni₃S₂@V-NiFe(III) LDH increases the specific surface area and regulates the electronic structure. Furthermore, the introduction of the V element forms an electron transport chain of Ni-O-Fe-O-V-O-Ni, which optimizes the binding energy between metal active sites and oxygen evolution reaction intermediates, accelerates electron transfer, and improves self-reconstruction. With this dual regulation strategy, Ni₃S₂@V-NiFe(III) LDH/NF exhibits exceptional OER performance with an overpotential of 280 mV at 100 mA/cm² and a Tafel slope of 45.4 mV/dec. This work develops a dual regulation strategy combining heterostructure formation and the doping effect, which are beneficial in the design of efficient OER catalysts.

Traditional graphite anode material typically shows a low theoretical capacity and easy lithium decomposition. Molybdenum disulfide is one of the promising anode materials for advanced lithium-ion batteries, which possess low cost, unique two-dimensional layered structure, and high theoretical capacity. However, the low reversible capacity and the cycling-capacity retention rate induced by its poor conductivity and volume expansion during cycling blocks further application. In this paper, a collaborative control strategy of monodisperse MoS₂/graphite composites was utilized and studied in detail. MoS₂/graphite nanocomposites with different ratios (MoS₂:graphite = 20%:80%, 40%:60%, 60%:40%, and 80%:20%) were prepared by mechanical ball-milling and low-temperature annealing. The graphite sheets were uniformly dispersed between the MoS₂ sheets by the ball-milling process, which effectively reduced the agglomeration of MoS₂ and simultaneously improved the electrical conductivity of the composite. It was found that the capacity of MoS₂/graphite composites kept increasing along with the increasing percentage of MoS₂ and possessed the highest initial discharge capacity (832.70 mAh/g) when MoS₂:graphite = 80%:20%. This facile strategy is easy to implement, is low-cost, and is cosmically produced, which is suitable for the development and manufacture of advance lithium-ion batteries.

Lithium batteries incorporating LiFePO₄ (LFP) as the cathode material have gained significant attention in recent research. However, the limited electronic and ionic conductivity of LFP poses challenges to its cycling performance and overall efficiency. In this study, we address these issues by synthesizing a series of LiFePO₄/carbon (LFP/C) composites through low-temperature carbonization coating of LFP in the presence of Coke as the carbon source. The resulting lithium batteries utilizing LFP/C as the cathode material exhibited impressive discharge specific capacities of 148.35 mA·h/g and 126.74 mA·h/g at 0.1 C and 1 C rates, respectively. Even after 200 cycles of charging and discharging, the capacities remained remarkably high, with values of 93.74% and 97.05% retention, showcasing excellent cycling stability. Notably, the LFP/C composite displayed exceptional rate capability, and capacity retention of 99.27% after cycling at different multiplication rates. These findings underscore the efficacy of in situ low-temperature carbonization capping of LFP with Coke in significantly improving both the cycling stability and rate capability of lithium batteries.