In this paper, porous zinc oxide (ZnO) nanosheets were successfully prepared by a simple low-temperature hydrothermal method. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) tests showed that the synthesized product was ZnO with porous sheet structure. The diameter of porous nanosheets was about 100 nm and the thickness was about 8 nm. As a photocatalyst, the degradation efficiencies of porous ZnO nanosheets for methyl orange (MO), methylene blue (MB) and Rhodamine B (RhB) were 97.5%, 99% and 96.8%, respectively. In addition, the degradation efficiency of ZnO for mixed dyes (Mo, MB and RhB) was satisfactory, reaching 97.7%. The photocatalytic stability of MB was further tested and remained at 99% after 20 cycles. In the experiment, ZnO/FTO (fluorine-doped tin oxide) composites were prepared by using ZnO as the conductive layer. Titanium dioxide (TiO₂) was deposited on the surface of ZnO/FTO by electrodeposition, so as to obtain a TiO₂/ZnO/FTO composite. By studying the electrochromic properties of this composite, it was found that the TiO₂/ZnO/FTO composite shows a large light modulation range (55% at 1000 nm) and excellent cycle stability (96.6% at 200 cycles). The main reason for the excellent electrochromic properties may be the synergistic effect between the porous structure and the polymetallic oxides. This study is helpful to improve the photocatalytic efficiency and cycling stability of metal oxides, improve the transmittance of thin films and provide a new strategy for the preparation of ZnO composite materials with excellent photocatalytic and electrochromic properties.

In this paper, the effect of nitrogen annealing on the resistive switching characteristics of the rutile TiO₂ nanowire-based W/TiO₂/FTO memory device is analyzed. The W/TiO₂/FTO memory device exhibits a nonvolatile bipolar resistive switching behavior with a high resistance ratio (R_HRS/R_LRS) of about two orders of magnitude. The conduction behaviors of the W/TiO₂/FTO memory device are attributed to the Ohmic conduction mechanism and the Schottky emission in the low resistance state and the high resistance state, respectively. Furthermore, the R_HRS/R_LRS of the W/TiO₂/FTO memory device is obviously increased from about two orders of magnitude to three orders of magnitude after the rapid nitrogen annealing treatment. In addition, the change in the W/TiO₂ Schottky barrier depletion layer thickness and barrier height modified by the oxygen vacancies at the W/TiO₂ interface is suggested to be responsible for the resistive switching characteristics of the W/TiO₂/FTO memory device. This work demonstrates the potential applications of the rutile TiO₂ nanowire-based W/TiO₂/FTO memory device for high-density data storage in nonvolatile memory devices.

Traditional graphite anode material typically shows a low theoretical capacity and easy lithium decomposition. Molybdenum disulfide is one of the promising anode materials for advanced lithium-ion batteries, which possess low cost, unique two-dimensional layered structure, and high theoretical capacity. However, the low reversible capacity and the cycling-capacity retention rate induced by its poor conductivity and volume expansion during cycling blocks further application. In this paper, a collaborative control strategy of monodisperse MoS₂/graphite composites was utilized and studied in detail. MoS₂/graphite nanocomposites with different ratios (MoS₂:graphite = 20%:80%, 40%:60%, 60%:40%, and 80%:20%) were prepared by mechanical ball-milling and low-temperature annealing. The graphite sheets were uniformly dispersed between the MoS₂ sheets by the ball-milling process, which effectively reduced the agglomeration of MoS₂ and simultaneously improved the electrical conductivity of the composite. It was found that the capacity of MoS₂/graphite composites kept increasing along with the increasing percentage of MoS₂ and possessed the highest initial discharge capacity (832.70 mAh/g) when MoS₂:graphite = 80%:20%. This facile strategy is easy to implement, is low-cost, and is cosmically produced, which is suitable for the development and manufacture of advance lithium-ion batteries.

In this paper, WO₃ nanowires were successfully synthesized via a one-step water bath method at an appropriate temperature. The XRD (Energy Dispersive Spectrometer), SEM (Scanning electron microscope), TEM (Transmission Electron Microscope) and other characterization methods proved that the synthesized product was WO₃, and the product of water bath reaction for 9 h showed the nanowires’ structure. The nanowires were evenly distributed, and the length ranged from 2 μm to 4 μm. The results showed that the nanowires had excellent light transmittance (66%), a very short response time (1.2 s, 2 s) and excellent color rendering efficiency (115.2 cm² C⁻¹) at 650 nm. The electrochemical performance test showed that the specific capacity of the WO₃ nanowires was up to 565 F/g at 1 A/g. Change the different current densities and cycle 100 times, then return to the initial current density, accounting for 99% of the initial specific capacity of 565 F/g. We used this method for the first time to prepare tungsten oxide nanowires and investigated the bifunctional properties of the material, namely the electrochromic and capacitive properties. All of these data indicate that WO₃ nanorods have excellent electrochromic and electrochromic properties and have potential market prospects in the fields of electrochromic glass, variable glasses, advertising, and supercapacitors.

Lithium batteries incorporating LiFePO₄ (LFP) as the cathode material have gained significant attention in recent research. However, the limited electronic and ionic conductivity of LFP poses challenges to its cycling performance and overall efficiency. In this study, we address these issues by synthesizing a series of LiFePO₄/carbon (LFP/C) composites through low-temperature carbonization coating of LFP in the presence of Coke as the carbon source. The resulting lithium batteries utilizing LFP/C as the cathode material exhibited impressive discharge specific capacities of 148.35 mA·h/g and 126.74 mA·h/g at 0.1 C and 1 C rates, respectively. Even after 200 cycles of charging and discharging, the capacities remained remarkably high, with values of 93.74% and 97.05% retention, showcasing excellent cycling stability. Notably, the LFP/C composite displayed exceptional rate capability, and capacity retention of 99.27% after cycling at different multiplication rates. These findings underscore the efficacy of in situ low-temperature carbonization capping of LFP with Coke in significantly improving both the cycling stability and rate capability of lithium batteries.

A facile hydrothermal process has been developed to synthesize the α-Fe₂O₃ nanowire arrays with a preferential growth orientation along the [110] direction. The W/α-Fe₂O₃/FTO memory device with the nonvolatile resistive switching behavior has been achieved. The resistance ratio (R_HRS/R_LRS) of the W/α-Fe₂O₃/FTO memory device exceeds two orders of magnitude, which can be preserved for more than 10³s without obvious decline. Furthermore, the carrier transport properties of the W/α-Fe₂O₃/FTO memory device are dominated by the Ohmic conduction mechanism in the low resistance state and trap-controlled space-charge-limited current conduction mechanism in the high resistance state, respectively. The partial formation and rupture of conducting nanofilaments modified by the intrinsic oxygen vacancies have been suggested to be responsible for the nonvolatile resistive switching behavior of the W/α-Fe₂O₃/FTO memory device. This work suggests that the as-prepared α-Fe₂O₃ nanowire-based W/α-Fe₂O₃/FTO memory device may be a potential candidate for applications in the next-generation nonvolatile memory devices.