The characterization of three commercial thermoelectric modules, which are designed for cooling/heating applications, is presented to employ the devices for power conversion, i.e., as thermoelectric generators (TEGs). The thermoelectric theory is briefly summarized at first, taking into account the relationship between the effective temperature difference across the TEG junctions and the temperature difference applied externally, considering insulating ceramic plates having finite thermal conductance. The thermoelectric modules have been characterized in terms of open-circuit output voltage and output power density for different temperature gradients and load conditions. Measurement techniques and experimental data are reported, which show the possibility of using thermoelectric devices for energy-harvesting applications. A comparison of the results from the tested devices with the performance data of commercial TEGs that are specifically designed for power harvesting is then presented, and the main characteristics of the two device typologies are discussed. A TEG was then used to supply an autonomous system that interfaces with a temperature sensor and periodically transmits the measurement information via an RF link. Experimental data show that the system works correctly and sends the RF signal when the temperature difference that is applied across the TEG is higher than 34 K.

In this paper, an autonomous sensor system, with low-power electronics for radio-frequency (RF) communication, incorporating a thermoelectric energy-harvesting module for unattended operation is presented. A target application is proposed for temperature measurement of walled-in pipes. When the autonomous sensor is placed on the heat source, a thermoelectric module harvests energy, powering the autonomous sensor. In this condition, no external power source is necessary, the temperature measurement is performed, and the data are saved into a nonvolatile memory. When the external readout unit is active, the electromagnetic field is used to power the autonomous sensor system and to communicate the data. An experimental setup has been arranged and characterized by measuring the temperature along the pipe, the voltage that can be generated by thermoelectric generators, and the influence of different materials on RF communication. The temperature data of the heat source, which are collected by the autonomous sensor, are compared with that of a reference thermistor. The measurement results show good agreement between the two measured temperature data sets. The experimental data demonstrate that the autonomous system works correctly for a temperature gradient that is higher than 9degC, within a readout distance of a few centimeters. The presented autonomous sensor system can be effectively used for measurements into a close environment in which a temperature difference is present.

A smart system for flow measurement is presented, consisting of a micromachined thermal flow sensor combined with a smart front-end electronic interface. The flow sensor is based on a novel thermal transduction method, which combines the hot-film and calorimetric sensing principles. The sensor consists of four germanium thermistors embedded in a thin membrane and connected to form a Wheatstone bridge supplied with a constant DC current. In this configuration, both the bridge unbalance voltage and the voltage at the bridge supply terminals are functions of the flow offering high initial sensitivity, i.e., near zero flow and wide measurement range, respectively. The front-end interface is based on a CMOS relaxation oscillator circuit where the frequency and the duty cycle of a rectangular-wave output signal are related to the bridge unbalance voltage and the voltage at the bridge supply terminals, respectively. Furthermore, the amplitude of the output signal is a linear function of the operating temperature. In this way, a single output signal advantageously carries two pieces of information related to the flow velocity and provides an additional measurement of the sensor operating temperature, which enables the correction of the temperature dependence of the sensor readouts. The system has been experimentally characterized for the measurement of nitrogen gas flow velocity at different sensor temperatures. The initial sensitivities at room temperature result 13.7 kHz/(m/s) and 23.5%/(m/s), in agreement with FEM simulations, for frequency and duty cycle readouts, respectively, with an equivalent velocity resolution of about 0.5 and 1.3 cm/s.

Zinc oxide (ZnO, n-type) and copper oxide (CuO, p-type) nanowires have been synthesized and preliminarily investigated as innovative materials for the fabrication of a proof-of-concept thermoelectric device. The Seebeck coefficients, electrical conductivity and thermoelectric power factors (TPF) of both semiconductor materials have been determined independently using a custom experimental set-up, leading to results in agreement with available literature with potential improvement. Combining bundles of ZnO and CuO nanowires in a series of five thermocouples on alumina leads to a macroscopic prototype of a planar thermoelectric generator (TEG) unit. This demonstrates the possibility of further integration of metal oxide nanostructures into efficient thermoelectric devices.