Hydrogen energy represents a crucial pathway towards achieving carbon neutrality and is a pivotal facet of future strategic emerging industries. The safe and efficient transportation of hydrogen is a key link in the entire chain development of the hydrogen energy industry’s “production, storage, and transportation”. Mixing hydrogen into natural gas pipelines for transportation is the potential best way to achieve large-scale, long-distance, safe, and efficient hydrogen transportation. Welds are identified as the vulnerable points in natural gas pipelines, and compatibility between hydrogen-doped natural gas and existing pipeline welds is a critical technical challenge that affects the global-scale transportation of hydrogen energy. Therefore, this article systematically discusses the construction and weld characteristics of hydrogen-doped natural gas pipelines, the research status of hydrogen damage mechanism, and mechanical property strengthening methods of hydrogen-doped natural gas pipeline welds, and points out the future development direction of hydrogen damage mechanism research in hydrogen-doped natural gas pipeline welds. The research results show that: ① Currently, there is a need for comprehensive research on the degradation of mechanical properties in welds made from typical pipe materials on a global scale. It is imperative to systematically elucidate the mechanism of mechanical property degradation due to conventional and hydrogen-induced damage in welds of high-pressure hydrogen-doped natural gas pipelines worldwide. ② The deterioration of mechanical properties in welds of hydrogen-doped natural gas pipelines is influenced by various components, including hydrogen, carbon dioxide, and nitrogen. It is necessary to reveal the mechanism of mechanical property deterioration of pipeline welds under the joint participation of multiple damage mechanisms under multi-component gas conditions. ③ Establishing a fundamental database of mechanical properties for typical pipeline steel materials under hydrogen-doped natural gas conditions globally is imperative, to form a method for strengthening the mechanical properties of typical high-pressure hydrogen-doped natural gas pipeline welds. ④ It is essential to promptly develop relevant standards for hydrogen blending transportation, welding technology, as well as weld evaluation, testing, and repair procedures for natural gas pipelines.
13 November 2022 in Journal of Petroleum Science and Engineering
High-temperature lithiation is one of the crucial steps for the synthesis of Li- and Mn-rich layered metal oxide (LMLO) cathodes. A profound insight of the micromorphology and crystal structure evolution during calcination helps to realize the finely controlled preparation of final cathodes, finally achieving a desired electrochemical performance. In this work, two typical precursors (hydroxide and oxalate) were selected to prepare LMLO. It is found that the influence of the lithium source on reaction pathways is determined by the properties of precursors. In the case of hydroxide as a precursor, whatever lithium sources it is, the flake morphology of LMLO is inherited from hydroxide precursors. This is because the crystal structure of cathode products has a high similarity with its precursor in terms of the oxygen array arrangement, and the topological transformation occurs from hydroxide (P-(3)ml) to LMLOs (C/2m and R(3)m). Thus, the morphology and microstructure of LMLO cathodes could be well controlled only by tuning the properties of hydroxide precursors. Conversely, the decomposition of a lithium source has a great influence on the intermediate transformation when oxalate is used as the precursor. This is because a large amount of CO2 is released from the oxalate precursor after the decomposition reaction, resulting in drastic structural changes. At this time, the diffusion ability of the lithium source leads to the competition between the spinel phase and layered phase. Based on this point, the formation of a spinel intermediate phase can be reduced by accelerating the decomposition of the lithium source, contributing to the generation of a highly pure layered phase, thus exhibiting higher electrochemical performance. These insights provide an exciting cue to the rational selection and design of raw materials and lithium sources for the controlled synthesis of LMLO cathodes.
With the breakthrough in mixing hydrogen into natural gas pipelines for urban use, the widespread application of hydrogen-blended natural gas (HBNG) in energy delivery is imminent. However, this development also introduces significant safety concerns due to notable disparities in the physical and chemical properties between methane and hydrogen, heightening the risks associated with gas leaks. Current models that simulate the diffusion of leaked HBNG from buried pipelines into the atmosphere often employ fixed average leakage rates, which do not accurately represent the dynamic nature of gas leakage and diffusion. This study uses computational fluid dynamics (CFD) 2024R1 software to build a three-dimensional simulation model under a soil–atmosphere coupling model for HBNG leakage and diffusion. The findings reveal that, in the soil–atmosphere coupling model, the gas diffusion range under a fixed leakage rate is smaller than that under a dynamic leakage rate. Under the same influencing factors in calm wind conditions, the gas primarily diffuses in the vertical direction, whereas under the same influencing factors in windy conditions, the gas mainly diffuses in the horizontal direction.
During the transportation of hydrogen-doped natural gas (HCNG), there is a risk of uneven distribution of hydrogen at the elbow, causing hydrogen damage to the pipeline. Therefore, based on the basic principles of computational fluid dynamics, this paper uses a hybrid model to describe the flow process of HCNG in an elbow. The results show that under normal transportation, the hydrogen volume fraction varies within 0.2% with the influence of pressure, flow velocity, temperature, hydrogen volume fraction, and undulating angle, and the uneven distribution of hydrogen in the elbow can be ignored. However, in the shutdown state, the hydrogen slip rate gradually slows down, the hydrogen volume fraction is distributed in a horizontal concentration gradient along the vertical direction, and it gradually accumulates at the height of the undulating tube. The difference in hydrogen volume fraction reaches 50%, and the stratification phenomenon is obvious.